Corrosion Protection of Molten Carbonate Fuel Cell Gas Seals
Because the corrosion rates of metallic cell components in the gas seals of molten-carbonate fuel cells are a limiting factor in the useful lifetimes of such cells, Argonne National Laboratory conducted a study on ways of inhibiting corrosion at the cell-housing seals. The study showed that a lithiu...
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Veröffentlicht in: | J. Electrochem. Soc.; (United States) 1978-11, Vol.125 (11), p.1799-1800 |
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container_title | J. Electrochem. Soc.; (United States) |
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creator | Swaroop, R. B. Sim, J. W. Kinoshita, K. |
description | Because the corrosion rates of metallic cell components in the gas seals of molten-carbonate fuel cells are a limiting factor in the useful lifetimes of such cells, Argonne National Laboratory conducted a study on ways of inhibiting corrosion at the cell-housing seals. The study showed that a lithium aluminate coating on 316 stainless steel offers corrosion protection to metallic cell components susceptible to corrosive attack in a molten-carbonate fuel-cell environment, especially at the wet seal areas. Although the study describes the corrosion protection of only Type 316, Argonne expects that other stainless steels can be protected from corrosion by the application of an aluminized layer. Based on this experience, a further improvement for the corrosion protection of wet seals has been developed. Those areas of the cell housing covered by an aluminized coating have been increased to encompass the areas adjacent to the wet seal. This procedure presents the formation of a corrosion layer beneath the edge of the diffuse intermediate layer. |
doi_str_mv | 10.1149/1.2131297 |
format | Article |
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B. ; Sim, J. W. ; Kinoshita, K.</creator><creatorcontrib>Swaroop, R. B. ; Sim, J. W. ; Kinoshita, K.</creatorcontrib><description>Because the corrosion rates of metallic cell components in the gas seals of molten-carbonate fuel cells are a limiting factor in the useful lifetimes of such cells, Argonne National Laboratory conducted a study on ways of inhibiting corrosion at the cell-housing seals. The study showed that a lithium aluminate coating on 316 stainless steel offers corrosion protection to metallic cell components susceptible to corrosive attack in a molten-carbonate fuel-cell environment, especially at the wet seal areas. Although the study describes the corrosion protection of only Type 316, Argonne expects that other stainless steels can be protected from corrosion by the application of an aluminized layer. Based on this experience, a further improvement for the corrosion protection of wet seals has been developed. Those areas of the cell housing covered by an aluminized coating have been increased to encompass the areas adjacent to the wet seal. This procedure presents the formation of a corrosion layer beneath the edge of the diffuse intermediate layer.</description><identifier>ISSN: 0013-4651</identifier><identifier>EISSN: 1945-7111</identifier><identifier>DOI: 10.1149/1.2131297</identifier><language>eng</language><publisher>United States</publisher><subject>30 DIRECT ENERGY CONVERSION ; 300503 - Fuel Cells- Materials, Components, & Auxiliaries ; 360105 - Metals & Alloys- Corrosion & Erosion ; ALKALI METAL COMPOUNDS ; ALLOYS ; ALUMINATES ; ALUMINIUM COMPOUNDS ; CARBON COMPOUNDS ; CARBONATES ; CHROMIUM ALLOYS ; CHROMIUM STEELS ; CHROMIUM-NICKEL STEELS ; COATINGS ; CORROSION PROTECTION ; CORROSION RESISTANT ALLOYS ; DIRECT ENERGY CONVERTERS ; ELECTROCHEMICAL CELLS ; FUEL CELLS ; HEAT RESISTANT MATERIALS ; HEAT RESISTING ALLOYS ; HIGH-TEMPERATURE FUEL CELLS ; IRON ALLOYS ; IRON BASE ALLOYS ; LITHIUM COMPOUNDS ; MATERIALS ; MATERIALS SCIENCE ; MOLTEN CARBONATE FUEL CELLS ; MOLTEN SALTS ; MOLYBDENUM ALLOYS ; NICKEL ALLOYS ; OXYGEN COMPOUNDS ; SALTS ; SEALS ; STAINLESS STEEL-316 ; STAINLESS STEELS ; STEELS</subject><ispartof>J. 