Thin film cadmium chalcogenide/aqueous polysulfide photoelectrochemical solar cells with in-situ tin storage
A photoelectrical system is presented which converts solar energy to both electrical and electrochemically stored energy. A decrease in cell illumination initiates spontaneous reconversion of electrochemical to electrical energy, providing nearly constant (light insensitive) electrical power for an...
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| Veröffentlicht in: | J. Electrochem. Soc.; (United States) 1987-05, Vol.134 (5), p.1064-1070 |
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| container_end_page | 1070 |
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| container_issue | 5 |
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| container_title | J. Electrochem. Soc.; (United States) |
| container_volume | 134 |
| creator | LICHT, S MANASSEN, J |
| description | A photoelectrical system is presented which converts solar energy to both electrical and electrochemically stored energy. A decrease in cell illumination initiates spontaneous reconversion of electrochemical to electrical energy, providing nearly constant (light insensitive) electrical power for an external applied load. The cell contains a thin film CD(Se,Te) photoelectrode and a thin film CoS counterelectrode immersed in an aqueous polysulfide electrolyte separated by cation selective membrane from a tin electrode immersed in an aqueous sulfide electrolyte (Sn/S/sup =/). Cyclic voltammetry indicates that unlike tin/alkali systems, the Sn/S/sup =/ half-cell does not undergo passivation at storage potentials. |
| doi_str_mv | 10.1149/1.2100617 |
| format | Article |
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A decrease in cell illumination initiates spontaneous reconversion of electrochemical to electrical energy, providing nearly constant (light insensitive) electrical power for an external applied load. The cell contains a thin film CD(Se,Te) photoelectrode and a thin film CoS counterelectrode immersed in an aqueous polysulfide electrolyte separated by cation selective membrane from a tin electrode immersed in an aqueous sulfide electrolyte (Sn/S/sup =/). Cyclic voltammetry indicates that unlike tin/alkali systems, the Sn/S/sup =/ half-cell does not undergo passivation at storage potentials.</description><identifier>ISSN: 0013-4651</identifier><identifier>EISSN: 1945-7111</identifier><identifier>DOI: 10.1149/1.2100617</identifier><identifier>CODEN: JESOAN</identifier><language>eng</language><publisher>Pennington, NJ: Electrochemical Society</publisher><subject>140505 - Solar Energy Conversion- Photochemical, Photobiological, & Thermochemical Conversion- (1980-) ; 360603 - Materials- Properties ; 400400 - Electrochemistry ; 400500 - Photochemistry ; Applied sciences ; AQUEOUS SOLUTIONS ; CADMIUM COMPOUNDS ; CADMIUM SELENIDES ; CADMIUM TELLURIDES ; CHALCOGENIDES ; CHEMISTRY ; COBALT COMPOUNDS ; COBALT SULFIDES ; DISPERSIONS ; EFFICIENCY ; ELECTRICAL PROPERTIES ; ELECTROCHEMICAL CELLS ; ELECTROCHEMISTRY ; ELECTRODES ; ELECTROLYTES ; ELEMENTS ; ENERGY EFFICIENCY ; ENERGY LOSSES ; Exact sciences and technology ; FIELD TESTS ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; LOSSES ; MATERIALS SCIENCE ; METALS ; MIXTURES ; ORGANIC COMPOUNDS ; ORGANIC POLYMERS ; Other techniques and industries ; PHOTOCHEMISTRY ; PHOTOELECTROCHEMICAL CELLS ; PHYSICAL PROPERTIES ; POLYETHYLENES ; POLYMERS ; POLYOLEFINS ; SELENIDES ; SELENIUM COMPOUNDS ; SOLAR ENERGY ; SOLAR EQUIPMENT ; SOLUTIONS ; SULFIDES ; SULFUR COMPOUNDS ; TELLURIDES ; TELLURIUM COMPOUNDS ; TESTING ; THIN FILMS ; TIN ; TRANSITION ELEMENT COMPOUNDS ; VOLTAMETRY</subject><ispartof>J. 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Soc.; (United States), 1987-05, Vol.134 (5), p.1064-1070</ispartof><rights>1988 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c234t-f8950537934b4882306d8ed1e3cf20315ead52a9ccabadd025493785bde9cb283</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,881,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=7753579$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/6306791$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>LICHT, S</creatorcontrib><creatorcontrib>MANASSEN, J</creatorcontrib><creatorcontrib>Dept. of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139</creatorcontrib><title>Thin