A New Niobium Selenide Cathode for Nonaqueous Lithium Batteries
The ..gamma..-''NbSe/sub 4/'' phase, with a single phase composition range NbSe/sub 4/./sub 0/ to NbSe/sub 4/./sub 5/, is shown to behave as an electrochemically active, reversible cathode material in nonaqueous lithium cells. The cell data, together with the results of n-butyl l...
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| Veröffentlicht in: | J. Electrochem. Soc.; (United States) 1977-03, Vol.124 (3), p.325-329 |
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| container_title | J. Electrochem. Soc.; (United States) |
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| creator | Murphy, D. W. Trumbore, F. A. Carides, J. N. |
| description | The ..gamma..-''NbSe/sub 4/'' phase, with a single phase composition range NbSe/sub 4/./sub 0/ to NbSe/sub 4/./sub 5/, is shown to behave as an electrochemically active, reversible cathode material in nonaqueous lithium cells. The cell data, together with the results of n-butyl lithium reaction studies, indicate a topotactic reaction to give an Li/sub 4/NbSe/sub 4 + x/ (x = 0 to 0.5) discharge product. Cycle data are presented for nonaqueous lithium cells with cathodes of either NbSe/sub 4/ containing small amounts of fibrous NbSe/sub 3/ or hot-pressed composites of NbSe/sub 4 + x/ with graphite and polyethylene. 9 figures. |
| doi_str_mv | 10.1149/1.2133298 |
| format | Article |
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Cycle data are presented for nonaqueous lithium cells with cathodes of either NbSe/sub 4/ containing small amounts of fibrous NbSe/sub 3/ or hot-pressed composites of NbSe/sub 4 + x/ with graphite and polyethylene. 9 figures.</description><identifier>ISSN: 0013-4651</identifier><identifier>EISSN: 1945-7111</identifier><identifier>DOI: 10.1149/1.2133298</identifier><language>eng</language><publisher>United States</publisher><subject>250903 - Energy Storage- Batteries- Materials, Components, & Auxiliaries ; ALKALI METAL COMPOUNDS ; ALKALI METALS ; CARBONIC ACID ESTERS ; CATHODES ; CHALCOGENIDES ; CHEMICAL PREPARATION ; CHEMICAL REACTIONS ; CHLORATES ; CHLORINE COMPOUNDS ; ELECTRIC BATTERIES ; ELECTRIC POTENTIAL ; ELECTROCHEMICAL CELLS ; ELECTRODES ; ELEMENTS ; ENERGY STORAGE ; ENERGY STORAGE SYSTEMS ; ESTERS ; HALOGEN COMPOUNDS ; LITHIUM ; LITHIUM COMPOUNDS ; METAL-NONMETAL BATTERIES ; METALS ; NIOBIUM COMPOUNDS ; NIOBIUM SELENIDES ; ORGANIC COMPOUNDS ; OXYGEN COMPOUNDS ; SELENIDES ; SELENIUM COMPOUNDS ; SYNTHESIS ; TRANSITION ELEMENT COMPOUNDS</subject><ispartof>J. 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Soc.; (United States)</title><description>The ..gamma..-''NbSe/sub 4/'' phase, with a single phase composition range NbSe/sub 4/./sub 0/ to NbSe/sub 4/./sub 5/, is shown to behave as an electrochemically active, reversible cathode material in nonaqueous lithium cells. The cell data, together with the results of n-butyl lithium reaction studies, indicate a topotactic reaction to give an Li/sub 4/NbSe/sub 4 + x/ (x = 0 to 0.5) discharge product. Cycle data are presented for nonaqueous lithium cells with cathodes of either NbSe/sub 4/ containing small amounts of fibrous NbSe/sub 3/ or hot-pressed composites of NbSe/sub 4 + x/ with graphite and polyethylene. 9 figures.