Polymer electrolytes reinforced by Celgard® membranes
Solid polymer electrolytes have been prepared by encapsulating plasticized polymer electrolytes based on poly(tetraethylene glycol diacrylate) into the pores of Celgard{reg_sign} microporous membranes. Electrolyte membranes with thicknesses of {approximately}40 {mu}m have been prepared. The conducti...
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| Veröffentlicht in: | Journal of the Electrochemical Society 1995-03, Vol.142 (3), p.683-687 |
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| container_end_page | 687 |
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| container_issue | 3 |
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| container_title | Journal of the Electrochemical Society |
| container_volume | 142 |
| creator | ABRAHAM, K. M ALAMGIR, M HOFFMAN, D. K |
| description | Solid polymer electrolytes have been prepared by encapsulating plasticized polymer electrolytes based on poly(tetraethylene glycol diacrylate) into the pores of Celgard{reg_sign} microporous membranes. Electrolyte membranes with thicknesses of {approximately}40 {mu}m have been prepared. The conductivity of the electrolyte is determined by the porosity of the membrane, and a conductivity of {approximately}2 {times} 10{sup {minus}4} {Omega}{sup {minus}1} {center_dot} cm{sup {minus}1} at room temperature has been demonstrated. These electrolytes showed good compatibility with Li and an electrochemical stability window spanning the range of 0.0 to {approximately}4.5 V vs. Li{sup +}/Li. The excellent chemical and electrochemical stabilities enabling the use of the membranes in rechargeable Li batteries have been confirmed by the discharge/charge cycling of Li/solid polymer electrolyte/LiMn{sub 2}O{sub 4} cells at room temperature. |
| doi_str_mv | 10.1149/1.2048517 |
| format | Article |
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The excellent chemical and electrochemical stabilities enabling the use of the membranes in rechargeable Li batteries have been confirmed by the discharge/charge cycling of Li/solid polymer electrolyte/LiMn{sub 2}O{sub 4} cells at room temperature.</description><identifier>ISSN: 0013-4651</identifier><identifier>EISSN: 1945-7111</identifier><identifier>DOI: 10.1149/1.2048517</identifier><identifier>CODEN: JESOAN</identifier><language>eng</language><publisher>Pennington, NJ: Electrochemical Society</publisher><subject>Applied sciences ; BATTERY CHARGING ; ELECTRIC BATTERIES ; ENERGY STORAGE ; Exact sciences and technology ; LITHIUM ; LITHIUM COMPOUNDS ; MANGANATES ; MEMBRANES ; ORGANIC POLYMERS ; Physicochemistry of polymers ; Polymerization ; Polymers and radiations ; SOLID ELECTROLYTES ; VOLTAGE DROP</subject><ispartof>Journal of the Electrochemical Society, 1995-03, Vol.142 (3), p.683-687</ispartof><rights>1995 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c255t-d469d08b33b7817868a6e91a8d5a50e06e4abeee88465ce7de26c3bc651a6eb93</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,881,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=3480086$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/40300$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>ABRAHAM, K. M</creatorcontrib><creatorcontrib>ALAMGIR, M</creatorcontrib><creatorcontrib>HOFFMAN, D. K</creatorcontrib><title>Polymer electrolytes reinforced by Celgard® membranes</title><title>Journal of the Electrochemical Society</title><description>Solid polymer electrolytes have been prepared by encapsulating plasticized polymer electrolytes based on poly(tetraethylene glycol diacrylate) into the pores of Celgard{reg_sign} microporous membranes. Electrolyte membranes with thicknesses of {approximately}40 {mu}m have been prepared. The conductivity of the electrolyte is determined by the porosity of the membrane, and a conductivity of {approximately}2 {times} 10{sup {minus}4} {Omega}{sup {minus}1} {center_dot} cm{sup {minus}1} at room temperature has been demonstrated. These electrolytes showed good compatibility with Li and an electrochemical stability window spanning the range of 0.0 to {approximately}4.5 V vs. Li{sup +}/Li. The excellent chemical and electrochemical stabilities enabling the use of the membranes in rechargeable Li batteries have been confirmed by the discharge/charge cycling of Li/solid polymer electrolyte/LiMn{sub 2}O{sub 4} cells at room temperature.