Catechol-Modified Carbon Cloth as Hybrid Electrode for Energy Storage Devices
Diazonium chemistry was used to enrich Kynol carbon cloth with catechol (dihydroxybenzene) moieties as redox agents. Comprehensive surface analyses (combining BET, SEM, TGA, and TGA-GC/MS) were carried out to evaluate the effect of redox molecules grafted over the carbon cloth surface. Electrochemic...
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| Veröffentlicht in: | Journal of the Electrochemical Society 2019, Vol.166 (6), p.A1147-A1153 |
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| container_end_page | A1153 |
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| container_issue | 6 |
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| container_title | Journal of the Electrochemical Society |
| container_volume | 166 |
| creator | Malka, David Giladi, Sapir Hanna, Ortal Weitman, Michal Cohen, Reut Elias, Yuval Attias, Ran Brousse, Thierry Frimer, Aryeh A. Aurbach, Doron |
| description | Diazonium chemistry was used to enrich Kynol carbon cloth with catechol (dihydroxybenzene) moieties as redox agents. Comprehensive surface analyses (combining BET, SEM, TGA, and TGA-GC/MS) were carried out to evaluate the effect of redox molecules grafted over the carbon cloth surface. Electrochemical deprotection of 3,4-dimethoxyaniline grafted to the electrochemically active catechol, followed by electrochemical assessment in a three-electrode cell, shows a faradaic contribution due to redox reactions from the catechol-grafted moieties. Galvanostatic measurements underline the remarkably stable performance of this redox reaction, which permits over 3,000 cycles. |
| doi_str_mv | 10.1149/2.0911906jes |
| format | Article |
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Comprehensive surface analyses (combining BET, SEM, TGA, and TGA-GC/MS) were carried out to evaluate the effect of redox molecules grafted over the carbon cloth surface. Electrochemical deprotection of 3,4-dimethoxyaniline grafted to the electrochemically active catechol, followed by electrochemical assessment in a three-electrode cell, shows a faradaic contribution due to redox reactions from the catechol-grafted moieties. 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Galvanostatic measurements underline the remarkably stable performance of this redox reaction, which permits over 3,000 cycles.</description><subject>Condensed Matter</subject><subject>Materials Science</subject><subject>Physics</subject><issn>0013-4651</issn><issn>1945-7111</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpt0E1LAzEQBuAgCtbqzR-Qo4KrmexnjmWtVmjxoJ7D5KtNWZuSrIX-e7dU9OJpmOGZgXkJuQZ2D1CIB37PBIBg1dqmEzICUZRZDQCnZMQY5FlRlXBOLlJaDy00RT0iixZ7q1ehyxbBeOetoS1GFTa07UK_opjobK-iN3TaWd3HYCx1IdLpxsblnr71IeLS0ke789qmS3LmsEv26qeOycfT9L2dZfPX55d2Ms90znif8QoZL_McnWtQK2Ftw1AbrUwN3AihEFmlEJRiwvCSV6UVqtamqSHnhVP5mNwe766wk9voPzHuZUAvZ5O5PMwYB1bVpdjBYO-OVseQUrTudwGYPMQmufyLbeA3R-7DVq7DV9wMj_xPvwFH0myi</recordid><startdate>2019</startdate><enddate>2019</enddate><creator>Malka, David</creator><creator>Giladi, Sapir</creator><creator>Hanna, Ortal</creator><creator>Weitman, Michal</creator><creator>Cohen, Reut</creator><creator>Elias, Yuval</creator><creator>Attias, Ran</creator><creator>Brousse, Thierry</creator><creator>Frimer, Aryeh A.</creator><creator>Aurbach, Doron</creator><general>The Electrochemical Society</general><general>Electrochemical Society</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-1151-546X</orcidid><orcidid>https://orcid.org/0000-0002-1715-0377</orcidid></search><sort><creationdate>2019</creationdate><title>Catechol-Modified Carbon Cloth as Hybrid Electrode for Energy Storage Devices</title><author>Malka, David ; Giladi, Sapir ; Hanna, Ortal ; Weitman, Michal ; Cohen, Reut ; Elias, Yuval ; Attias, Ran ; Brousse, Thierry ; Frimer, Aryeh A. ; Aurbach, Doron</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c302t-26a02533aff8acb9ee80acdcbd712d99baa06ba1bb09d25265e9b7cd871324fb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Condensed Matter</topic><topic>Materials Science</topic><topic>Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Malka, David</creatorcontrib><creatorcontrib>Giladi, Sapir</creatorcontrib><creatorcontrib>Hanna, Ortal</creatorcontrib><creatorcontrib>Weitman, Michal</creatorcontrib><creatorcontrib>Cohen, Reut</creatorcontrib><creatorcontrib>Elias, Yuval</creatorcontrib><creatorcontrib>Attias, Ran</creatorcontrib><creatorcontrib>Brousse, Thierry</creatorcontrib><creatorcontrib>Frimer, Aryeh A.</creatorcontrib><creatorcontrib>Aurbach, Doron</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of the Electrochemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Malka, David</au><au>Giladi, Sapir</au><au>Hanna, Ortal</au><au>Weitman, Michal</au><au>Cohen, Reut</au><au>Elias, Yuval</au><au>Attias, Ran</au><au>Brousse, Thierry</au><au>Frimer, Aryeh A.</au><au>Aurbach, Doron</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Catechol-Modified Carbon Cloth as Hybrid Electrode for Energy Storage Devices</atitle><jtitle>Journal of the Electrochemical Society</jtitle><addtitle>J. Electrochem. Soc</addtitle><date>2019</date><risdate>2019</risdate><volume>166</volume><issue>6</issue><spage>A1147</spage><epage>A1153</epage><pages>A1147-A1153</pages><issn>0013-4651</issn><eissn>1945-7111</eissn><abstract>Diazonium chemistry was used to enrich Kynol carbon cloth with catechol (dihydroxybenzene) moieties as redox agents. Comprehensive surface analyses (combining BET, SEM, TGA, and TGA-GC/MS) were carried out to evaluate the effect of redox molecules grafted over the carbon cloth surface. Electrochemical deprotection of 3,4-dimethoxyaniline grafted to the electrochemically active catechol, followed by electrochemical assessment in a three-electrode cell, shows a faradaic contribution due to redox reactions from the catechol-grafted moieties. 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| ispartof | Journal of the Electrochemical Society, 2019, Vol.166 (6), p.A1147-A1153 |
| issn | 0013-4651 1945-7111 |
| language | eng |
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| source | IOP Publishing Journals |
| subjects | Condensed Matter Materials Science Physics |
| title | Catechol-Modified Carbon Cloth as Hybrid Electrode for Energy Storage Devices |
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