</description><subject>250903 - Energy Storage- Batteries- Materials, Components, & Auxiliaries</subject><subject>ALKALI METAL COMPOUNDS</subject><subject>ALKALI METALS</subject><subject>CARBONIC ACID ESTERS</subject><subject>CATHODES</subject><subject>CHALCOGENIDES</subject><subject>CHEMICAL PREPARATION</subject><subject>CHEMICAL REACTIONS</subject><subject>CHLORATES</subject><subject>CHLORINE COMPOUNDS</subject><subject>ELECTRIC BATTERIES</subject><subject>ELECTRIC POTENTIAL</subject><subject>ELECTROCHEMICAL CELLS</subject><subject>ELECTRODES</subject><subject>ELEMENTS</subject><subject>ENERGY STORAGE</subject><subject>ENERGY STORAGE SYSTEMS</subject><subject>ESTERS</subject><subject>HALOGEN COMPOUNDS</subject><subject>LITHIUM</subject><subject>LITHIUM COMPOUNDS</subject><subject>METAL-NONMETAL BATTERIES</subject><subject>METALS</subject><subject>NIOBIUM COMPOUNDS</subject><subject>NIOBIUM SELENIDES</subject><subject>ORGANIC COMPOUNDS</subject><subject>OXYGEN COMPOUNDS</subject><subject>SELENIDES</subject><subject>SELENIUM COMPOUNDS</subject><subject>SYNTHESIS</subject><subject>TRANSITION ELEMENT COMPOUNDS</subject><issn>0013-4651</issn><issn>1945-7111</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1977</creationdate><recordtype>article</recordtype><recordid>eNotkM1KAzEYRYMoWKsL32Bw52JqvvxMkpXU4h-UulDXIc18YSLtRCcZxLe3pV0dLhzu4hByDXQGIMwdzBhwzow-IRMwQtYKAE7JhFLgtWgknJOLnL92E7RQE3I_r1b4W61iWsdxW73jBvvYYrVwpUs7hjRUq9S7nxHTmKtlLN3ee3Cl4BAxX5Kz4DYZr46cks-nx4_FS718e35dzJe1B654HVrFaaONFsxQI1TQIgSFaBxjArWSQTIJwgO0iq0ZUMUdC6ZtUQavm4ZPyc3hN-USbfaxoO986nv0xSoOUgi-k24Pkh9SzgMG-z3ErRv-LFC7z2PBHvPwf1IzVL4</recordid><startdate>19770301</startdate><enddate>19770301</enddate><creator>Murphy, D. 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W.</creatorcontrib><creatorcontrib>Trumbore, F. A.</creatorcontrib><creatorcontrib>Carides, J. N.</creatorcontrib><creatorcontrib>Bell Telephone Labs., Murray Hill, NJ</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>J. Electrochem. Soc.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Murphy, D. W.</au><au>Trumbore, F. A.</au><au>Carides, J. N.</au><aucorp>Bell Telephone Labs., Murray Hill, NJ</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A New Niobium Selenide Cathode for Nonaqueous Lithium Batteries</atitle><jtitle>J. Electrochem. Soc.; (United States)</jtitle><date>1977-03-01</date><risdate>1977</risdate><volume>124</volume><issue>3</issue><spage>325</spage><epage>329</epage><pages>325-329</pages><issn>0013-4651</issn><eissn>1945-7111</eissn><abstract>The ..gamma..-''NbSe/sub 4/'' phase, with a single phase composition range NbSe/sub 4/./sub 0/ to NbSe/sub 4/./sub 5/, is shown to behave as an electrochemically active, reversible cathode material in nonaqueous lithium cells. The cell data, together with the results of n-butyl lithium reaction studies, indicate a topotactic reaction to give an Li/sub 4/NbSe/sub 4 + x/ (x = 0 to 0.5) discharge product. Cycle data are presented for nonaqueous lithium cells with cathodes of either NbSe/sub 4/ containing small amounts of fibrous NbSe/sub 3/ or hot-pressed composites of NbSe/sub 4 + x/ with graphite and polyethylene. 9 figures.</abstract><cop>United States</cop><doi>10.1149/1.2133298</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0013-4651 |
| ispartof | J. Electrochem. Soc.; (United States), 1977-03, Vol.124 (3), p.325-329 |
| issn | 0013-4651 1945-7111 |
| language | eng |
| recordid | cdi_crossref_primary_10_1149_1_2133298 |
| source | IOP Publishing Journals |
| subjects | 250903 - Energy Storage- Batteries- Materials, Components, & Auxiliaries ALKALI METAL COMPOUNDS ALKALI METALS CARBONIC ACID ESTERS CATHODES CHALCOGENIDES CHEMICAL PREPARATION CHEMICAL REACTIONS CHLORATES CHLORINE COMPOUNDS ELECTRIC BATTERIES ELECTRIC POTENTIAL ELECTROCHEMICAL CELLS ELECTRODES ELEMENTS ENERGY STORAGE ENERGY STORAGE SYSTEMS ESTERS HALOGEN COMPOUNDS LITHIUM LITHIUM COMPOUNDS METAL-NONMETAL BATTERIES METALS NIOBIUM COMPOUNDS NIOBIUM SELENIDES ORGANIC COMPOUNDS OXYGEN COMPOUNDS SELENIDES SELENIUM COMPOUNDS SYNTHESIS TRANSITION ELEMENT COMPOUNDS |
| title | A New Niobium Selenide Cathode for Nonaqueous Lithium Batteries |
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