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Soc.; (United States)</title><description>Because the corrosion rates of metallic cell components in the gas seals of molten-carbonate fuel cells are a limiting factor in the useful lifetimes of such cells, Argonne National Laboratory conducted a study on ways of inhibiting corrosion at the cell-housing seals. The study showed that a lithium aluminate coating on 316 stainless steel offers corrosion protection to metallic cell components susceptible to corrosive attack in a molten-carbonate fuel-cell environment, especially at the wet seal areas. Although the study describes the corrosion protection of only Type 316, Argonne expects that other stainless steels can be protected from corrosion by the application of an aluminized layer. Based on this experience, a further improvement for the corrosion protection of wet seals has been developed. Those areas of the cell housing covered by an aluminized coating have been increased to encompass the areas adjacent to the wet seal. This procedure presents the formation of a corrosion layer beneath the edge of the diffuse intermediate layer.</description><subject>30 DIRECT ENERGY CONVERSION</subject><subject>300503 - Fuel Cells- Materials, Components, & Auxiliaries</subject><subject>360105 - Metals & Alloys- Corrosion & Erosion</subject><subject>ALKALI METAL COMPOUNDS</subject><subject>ALLOYS</subject><subject>ALUMINATES</subject><subject>ALUMINIUM COMPOUNDS</subject><subject>CARBON COMPOUNDS</subject><subject>CARBONATES</subject><subject>CHROMIUM ALLOYS</subject><subject>CHROMIUM STEELS</subject><subject>CHROMIUM-NICKEL STEELS</subject><subject>COATINGS</subject><subject>CORROSION PROTECTION</subject><subject>CORROSION RESISTANT ALLOYS</subject><subject>DIRECT ENERGY CONVERTERS</subject><subject>ELECTROCHEMICAL CELLS</subject><subject>FUEL CELLS</subject><subject>HEAT RESISTANT MATERIALS</subject><subject>HEAT RESISTING ALLOYS</subject><subject>HIGH-TEMPERATURE FUEL CELLS</subject><subject>IRON ALLOYS</subject><subject>IRON BASE ALLOYS</subject><subject>LITHIUM COMPOUNDS</subject><subject>MATERIALS</subject><subject>MATERIALS SCIENCE</subject><subject>MOLTEN CARBONATE FUEL CELLS</subject><subject>MOLTEN SALTS</subject><subject>MOLYBDENUM ALLOYS</subject><subject>NICKEL ALLOYS</subject><subject>OXYGEN COMPOUNDS</subject><subject>SALTS</subject><subject>SEALS</subject><subject>STAINLESS STEEL-316</subject><subject>STAINLESS STEELS</subject><subject>STEELS</subject><issn>0013-4651</issn><issn>1945-7111</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1978</creationdate><recordtype>article</recordtype><recordid>eNotUM1KxDAYDKLgunrwDYI3D13z5adtwIsUd1dYUVDPIU2-YqU2ksSDb2-W3dPMwDDMDCHXwFYAUt_BioMArpsTsgAtVdUAwClZMAaikrWCc3KR0leR0MpmQe67EGNIY5jpawwZXd7TMNDnMGWcaWdjH2abka5_caIdThPd2ETf0E7pkpwNBfDqiEvysX5877bV7mXz1D3sKieUypVDj9h7N0ihsBbIrKr14PRguW8lNKJ3WtTeMgWaeY22BdU3DAXnvuYWxZLcHHJDyqNJbiw9P12Y51LXKGibmvFiuj2YXNmTIg7mJ47fNv4ZYGb_jQFz_Eb8AytNVUc</recordid><startdate>19781101</startdate><enddate>19781101</enddate><creator>Swaroop, R. B.</creator><creator>Sim, J. W.</creator><creator>Kinoshita, K.