Rechargeable lithium and sodium anodes in chloroaluminate molten salts containing thionyl chloride
Lithium and sodium deposition-stripping studies were performed in room temperature buffered neutral chloroaluminate melts containing low concentrations of thionyl chloride (SOCl{sub 2}). The SOCl{sub 2} solute promotes high cycling efficiencies of the alkali metals in these electrolytes. Staircase c...
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| Veröffentlicht in: | Journal of the Electrochemical Society 1995-11, Vol.142 (11), p.3632-3636 |
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| container_end_page | 3636 |
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| container_issue | 11 |
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| container_title | Journal of the Electrochemical Society |
| container_volume | 142 |
| creator | FULLER, J OSTERYOUNG, R. A CARLIN, R. T |
| description | Lithium and sodium deposition-stripping studies were performed in room temperature buffered neutral chloroaluminate melts containing low concentrations of thionyl chloride (SOCl{sub 2}). The SOCl{sub 2} solute promotes high cycling efficiencies of the alkali metals in these electrolytes. Staircase cyclic voltammetry and chronopotentiometry show cycling efficiencies of approximately 90% for both lithium and sodium. High cycling efficiencies are maintained following extended exposure of the melt to the dry box atmosphere and after time delays at open circuit. The performance of the SOCl{sub 2}-promoted systems is substantially improved over previous studies in room temperature melts containing hydrogen chloride as the promoting solute. |
| doi_str_mv | 10.1149/1.2048390 |
| format | Article |
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A ; CARLIN, R. T</creator><creatorcontrib>FULLER, J ; OSTERYOUNG, R. A ; CARLIN, R. T</creatorcontrib><description>Lithium and sodium deposition-stripping studies were performed in room temperature buffered neutral chloroaluminate melts containing low concentrations of thionyl chloride (SOCl{sub 2}). The SOCl{sub 2} solute promotes high cycling efficiencies of the alkali metals in these electrolytes. Staircase cyclic voltammetry and chronopotentiometry show cycling efficiencies of approximately 90% for both lithium and sodium. High cycling efficiencies are maintained following extended exposure of the melt to the dry box atmosphere and after time delays at open circuit. The performance of the SOCl{sub 2}-promoted systems is substantially improved over previous studies in room temperature melts containing hydrogen chloride as the promoting solute.</description><identifier>ISSN: 0013-4651</identifier><identifier>EISSN: 1945-7111</identifier><identifier>DOI: 10.1149/1.2048390</identifier><identifier>CODEN: JESOAN</identifier><language>eng</language><publisher>Pennington, NJ: Electrochemical Society</publisher><subject>ALUMINIUM CHLORIDES ; Applied sciences ; BATTERY CHARGING ; Direct energy conversion and energy accumulation ; Electrical engineering. 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A</creatorcontrib><creatorcontrib>CARLIN, R. T</creatorcontrib><title>Rechargeable lithium and sodium anodes in chloroaluminate molten salts containing thionyl chloride</title><title>Journal of the Electrochemical Society</title><description>Lithium and sodium deposition-stripping studies were performed in room temperature buffered neutral chloroaluminate melts containing low concentrations of thionyl chloride (SOCl{sub 2}). The SOCl{sub 2} solute promotes high cycling efficiencies of the alkali metals in these electrolytes. Staircase cyclic voltammetry and chronopotentiometry show cycling efficiencies of approximately 90% for both lithium and sodium. High cycling efficiencies are maintained following extended exposure of the melt to the dry box atmosphere and after time delays at open circuit. The performance of the SOCl{sub 2}-promoted systems is substantially improved over previous studies in room temperature melts containing hydrogen chloride as the promoting solute.