film cadmium chalcogenide/aqueous polysulfide photoelectrochemical solar cells with in-situ tin storage</title><title>J. Electrochem. Soc.; (United States)</title><description>A photoelectrical system is presented which converts solar energy to both electrical and electrochemically stored energy. A decrease in cell illumination initiates spontaneous reconversion of electrochemical to electrical energy, providing nearly constant (light insensitive) electrical power for an external applied load. The cell contains a thin film CD(Se,Te) photoelectrode and a thin film CoS counterelectrode immersed in an aqueous polysulfide electrolyte separated by cation selective membrane from a tin electrode immersed in an aqueous sulfide electrolyte (Sn/S/sup =/). Cyclic voltammetry indicates that unlike tin/alkali systems, the Sn/S/sup =/ half-cell does not undergo passivation at storage potentials.</description><subject>140505 - Solar Energy Conversion- Photochemical, Photobiological, & Thermochemical Conversion- (1980-)</subject><subject>360603 - Materials- Properties</subject><subject>400400 - Electrochemistry</subject><subject>400500 - Photochemistry</subject><subject>Applied sciences</subject><subject>AQUEOUS SOLUTIONS</subject><subject>CADMIUM COMPOUNDS</subject><subject>CADMIUM SELENIDES</subject><subject>CADMIUM TELLURIDES</subject><subject>CHALCOGENIDES</subject><subject>CHEMISTRY</subject><subject>COBALT COMPOUNDS</subject><subject>COBALT SULFIDES</subject><subject>DISPERSIONS</subject><subject>EFFICIENCY</subject><subject>ELECTRICAL PROPERTIES</subject><subject>ELECTROCHEMICAL CELLS</subject><subject>ELECTROCHEMISTRY</subject><subject>ELECTRODES</subject><subject>ELECTROLYTES</subject><subject>ELEMENTS</subject><subject>ENERGY EFFICIENCY</subject><subject>ENERGY LOSSES</subject><subject>Exact sciences and technology</subject><subject>FIELD TESTS</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>LOSSES</subject><subject>MATERIALS SCIENCE</subject><subject>METALS</subject><subject>MIXTURES</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANIC POLYMERS</subject><subject>Other techniques and industries</subject><subject>PHOTOCHEMISTRY</subject><subject>PHOTOELECTROCHEMICAL CELLS</subject><subject>PHYSICAL PROPERTIES</subject><subject>POLYETHYLENES</subject><subject>POLYMERS</subject><subject>POLYOLEFINS</subject><subject>SELENIDES</subject><subject>SELENIUM COMPOUNDS</subject><subject>SOLAR ENERGY</subject><subject>SOLAR EQUIPMENT</subject><subject>SOLUTIONS</subject><subject>SULFIDES</subject><subject>SULFUR COMPOUNDS</subject><subject>TELLURIDES</subject><subject>TELLURIUM COMPOUNDS</subject><subject>TESTING</subject><subject>THIN FILMS</subject><subject>TIN</subject><subject>TRANSITION ELEMENT COMPOUNDS</subject><subject>VOLTAMETRY</subject><issn>0013-4651</issn><issn>1945-7111</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1987</creationdate><recordtype>article</recordtype><recordid>eNo9kEtrwzAQhEVpoenj0H8gSi89ONFakmUfS-gLAr2kZyNLcqwiW6kkU_Lvq5LQ07DLt8PsIHQHZAnAmhUsSyCkAnGGFtAwXggAOEcLQoAWrOJwia5i_Moj1EwskNsOdsK9dSNWUo92zjpIp_zOTFablfyejZ8j3nt3iLPr8w7vB5-8cUal4NVgRqukw9E7GbAyzkX8Y9OA7VREm2acsn9MPsiduUEXvXTR3J70Gn2-PG_Xb8Xm4_V9_bQpVElZKvq64YRT0VDWsbouKal0bTQYqvqSUOBGal7KRinZSa1JyVlDRc07bRrVlTW9RvdHXx-TbaOyyahB-WnKkdsq24kGMvR4hFTwMQbTt_tgRxkOLZD2r8sW2lOXmX04snsZ87N9kJOy8f9ACE55jvsLyfl0sA</recordid><startdate>19870501</startdate><enddate>19870501</enddate><creator>LICHT, S</creator><creator>MANASSEN, J</creator><general>Electrochemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19870501</creationdate><title>Thin film cadmium chalcogenide/aqueous polysulfide photoelectrochemical solar cells with in-situ tin storage</title><author>LICHT, S ; MANASSEN, J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c234t-f8950537934b4882306d8ed1e3cf20315ead52a9ccabadd025493785bde9cb283</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1987</creationdate><topic>140505 - Solar Energy Conversion- Photochemical, Photobiological, & Thermochemical Conversion- (1980-)</topic><topic>360603 - Materials- Properties</topic><topic>400400 - Electrochemistry</topic><topic>400500 - Photochemistry</topic><topic>Applied sciences</topic><topic>AQUEOUS SOLUTIONS</topic><topic>CADMIUM COMPOUNDS</topic><topic>CADMIUM SELENIDES</topic><topic>CADMIUM