</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19781101</creationdate><title>Corrosion Protection of Molten Carbonate Fuel Cell Gas Seals</title><author>Swaroop, R. B. ; Sim, J. W. ; Kinoshita, K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c355t-cedeebdcf435e63e0a569fc9fa2d84173bc936da05190d9ea815b70e322d62ae3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1978</creationdate><topic>30 DIRECT ENERGY CONVERSION</topic><topic>300503 - Fuel Cells- Materials, Components, & Auxiliaries</topic><topic>360105 - Metals & Alloys- Corrosion & Erosion</topic><topic>ALKALI METAL COMPOUNDS</topic><topic>ALLOYS</topic><topic>ALUMINATES</topic><topic>ALUMINIUM COMPOUNDS</topic><topic>CARBON COMPOUNDS</topic><topic>CARBONATES</topic><topic>CHROMIUM ALLOYS</topic><topic>CHROMIUM STEELS</topic><topic>CHROMIUM-NICKEL STEELS</topic><topic>COATINGS</topic><topic>CORROSION PROTECTION</topic><topic>CORROSION RESISTANT ALLOYS</topic><topic>DIRECT ENERGY CONVERTERS</topic><topic>ELECTROCHEMICAL CELLS</topic><topic>FUEL CELLS</topic><topic>HEAT RESISTANT MATERIALS</topic><topic>HEAT RESISTING ALLOYS</topic><topic>HIGH-TEMPERATURE FUEL CELLS</topic><topic>IRON ALLOYS</topic><topic>IRON BASE ALLOYS</topic><topic>LITHIUM COMPOUNDS</topic><topic>MATERIALS</topic><topic>MATERIALS SCIENCE</topic><topic>MOLTEN CARBONATE FUEL CELLS</topic><topic>MOLTEN SALTS</topic><topic>MOLYBDENUM ALLOYS</topic><topic>NICKEL ALLOYS</topic><topic>OXYGEN COMPOUNDS</topic><topic>SALTS</topic><topic>SEALS</topic><topic>STAINLESS STEEL-316</topic><topic>STAINLESS STEELS</topic><topic>STEELS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Swaroop, R. B.</creatorcontrib><creatorcontrib>Sim, J. W.</creatorcontrib><creatorcontrib>Kinoshita, K.</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>J. Electrochem. Soc.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Swaroop, R. B.</au><au>Sim, J. W.</au><au>Kinoshita, K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Corrosion Protection of Molten Carbonate Fuel Cell Gas Seals</atitle><jtitle>J. Electrochem. Soc.; (United States)</jtitle><date>1978-11-01</date><risdate>1978</risdate><volume>125</volume><issue>11</issue><spage>1799</spage><epage>1800</epage><pages>1799-1800</pages><issn>0013-4651</issn><eissn>1945-7111</eissn><abstract>Because the corrosion rates of metallic cell components in the gas seals of molten-carbonate fuel cells are a limiting factor in the useful lifetimes of such cells, Argonne National Laboratory conducted a study on ways of inhibiting corrosion at the cell-housing seals. The study showed that a lithium aluminate coating on 316 stainless steel offers corrosion protection to metallic cell components susceptible to corrosive attack in a molten-carbonate fuel-cell environment, especially at the wet seal areas. Although the study describes the corrosion protection of only Type 316, Argonne expects that other stainless steels can be protected from corrosion by the application of an aluminized layer. Based on this experience, a further improvement for the corrosion protection of wet seals has been developed. Those areas of the cell housing covered by an aluminized coating have been increased to encompass the areas adjacent to the wet seal. This procedure presents the formation of a corrosion layer beneath the edge of the diffuse intermediate layer.</abstract><cop>United States</cop><doi>10.1149/1.2131297</doi><tpages>2</tpages><oa>free_for_read</oa></addata></record> |
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issn | 0013-4651 1945-7111 |
language | eng |
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subjects | 30 DIRECT ENERGY CONVERSION 300503 - Fuel Cells- Materials, Components, & Auxiliaries 360105 - Metals & Alloys- Corrosion & Erosion ALKALI METAL COMPOUNDS ALLOYS ALUMINATES ALUMINIUM COMPOUNDS CARBON COMPOUNDS CARBONATES CHROMIUM ALLOYS CHROMIUM STEELS CHROMIUM-NICKEL STEELS COATINGS CORROSION PROTECTION CORROSION RESISTANT ALLOYS DIRECT ENERGY CONVERTERS ELECTROCHEMICAL CELLS FUEL CELLS HEAT RESISTANT MATERIALS HEAT RESISTING ALLOYS HIGH-TEMPERATURE FUEL CELLS IRON ALLOYS IRON BASE ALLOYS LITHIUM COMPOUNDS MATERIALS MATERIALS SCIENCE MOLTEN CARBONATE FUEL CELLS MOLTEN SALTS MOLYBDENUM ALLOYS NICKEL ALLOYS OXYGEN COMPOUNDS SALTS SEALS STAINLESS STEEL-316 STAINLESS STEELS STEELS |
title | Corrosion Protection of Molten Carbonate Fuel Cell Gas Seals |
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