</description><subject>ALUMINIUM CHLORIDES</subject><subject>Applied sciences</subject><subject>BATTERY CHARGING</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>ENERGY EFFICIENCY</subject><subject>ENERGY STORAGE</subject><subject>Exact sciences and technology</subject><subject>LITHIUM-SULFUR BATTERIES</subject><subject>SODIUM-SULFUR BATTERIES</subject><subject>STABILITY</subject><subject>THIONYL CHLORIDES</subject><issn>0013-4651</issn><issn>1945-7111</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1995</creationdate><recordtype>article</recordtype><recordid>eNo9kEtLAzEUhYMoWKsL_0EENy6m5k4ynWQpxRcUBNH1kEnutJE0KZN00X9vZIqb-4DvHs49hNwCWwAI9QiLmgnJFTsjM1CiqVoAOCczxoBXYtnAJblK6aesIEU7I_0nmq0eN6h7j9S7vHWHHdXB0hTtNEaLibpAzdbHMWp_2LmgM9Jd9BkDTdrnRE0MWbvgwoYWiRiOfuKdxWtyMWif8ObU5-T75flr9VatP17fV0_rynAhc6UGrJvWMF1Ka3vGrFKNFQP2HFFbVfOB94gNa3stmeamKSC0PQJjS15LPid3k25M2XXJuFxeK74CmtxBw5eSFeZhYswYUxpx6Paj2-nx2AHr_gLsoDsFWNj7id3rZLQfRh2MS_8HtWKilpL_Ane0cSE</recordid><startdate>19951101</startdate><enddate>19951101</enddate><creator>FULLER, J</creator><creator>OSTERYOUNG, R. A</creator><creator>CARLIN, R. T</creator><general>Electrochemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19951101</creationdate><title>Rechargeable lithium and sodium anodes in chloroaluminate molten salts containing thionyl chloride</title><author>FULLER, J ; OSTERYOUNG, R. A ; CARLIN, R. T</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c348t-9fe257c0a57c7db00d995d4feb3eead923f3bee507ba80a3c557c17be10063283</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1995</creationdate><topic>ALUMINIUM CHLORIDES</topic><topic>Applied sciences</topic><topic>BATTERY CHARGING</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>Electrochemical conversion: primary and secondary batteries, fuel cells</topic><topic>ENERGY EFFICIENCY</topic><topic>ENERGY STORAGE</topic><topic>Exact sciences and technology</topic><topic>LITHIUM-SULFUR BATTERIES</topic><topic>SODIUM-SULFUR BATTERIES</topic><topic>STABILITY</topic><topic>THIONYL CHLORIDES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>FULLER, J</creatorcontrib><creatorcontrib>OSTERYOUNG, R. A</creatorcontrib><creatorcontrib>CARLIN, R. T</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Journal of the Electrochemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>FULLER, J</au><au>OSTERYOUNG, R. A</au><au>CARLIN, R. T</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rechargeable lithium and sodium anodes in chloroaluminate molten salts containing thionyl chloride</atitle><jtitle>Journal of the Electrochemical Society</jtitle><date>1995-11-01</date><risdate>1995</risdate><volume>142</volume><issue>11</issue><spage>3632</spage><epage>3636</epage><pages>3632-3636</pages><issn>0013-4651</issn><eissn>1945-7111</eissn><coden>JESOAN</coden><abstract>Lithium and sodium deposition-stripping studies were performed in room temperature buffered neutral chloroaluminate melts containing low concentrations of thionyl chloride (SOCl{sub 2}). The SOCl{sub 2} solute promotes high cycling efficiencies of the alkali metals in these electrolytes. Staircase cyclic voltammetry and chronopotentiometry show cycling efficiencies of approximately 90% for both lithium and sodium. High cycling efficiencies are maintained following extended exposure of the melt to the dry box atmosphere and after time delays at open circuit. The performance of the SOCl{sub 2}-promoted systems is substantially improved over previous studies in room temperature melts containing hydrogen chloride as the promoting solute.</abstract><cop>Pennington, NJ</cop><pub>Electrochemical Society</pub><doi>10.1149/1.2048390</doi><tpages>5</tpages></addata></record> |
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| ispartof | Journal of the Electrochemical Society, 1995-11, Vol.142 (11), p.3632-3636 |
| issn | 0013-4651 1945-7111 |
| language | eng |
| recordid | cdi_crossref_primary_10_1149_1_2048390 |
| source | IOP Publishing Journals |
| subjects | ALUMINIUM CHLORIDES Applied sciences BATTERY CHARGING Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells ENERGY EFFICIENCY ENERGY STORAGE Exact sciences and technology LITHIUM-SULFUR BATTERIES SODIUM-SULFUR BATTERIES STABILITY THIONYL CHLORIDES |
| title | Rechargeable lithium and sodium anodes in chloroaluminate molten salts containing thionyl chloride |
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