A mathematical model of a zinc/bromine flow cell

A mathematical model is presented for a zinc/bromine flow cell. The model includes a thin porous layer on the bromine electrode and a porous separator. The independent parameters of the porous layer are defined, and their effect on cell performance during charge and discharge is investigated. The de...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:J. Electrochem. Soc.; (United States) 1987-04, Vol.134 (4), p.866-874
Hauptverfasser: EVANS, T. I, WHITE, R. E
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 874
container_issue 4
container_start_page 866
container_title J. Electrochem. Soc.; (United States)
container_volume 134
creator EVANS, T. I
WHITE, R. E
description A mathematical model is presented for a zinc/bromine flow cell. The model includes a thin porous layer on the bromine electrode and a porous separator. The independent parameters of the porous layer are defined, and their effect on cell performance during charge and discharge is investigated. The dependence of the round trip energy efficiency on the thickness of the porous layer and mode of discharge is presented. The predictions of the model show that a maximum round trip energy efficiency of 70% should be possible under the design conditions considered.
doi_str_mv 10.1149/1.2100588
format Article
fullrecord <record><control><sourceid>pascalfrancis_osti_</sourceid><recordid>TN_cdi_crossref_primary_10_1149_1_2100588</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>7470982</sourcerecordid><originalsourceid>FETCH-LOGICAL-c318t-5f3ed1cdfb251f87ea6c0f13641a0b7b479d5982a335c091896518d4ba1b7e303</originalsourceid><addsrcrecordid>eNo9kE9LxDAQxYMoWFcPfoMgXjx0N9MkTXpcFv_Bghc9h3SasJG2WZqC6Kc30sXLPAZ-83jzCLkFtgYQzQbWFTAmtT4jBTRClgoAzknBGPBS1BIuyVVKn3kFLVRB2JYOdj64PALang6xcz2Nnlr6E0bctFMcwuio7-MXRdf31-TC2z65m5OuyMfT4_vupdy_Pb_utvsSOei5lJ67DrDzbSXBa-VsjcwDrwVY1qpWqKaTja4s5xJZA7rJ2XQnWgutcpzxFblbfGOag0kYZocHjOPocDaZVaB5hh4WCKeY0uS8OU5hsNO3AWb--jBgTn1k9n5hjzblT_1kRwzp_0AJxXIe_gsKpVxD</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>A mathematical model of a zinc/bromine flow cell</title><source>Institute of Physics Journals</source><creator>EVANS, T. I ; WHITE, R. E</creator><creatorcontrib>EVANS, T. I ; WHITE, R. E ; Dept. of Chemical Engineering, Texas A and M Univ., College Station, TX 77843</creatorcontrib><description>A mathematical model is presented for a zinc/bromine flow cell. The model includes a thin porous layer on the bromine electrode and a porous separator. The independent parameters of the porous layer are defined, and their effect on cell performance during charge and discharge is investigated. The dependence of the round trip energy efficiency on the thickness of the porous layer and mode of discharge is presented. The predictions of the model show that a maximum round trip energy efficiency of 70% should be possible under the design conditions considered.</description><identifier>ISSN: 0013-4651</identifier><identifier>EISSN: 1945-7111</identifier><identifier>DOI: 10.1149/1.2100588</identifier><identifier>CODEN: JESOAN</identifier><language>eng</language><publisher>Pennington, NJ: Electrochemical Society</publisher><subject>250902 - Energy Storage- Batteries- Performance &amp; Testing ; 250903 - Energy Storage- Batteries- Materials, Components, &amp; Auxiliaries ; Applied sciences ; BATTERY SEPARATORS ; DESIGN ; DIMENSIONS ; Direct energy conversion and energy accumulation ; EFFICIENCY ; ELECTRIC BATTERIES ; ELECTRIC CHARGES ; ELECTRIC DISCHARGES ; Electrical engineering. Electrical power engineering ; Electrical power engineering ; ELECTROCHEMICAL CELLS ; Electrochemical conversion: primary and secondary batteries, fuel cells ; ELECTRODES ; ENERGY EFFICIENCY ; ENERGY STORAGE ; Exact