Solid-State Rechargeable Lithium Metal Battery with Li 4 B 4 Al 3 O 12 Cl-based Water-Resistant Lithium-Ion-Conducting Oxychloride Glass-Ceramic Electrolyte
Glass-ceramics of lithium chloroboracite Li 4 B 4 Al 3 O 12 Cl, an oxychloride with a wide electrochemical window of ∼0–6 V vs Li/Li + , were employed as solid electrolytes in solid-state rechargeable lithium metal batteries. These glass-ceramics were stable against short-term (∼1 h) immersion in wa...
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| Veröffentlicht in: | Journal of the Electrochemical Society 2021-04, Vol.168 (4), p.40524 |
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| container_issue | 4 |
| container_start_page | 40524 |
| container_title | Journal of the Electrochemical Society |
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| creator | Saito, Mayu Arima, Hidechika Shoji, Mao Kizuki, Yota Munakata, Hirokazu Kanamura, Kiyoshi Kajihara, Koichi |
| description | Glass-ceramics of lithium chloroboracite Li
4
B
4
Al
3
O
12
Cl, an oxychloride with a wide electrochemical window of ∼0–6 V vs Li/Li
+
, were employed as solid electrolytes in solid-state rechargeable lithium metal batteries. These glass-ceramics were stable against short-term (∼1 h) immersion in water. Test cells consisting of a LiCoO
2
-based composite cathode and Li-rich Li–Au alloy anode delivered an initial discharge capacity of ∼135 mAh g
−1
and good average Coulombic efficiency of ∼99.3% under operation at 60 °C. These results confirm the compatibility of Li
4
B
4
Al
3
O
12
Cl-based glass-ceramics with solid-state rechargeable lithium metal batteries employing 4 V-class transition metal oxide cathodes. |
| doi_str_mv | 10.1149/1945-7111/abf4b0 |
| format | Article |
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4
B
4
Al
3
O
12
Cl, an oxychloride with a wide electrochemical window of ∼0–6 V vs Li/Li
+
, were employed as solid electrolytes in solid-state rechargeable lithium metal batteries. These glass-ceramics were stable against short-term (∼1 h) immersion in water. Test cells consisting of a LiCoO
2
-based composite cathode and Li-rich Li–Au alloy anode delivered an initial discharge capacity of ∼135 mAh g
−1
and good average Coulombic efficiency of ∼99.3% under operation at 60 °C. These results confirm the compatibility of Li
4
B
4
Al
3
O
12
Cl-based glass-ceramics with solid-state rechargeable lithium metal batteries employing 4 V-class transition metal oxide cathodes.</description><identifier>ISSN: 0013-4651</identifier><identifier>EISSN: 1945-7111</identifier><identifier>DOI: 10.1149/1945-7111/abf4b0</identifier><language>eng</language><ispartof>Journal of the Electrochemical Society, 2021-04, Vol.168 (4), p.40524</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c880-9bea17f1ae4c49cb15fcef941cf3a4674d4ab0cb159f24fe143b98c869554c1b3</citedby><cites>FETCH-LOGICAL-c880-9bea17f1ae4c49cb15fcef941cf3a4674d4ab0cb159f24fe143b98c869554c1b3</cites><orcidid>0000-0002-0282-3890</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Saito, Mayu</creatorcontrib><creatorcontrib>Arima, Hidechika</creatorcontrib><creatorcontrib>Shoji, Mao</creatorcontrib><creatorcontrib>Kizuki, Yota</creatorcontrib><creatorcontrib>Munakata, Hirokazu</creatorcontrib><creatorcontrib>Kanamura, Kiyoshi</creatorcontrib><creatorcontrib>Kajihara, Koichi</creatorcontrib><title>Solid-State Rechargeable Lithium Metal Battery with Li 4 B 4 Al 3 O 12 Cl-based Water-Resistant Lithium-Ion-Conducting Oxychloride Glass-Ceramic Electrolyte</title><title>Journal of the Electrochemical Society</title><description>Glass-ceramics of lithium chloroboracite Li
4
B
4
Al
3
O
12
Cl, an oxychloride with a wide electrochemical window of ∼0–6 V vs Li/Li
+
, were employed as solid electrolytes in solid-state rechargeable lithium metal batteries. These glass-ceramics were stable against short-term (∼1 h) immersion in water. Test cells consisting of a LiCoO
2
-based composite cathode and Li-rich Li–Au alloy anode delivered an initial discharge capacity of ∼135 mAh g
−1