TELLURIDES</topic><topic>CHALCOGENIDES</topic><topic>CHEMISTRY</topic><topic>COBALT COMPOUNDS</topic><topic>COBALT SULFIDES</topic><topic>DISPERSIONS</topic><topic>EFFICIENCY</topic><topic>ELECTRICAL PROPERTIES</topic><topic>ELECTROCHEMICAL CELLS</topic><topic>ELECTROCHEMISTRY</topic><topic>ELECTRODES</topic><topic>ELECTROLYTES</topic><topic>ELEMENTS</topic><topic>ENERGY EFFICIENCY</topic><topic>ENERGY LOSSES</topic><topic>Exact sciences and technology</topic><topic>FIELD TESTS</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>LOSSES</topic><topic>MATERIALS SCIENCE</topic><topic>METALS</topic><topic>MIXTURES</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANIC POLYMERS</topic><topic>Other techniques and industries</topic><topic>PHOTOCHEMISTRY</topic><topic>PHOTOELECTROCHEMICAL CELLS</topic><topic>PHYSICAL PROPERTIES</topic><topic>POLYETHYLENES</topic><topic>POLYMERS</topic><topic>POLYOLEFINS</topic><topic>SELENIDES</topic><topic>SELENIUM COMPOUNDS</topic><topic>SOLAR ENERGY</topic><topic>SOLAR EQUIPMENT</topic><topic>SOLUTIONS</topic><topic>SULFIDES</topic><topic>SULFUR COMPOUNDS</topic><topic>TELLURIDES</topic><topic>TELLURIUM COMPOUNDS</topic><topic>TESTING</topic><topic>THIN FILMS</topic><topic>TIN</topic><topic>TRANSITION ELEMENT COMPOUNDS</topic><topic>VOLTAMETRY</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>LICHT, S</creatorcontrib><creatorcontrib>MANASSEN, J</creatorcontrib><creatorcontrib>Dept. of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>J. Electrochem. Soc.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>LICHT, S</au><au>MANASSEN, J</au><aucorp>Dept. of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thin film cadmium chalcogenide/aqueous polysulfide photoelectrochemical solar cells with in-situ tin storage</atitle><jtitle>J. Electrochem. Soc.; (United States)</jtitle><date>1987-05-01</date><risdate>1987</risdate><volume>134</volume><issue>5</issue><spage>1064</spage><epage>1070</epage><pages>1064-1070</pages><issn>0013-4651</issn><eissn>1945-7111</eissn><coden>JESOAN</coden><abstract>A photoelectrical system is presented which converts solar energy to both electrical and electrochemically stored energy. A decrease in cell illumination initiates spontaneous reconversion of electrochemical to electrical energy, providing nearly constant (light insensitive) electrical power for an external applied load. The cell contains a thin film CD(Se,Te) photoelectrode and a thin film CoS counterelectrode immersed in an aqueous polysulfide electrolyte separated by cation selective membrane from a tin electrode immersed in an aqueous sulfide electrolyte (Sn/S/sup =/). Cyclic voltammetry indicates that unlike tin/alkali systems, the Sn/S/sup =/ half-cell does not undergo passivation at storage potentials.</abstract><cop>Pennington, NJ</cop><pub>Electrochemical Society</pub><doi>10.1149/1.2100617</doi><tpages>7</tpages></addata></record> |
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| identifier | ISSN: 0013-4651 |
| ispartof | J. Electrochem. Soc.; (United States), 1987-05, Vol.134 (5), p.1064-1070 |
| issn | 0013-4651 1945-7111 |
| language | eng |
| recordid | cdi_crossref_primary_10_1149_1_2100617 |
| source | IOP Publishing Journals |
| subjects | 140505 - Solar Energy Conversion- Photochemical, Photobiological, & Thermochemical Conversion- (1980-) 360603 - Materials- Properties 400400 - Electrochemistry 400500 - Photochemistry Applied sciences AQUEOUS SOLUTIONS CADMIUM COMPOUNDS CADMIUM SELENIDES CADMIUM TELLURIDES CHALCOGENIDES CHEMISTRY COBALT COMPOUNDS COBALT SULFIDES DISPERSIONS EFFICIENCY ELECTRICAL PROPERTIES ELECTROCHEMICAL CELLS ELECTROCHEMISTRY ELECTRODES ELECTROLYTES ELEMENTS ENERGY EFFICIENCY ENERGY LOSSES Exact sciences and technology FIELD TESTS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY LOSSES MATERIALS SCIENCE METALS MIXTURES ORGANIC COMPOUNDS ORGANIC POLYMERS Other techniques and industries PHOTOCHEMISTRY PHOTOELECTROCHEMICAL CELLS PHYSICAL PROPERTIES POLYETHYLENES POLYMERS POLYOLEFINS SELENIDES SELENIUM COMPOUNDS SOLAR ENERGY SOLAR EQUIPMENT SOLUTIONS SULFIDES SULFUR COMPOUNDS TELLURIDES TELLURIUM COMPOUNDS TESTING THIN FILMS TIN TRANSITION ELEMENT COMPOUNDS VOLTAMETRY |
| title | Thin film cadmium chalcogenide/aqueous polysulfide photoelectrochemical solar cells with in-situ tin storage |
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