sciences and technology ; LAYERS ; MATHEMATICAL MODELS ; METAL-NONMETAL BATTERIES ; POROSITY ; THICKNESS ; ZINC-BROMINE BATTERIES</subject><ispartof>J. Electrochem. Soc.; (United States), 1987-04, Vol.134 (4), p.866-874</ispartof><rights>1988 INIST-CNRS</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c318t-5f3ed1cdfb251f87ea6c0f13641a0b7b479d5982a335c091896518d4ba1b7e303</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=7470982$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/6517183$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>EVANS, T. I</creatorcontrib><creatorcontrib>WHITE, R. E</creatorcontrib><creatorcontrib>Dept. of Chemical Engineering, Texas A and M Univ., College Station, TX 77843</creatorcontrib><title>A mathematical model of a zinc/bromine flow cell</title><title>J. Electrochem. Soc.; (United States)</title><description>A mathematical model is presented for a zinc/bromine flow cell. The model includes a thin porous layer on the bromine electrode and a porous separator. The independent parameters of the porous layer are defined, and their effect on cell performance during charge and discharge is investigated. The dependence of the round trip energy efficiency on the thickness of the porous layer and mode of discharge is presented. The predictions of the model show that a maximum round trip energy efficiency of 70% should be possible under the design conditions considered.</description><subject>250902 - Energy Storage- Batteries- Performance &amp; Testing</subject><subject>250903 - Energy Storage- Batteries- Materials, Components, &amp; Auxiliaries</subject><subject>Applied sciences</subject><subject>BATTERY SEPARATORS</subject><subject>DESIGN</subject><subject>DIMENSIONS</subject><subject>Direct energy conversion and energy accumulation</subject><subject>EFFICIENCY</subject><subject>ELECTRIC BATTERIES</subject><subject>ELECTRIC CHARGES</subject><subject>ELECTRIC DISCHARGES</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>ELECTROCHEMICAL CELLS</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>ELECTRODES</subject><subject>ENERGY EFFICIENCY</subject><subject>ENERGY STORAGE</subject><subject>Exact sciences and technology</subject><subject>LAYERS</subject><subject>MATHEMATICAL MODELS</subject><subject>METAL-NONMETAL BATTERIES</subject><subject>POROSITY</subject><subject>THICKNESS</subject><subject>ZINC-BROMINE BATTERIES</subject><issn>0013-4651</issn><issn>1945-7111</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1987</creationdate><recordtype>article</recordtype><recordid>eNo9kE9LxDAQxYMoWFcPfoMgXjx0N9MkTXpcFv_Bghc9h3SasJG2WZqC6Kc30sXLPAZ-83jzCLkFtgYQzQbWFTAmtT4jBTRClgoAzknBGPBS1BIuyVVKn3kFLVRB2JYOdj64PALang6xcz2Nnlr6E0bctFMcwuio7-MXRdf31-TC2z65m5OuyMfT4_vupdy_Pb_utvsSOei5lJ67DrDzbSXBa-VsjcwDrwVY1qpWqKaTja4s5xJZA7rJ2XQnWgutcpzxFblbfGOag0kYZocHjOPocDaZVaB5hh4WCKeY0uS8OU5hsNO3AWb--jBgTn1k9n5hjzblT_1kRwzp_0AJxXIe_gsKpVxD</recordid><startdate>19870401</startdate><enddate>19870401</enddate><creator>EVANS, T. I</creator><creator>WHITE, R. E</creator><general>Electrochemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19870401</creationdate><title>A mathematical model of a zinc/bromine flow cell</title><author>EVANS, T. I ; WHITE, R. E</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c318t-5f3ed1cdfb251f87ea6c0f13641a0b7b479d5982a335c091896518d4ba1b7e303</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1987</creationdate><topic>250902 - Energy Storage- Batteries- Performance &amp; Testing</topic><topic>250903 - Energy Storage- Batteries- Materials, Components, &amp; Auxiliaries</topic><topic>Applied sciences</topic><topic>BATTERY SEPARATORS</topic><topic>DESIGN</topic><topic>DIMENSIONS</topic><topic>Direct energy conversion and energy accumulation</topic><topic>EFFICIENCY</topic><topic>ELECTRIC