Understanding the Capacity Loss in LiNi 0.5 Mn 1.5 O 4  - Li 4 Ti 5 O 12  Lithium-Ion Cells at Ambient and Elevated Temperatures

The high voltage spinel LiNi 0.5 Mn 1.5 O 4 (LNMO) is an attractive positive electrode due to its operating voltage around 4.7 V (vs. Li/Li + ) arising from the Ni 2+ /Ni 4+ redox couple. In addition to high voltage operation, a second advantage of this material is its capability for fast lithium diffusion kinetics through 3-D transport paths in the spinel structure. However, the electrode material is prone to side reactions with conventional electrolytes, including electrolyte decomposition and transition metal dissolution, especially at elevated temperatures 1 . It is important to understand how undesired reactions originating from the high voltage spinel affect the aging of different cell components and overall cycle life. Half-cells are usually considered as an ideal cell configuration in order to get information only from the electrode of interest. However, this cell configuration may not be ideal to understand capacity fading for long-term cycling and the assumption of ‘stable’ lithium negative electrode may not be valid, especially at high current rates 2 . Also, among the variety of capacity fading mechanisms, the loss of “cyclable” lithium from the positive electrode (or gain of lithium from electrolyte into the negative electrode) due to side reactions in a full-cell can cause significant capacity loss. This capacity loss is not observable in a typical half-cell as a result of an excessive reserve of lithium in the negative electrode. In a full-cell, it is desired that the negative electrode does not contribute to side reactions in a significant way if the interest is more on the positive side. Among candidates on the negative side, Li 4 Ti 5 O 12 (LTO) is known for its stability since its voltage plateau (around 1.5 V vs. Li/Li + ) is in the electrochemical stability window of standard electrolytes and it shows a very small volume change during lithiation. These characteristics make the LNMO-LTO system attractive for a variety of applications (e.g. electric vehicles) but also make it a good model system for studying aging in high voltage spinel-based full cells. In this study, we aim to understand the fundamental mechanisms resulting in capacity fading for LNMO-LTO full cells both at room temperature and elevated temperature (55°C). It is known that electrode interactions occur in this system due to migration of reaction products from LNMO to the LTO side 3, 4 . For this purpose, three electrode cells have been cycled galvanostatically with shor