</description><subject>Applied sciences</subject><subject>BATTERY CHARGING</subject><subject>ELECTRIC BATTERIES</subject><subject>ENERGY STORAGE</subject><subject>Exact sciences and technology</subject><subject>LITHIUM</subject><subject>LITHIUM COMPOUNDS</subject><subject>MANGANATES</subject><subject>MEMBRANES</subject><subject>ORGANIC POLYMERS</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Polymers and radiations</subject><subject>SOLID ELECTROLYTES</subject><subject>VOLTAGE DROP</subject><issn>0013-4651</issn><issn>1945-7111</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1995</creationdate><recordtype>article</recordtype><recordid>eNo9kLtOxDAQRS0EEmGh4A9S0FBkmYkfcUq0ggVpJSigtmxnAkF5rOw0-Sk-gi_DaFdUoyudGZ25jF0jrBFFfYfrEoSWWJ2wDGshiwoRT1kGgLwQSuI5u4jxK0XUosqYep36ZaCQU09-DinMFPNA3dhOwVOTuyXfUP9hQ_PznQ80uGBHipfsrLV9pKvjXLH3x4e3zVOxe9k-b-53hS-lnItGqLoB7Th3lcZKK20V1Wh1I60EAkXCOiLSOql5qhoqlefOJ88EupqvWH64O8W5M9F3M_lPP41jkjUCOEBCbg-ID1OMgVqzD91gw2IQzF8nBs2xk8TeHNi9jd72bfrFd_F_gQsNoBX_BQPRYH8</recordid><startdate>19950301</startdate><enddate>19950301</enddate><creator>ABRAHAM, K. 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K</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c255t-d469d08b33b7817868a6e91a8d5a50e06e4abeee88465ce7de26c3bc651a6eb93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1995</creationdate><topic>Applied sciences</topic><topic>BATTERY CHARGING</topic><topic>ELECTRIC BATTERIES</topic><topic>ENERGY STORAGE</topic><topic>Exact sciences and technology</topic><topic>LITHIUM</topic><topic>LITHIUM COMPOUNDS</topic><topic>MANGANATES</topic><topic>MEMBRANES</topic><topic>ORGANIC POLYMERS</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>Polymers and radiations</topic><topic>SOLID ELECTROLYTES</topic><topic>VOLTAGE DROP</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>ABRAHAM, K. M</creatorcontrib><creatorcontrib>ALAMGIR, M</creatorcontrib><creatorcontrib>HOFFMAN, D. K</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Journal of the Electrochemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>ABRAHAM, K. M</au><au>ALAMGIR, M</au><au>HOFFMAN, D. K</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polymer electrolytes reinforced by Celgard® membranes</atitle><jtitle>Journal of the Electrochemical Society</jtitle><date>1995-03-01</date><risdate>1995</risdate><volume>142</volume><issue>3</issue><spage>683</spage><epage>687</epage><pages>683-687</pages><issn>0013-4651</issn><eissn>1945-7111</eissn><coden>JESOAN</coden><abstract>Solid polymer electrolytes have been prepared by encapsulating plasticized polymer electrolytes based on poly(tetraethylene glycol diacrylate) into the pores of Celgard{reg_sign} microporous membranes. Electrolyte membranes with thicknesses of {approximately}40 {mu}m have been prepared. The conductivity of the electrolyte is determined by the porosity of the membrane, and a conductivity of {approximately}2 {times} 10{sup {minus}4} {Omega}{sup {minus}1} {center_dot} cm{sup {minus}1} at room temperature has been demonstrated. These electrolytes showed good compatibility with Li and an electrochemical stability window spanning the range of 0.0 to {approximately}4.5 V vs. Li{sup +}/Li. The excellent chemical and electrochemical stabilities enabling the use of the membranes in rechargeable Li batteries have been confirmed by the discharge/charge cycling of Li/solid polymer electrolyte/LiMn{sub 2}O{sub 4} cells at room temperature.</abstract><cop>Pennington, NJ</cop><pub>Electrochemical Society</pub><doi>10.1149/1.2048517</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0013-4651 |
| ispartof | Journal of the Electrochemical Society, 1995-03, Vol.142 (3), p.683-687 |
| issn | 0013-4651 1945-7111 |
| language | eng |
| recordid | cdi_crossref_primary_10_1149_1_2048517 |
| source | IOP Publishing Journals |
| subjects | Applied sciences BATTERY CHARGING ELECTRIC BATTERIES ENERGY STORAGE Exact sciences and technology LITHIUM LITHIUM COMPOUNDS MANGANATES MEMBRANES ORGANIC POLYMERS Physicochemistry of polymers Polymerization Polymers and radiations SOLID ELECTROLYTES VOLTAGE DROP |
| title | Polymer electrolytes reinforced by Celgard® membranes |
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