BATTERIES</topic><topic>ELECTRIC CHARGES</topic><topic>ELECTRIC DISCHARGES</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>ELECTROCHEMICAL CELLS</topic><topic>Electrochemical conversion: primary and secondary batteries, fuel cells</topic><topic>ELECTRODES</topic><topic>ENERGY EFFICIENCY</topic><topic>ENERGY STORAGE</topic><topic>Exact sciences and technology</topic><topic>LAYERS</topic><topic>MATHEMATICAL MODELS</topic><topic>METAL-NONMETAL BATTERIES</topic><topic>POROSITY</topic><topic>THICKNESS</topic><topic>ZINC-BROMINE BATTERIES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>EVANS, T. I</creatorcontrib><creatorcontrib>WHITE, R. E</creatorcontrib><creatorcontrib>Dept. of Chemical Engineering, Texas A and M Univ., College Station, TX 77843</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>J. Electrochem. Soc.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>EVANS, T. I</au><au>WHITE, R. E</au><aucorp>Dept. of Chemical Engineering, Texas A and M Univ., College Station, TX 77843</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A mathematical model of a zinc/bromine flow cell</atitle><jtitle>J. Electrochem. Soc.; (United States)</jtitle><date>1987-04-01</date><risdate>1987</risdate><volume>134</volume><issue>4</issue><spage>866</spage><epage>874</epage><pages>866-874</pages><issn>0013-4651</issn><eissn>1945-7111</eissn><coden>JESOAN</coden><abstract>A mathematical model is presented for a zinc/bromine flow cell. The model includes a thin porous layer on the bromine electrode and a porous separator. The independent parameters of the porous layer are defined, and their effect on cell performance during charge and discharge is investigated. The dependence of the round trip energy efficiency on the thickness of the porous layer and mode of discharge is presented. The predictions of the model show that a maximum round trip energy efficiency of 70% should be possible under the design conditions considered.</abstract><cop>Pennington, NJ</cop><pub>Electrochemical Society</pub><doi>10.1149/1.2100588</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0013-4651
ispartof J. Electrochem. Soc.; (United States), 1987-04, Vol.134 (4), p.866-874
issn 0013-4651
1945-7111
language eng
recordid cdi_crossref_primary_10_1149_1_2100588
source Institute of Physics Journals
subjects 250902 - Energy Storage- Batteries- Performance & Testing
250903 - Energy Storage- Batteries- Materials, Components, & Auxiliaries
Applied sciences
BATTERY SEPARATORS
DESIGN
DIMENSIONS
Direct energy conversion and energy accumulation
EFFICIENCY
ELECTRIC BATTERIES
ELECTRIC CHARGES
ELECTRIC DISCHARGES
Electrical engineering. Electrical power engineering
Electrical power engineering
ELECTROCHEMICAL CELLS
Electrochemical conversion: primary and secondary batteries, fuel cells
ELECTRODES
ENERGY EFFICIENCY
ENERGY STORAGE
Exact sciences and technology
LAYERS
MATHEMATICAL MODELS
METAL-NONMETAL BATTERIES
POROSITY
THICKNESS
ZINC-BROMINE BATTERIES
title A mathematical model of a zinc/bromine flow cell
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-07T07%3A49%3A03IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pascalfrancis_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20mathematical%20model%20of%20a%20zinc/bromine%20flow%20cell&rft.jtitle=J.%20Electrochem.%20Soc.;%20(United%20States)&rft.au=EVANS,%20T.%20I&rft.aucorp=Dept.%20of%20Chemical%20Engineering,%20Texas%20A%20and%20M%20Univ.,%20College%20Station,%20TX%2077843&rft.date=1987-04-01&rft.volume=134&rft.issue=4&rft.spage=866&rft.epage=874&rft.pages=866-874&rft.issn=0013-4651&rft.eissn=1945-7111&rft.coden=JESOAN&rft_id=info:doi/10.1149/1.2100588&rft_dat=%3Cpascalfrancis_osti_%3E7470982%3C/pascalfrancis_osti_%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true