and good average Coulombic efficiency of ∼99.3% under operation at 60 °C. These results confirm the compatibility of Li
4
B
4
Al
3
O
12
Cl-based glass-ceramics with solid-state rechargeable lithium metal batteries employing 4 V-class transition metal oxide cathodes.</description><issn>0013-4651</issn><issn>1945-7111</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNo9kMFOAjEQQBujiYjePfYHKh22y-4eYYNIgiEBEo-btjuFmsKatkT3X_xYd4N6mEzmTfIOj5BH4E8AohhBIVKWAcBIKiMUvyKDf3RNBpxDwsQkhVtyF8J7d0IusgH53jbO1mwbZUS6QX2Qfo9SOaQrGw_2fKSvGKWjMxkj-pZ-drR7UUFn3UwdTeiawpiWjikZsKZvncizDQYbojzFPw1bNidWNqf6rKM97en6q9UH13hbI104GQIr0cuj1XTuUEffuDbiPbkx0gV8-N1Dsnue78oXtlovluV0xXSec1YolJAZkCi0KLSC1Gg0hQBtEikmmaiFVLznhRkLgyASVeQ6nxRpKjSoZEj4Rat9E4JHU314e5S-rYBXfdyqL1n1JatL3OQHAz5uvQ</recordid><startdate>20210401</startdate><enddate>20210401</enddate><creator>Saito, Mayu</creator><creator>Arima, Hidechika</creator><creator>Shoji, Mao</creator><creator>Kizuki, Yota</creator><creator>Munakata, Hirokazu</creator><creator>Kanamura, Kiyoshi</creator><creator>Kajihara, Koichi</creator><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-0282-3890</orcidid></search><sort><creationdate>20210401</creationdate><title>Solid-State Rechargeable Lithium Metal Battery with Li 4 B 4 Al 3 O 12 Cl-based Water-Resistant Lithium-Ion-Conducting Oxychloride Glass-Ceramic Electrolyte</title><author>Saito, Mayu ; Arima, Hidechika ; Shoji, Mao ; Kizuki, Yota ; Munakata, Hirokazu ; Kanamura, Kiyoshi ; Kajihara, Koichi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c880-9bea17f1ae4c49cb15fcef941cf3a4674d4ab0cb159f24fe143b98c869554c1b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Saito, Mayu</creatorcontrib><creatorcontrib>Arima, Hidechika</creatorcontrib><creatorcontrib>Shoji, Mao</creatorcontrib><creatorcontrib>Kizuki, Yota</creatorcontrib><creatorcontrib>Munakata, Hirokazu</creatorcontrib><creatorcontrib>Kanamura, Kiyoshi</creatorcontrib><creatorcontrib>Kajihara, Koichi</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of the Electrochemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Saito, Mayu</au><au>Arima, Hidechika</au><au>Shoji, Mao</au><au>Kizuki, Yota</au><au>Munakata, Hirokazu</au><au>Kanamura, Kiyoshi</au><au>Kajihara, Koichi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solid-State Rechargeable Lithium Metal Battery with Li 4 B 4 Al 3 O 12 Cl-based Water-Resistant Lithium-Ion-Conducting Oxychloride Glass-Ceramic Electrolyte</atitle><jtitle>Journal of the Electrochemical Society</jtitle><date>2021-04-01</date><risdate>2021</risdate><volume>168</volume><issue>4</issue><spage>40524</spage><pages>40524-</pages><issn>0013-4651</issn><eissn>1945-7111</eissn><abstract>Glass-ceramics of lithium chloroboracite Li
4
B
4
Al
3
O
12
Cl, an oxychloride with a wide electrochemical window of ∼0–6 V vs Li/Li
+
, were employed as solid electrolytes in solid-state rechargeable lithium metal batteries. These glass-ceramics were stable against short-term (∼1 h) immersion in water. Test cells consisting of a LiCoO
2
-based composite cathode and Li-rich Li–Au alloy anode delivered an initial discharge capacity of ∼135 mAh g
−1
and good average Coulombic efficiency of ∼99.3% under operation at 60 °C. These results confirm the compatibility of Li
4
B
4
Al
3
O
12
Cl-based glass-ceramics with solid-state rechargeable lithium metal batteries employing 4 V-class transition metal oxide cathodes.</abstract><doi>10.1149/1945-7111/abf4b0</doi><orcidid>https://orcid.org/0000-0002-0282-3890</orcidid></addata></record> |
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| identifier | ISSN: 0013-4651 |
| ispartof | Journal of the Electrochemical Society, 2021-04, Vol.168 (4), p.40524 |
| issn | 0013-4651 1945-7111 |
| language | eng |
| recordid | cdi_crossref_primary_10_1149_1945_7111_abf4b0 |
| source | IOP Publishing Journals |
| title | Solid-State Rechargeable Lithium Metal Battery with Li 4 B 4 Al 3 O 12 Cl-based Water-Resistant Lithium-Ion-Conducting Oxychloride Glass-Ceramic Electrolyte |
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