Synthesis of Reduced Graphene Oxide-Supported PtAu Catalysts and Their Electrocatalytic Activity for Formic Acid Oxidation

In this paper, we demonstrate a one-pot synthesis of a reduced graphene oxide (RGO)-supported freely assembled binary alloy catalyst (PtAu/RGO) under alkaline conditions. The synthesized PtAu/RGO catalyst was characterized by powder X-ray diffraction (pXRD), transmission electron microscopy (TEM), e...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:ECS transactions 2016-01, Vol.72 (29), p.15-21
Hauptverfasser: Jeevagan, Arockiam John, Gunji, Takao, Tanabe, Toyokazu, Kaneko, Shingo, Matsumoto, Futoshi
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 21
container_issue 29
container_start_page 15
container_title ECS transactions
container_volume 72
creator Jeevagan, Arockiam John
Gunji, Takao
Tanabe, Toyokazu
Kaneko, Shingo
Matsumoto, Futoshi
description In this paper, we demonstrate a one-pot synthesis of a reduced graphene oxide (RGO)-supported freely assembled binary alloy catalyst (PtAu/RGO) under alkaline conditions. The synthesized PtAu/RGO catalyst was characterized by powder X-ray diffraction (pXRD), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX) and X-ray photoelectron spectroscopy (XPS). It was found that graphene oxide (GO) was successfully reduced to RGO. The PtAu nanoparticles exhibited an alloyed structure with an average diameter of approximately 3.60 ± 0.20 nm and were uniformly distributed across the RGO surface. Furthermore, the electrocatalytic activity of the catalyst for formic acid (FA) oxidation was examined, and it exhibited better catalytic activity for the FA oxidation reaction.
doi_str_mv 10.1149/07229.0015ecst
format Article
fullrecord <record><control><sourceid>iop_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1149_07229_0015ecst</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10.1149/07229.0015ecst</sourcerecordid><originalsourceid>FETCH-LOGICAL-c311t-9478821058ca0d4f1da009ea7cb42ffdaf5d03ffd73f73cd13b0bbc4578d34503</originalsourceid><addsrcrecordid>eNp1kM1Lw0AQxRdRsFavnvcspM5mk25yLKWtQqFi6zls9oNsSbNhdyPGv96Y1qOnecyb9xh-CD0SmBGS5M_A4jifAZBUCR-u0ITkNIvmjLLri06zeXyL7rw_AsyHDJug733fhEp547HV-F3JTiiJN463lWoU3n0ZqaJ917bWhcF4C4sOL3ngde-Dx7yR-FAp4_CqViI4K0YrGIEXIphPE3qsrcNr607jzsixkgdjm3t0o3nt1cNlTtHHenVYvkTb3eZ1udhGghISojxhWRYTSDPBQSaaSA6QK85EmcRaS65TCXQQjGpGhSS0hLIUScoySZMU6BTNzr3CWe-d0kXrzIm7viBQ_JIrRnLFH7kh8HQOGNsWR9u5Znjvv-MfB-Bx4g</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Synthesis of Reduced Graphene Oxide-Supported PtAu Catalysts and Their Electrocatalytic Activity for Formic Acid Oxidation</title><source>IOP Publishing Journals</source><source>Institute of Physics (IOP) Journals - HEAL-Link</source><creator>Jeevagan, Arockiam John ; Gunji, Takao ; Tanabe, Toyokazu ; Kaneko, Shingo ; Matsumoto, Futoshi</creator><creatorcontrib>Jeevagan, Arockiam John ; Gunji, Takao ; Tanabe, Toyokazu ; Kaneko, Shingo ; Matsumoto, Futoshi</creatorcontrib><description>In this paper, we demonstrate a one-pot synthesis of a reduced graphene oxide (RGO)-supported freely assembled binary alloy catalyst (PtAu/RGO) under alkaline conditions. The synthesized PtAu/RGO catalyst was characterized by powder X-ray diffraction (pXRD), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX) and X-ray photoelectron spectroscopy (XPS). It was found that graphene oxide (GO) was successfully reduced to RGO. The PtAu nanoparticles exhibited an alloyed structure with an average diameter of approximately 3.60 ± 0.20 nm and were uniformly distributed across the RGO surface. Furthermore, the electrocatalytic activity of the catalyst for formic acid (FA) oxidation was examined, and it exhibited better catalytic activity for the FA oxidation reaction.</description><identifier>ISSN: 1938-5862</identifier><identifier>EISSN: 1938-6737</identifier><identifier>DOI: 10.1149/07229.0015ecst</identifier><language>eng</language><publisher>The Electrochemical Society, Inc</publisher><ispartof>ECS transactions, 2016-01, Vol.72 (29), p.15-21</ispartof><rights>2016 ECS - The Electrochemical Society</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c311t-9478821058ca0d4f1da009ea7cb42ffdaf5d03ffd73f73cd13b0bbc4578d34503</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://iopscience.iop.org/article/10.1149/07229.0015ecst/pdf$$EPDF$$P50$$Giop$$H</linktopdf><link.rule.ids>314,780,784,27924,27925,53846,53893</link.rule.ids></links><search><creatorcontrib>Jeevagan, Arockiam John</creatorcontrib><creatorcontrib>Gunji, Takao</creatorcontrib><creatorcontrib>Tanabe, Toyokazu</creatorcontrib><creatorcontrib>Kaneko, Shingo</creatorcontrib><creatorcontrib>Matsumoto, Futoshi</creatorcontrib><title>Synthesis of Reduced Graphene Oxide-Supported PtAu Catalysts and Their Electrocatalytic Activity for Formic Acid Oxidation</title><title>ECS transactions</title><addtitle>ECS Trans</addtitle><description>In this paper, we demonstrate a one-pot synthesis of a reduced graphene oxide (RGO)-supported freely assembled binary alloy catalyst (PtAu/RGO) under alkaline conditions. The synthesized PtAu/RGO catalyst was characterized by powder X-ray diffraction (pXRD), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX) and X-ray photoelectron spectroscopy (XPS). It was found that graphene oxide (GO) was successfully reduced to RGO. The PtAu nanoparticles exhibited an alloyed structure with an average diameter of approximately 3.60 ± 0.20 nm and were uniformly distributed across the RGO surface. Furthermore, the electrocatalytic activity of the catalyst for formic acid (FA) oxidation was examined, and it exhibited better catalytic activity for the FA oxidation reaction.</description><issn>1938-5862</issn><issn>1938-6737</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp1kM1Lw0AQxRdRsFavnvcspM5mk25yLKWtQqFi6zls9oNsSbNhdyPGv96Y1qOnecyb9xh-CD0SmBGS5M_A4jifAZBUCR-u0ITkNIvmjLLri06zeXyL7rw_AsyHDJug733fhEp547HV-F3JTiiJN463lWoU3n0ZqaJ917bWhcF4C4sOL3ngde-Dx7yR-FAp4_CqViI4K0YrGIEXIphPE3qsrcNr607jzsixkgdjm3t0o3nt1cNlTtHHenVYvkTb3eZ1udhGghISojxhWRYTSDPBQSaaSA6QK85EmcRaS65TCXQQjGpGhSS0hLIUScoySZMU6BTNzr3CWe-d0kXrzIm7viBQ_JIrRnLFH7kh8HQOGNsWR9u5Znjvv-MfB-Bx4g</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Jeevagan, Arockiam John</creator><creator>Gunji, Takao</creator><creator>Tanabe, Toyokazu</creator><creator>Kaneko, Shingo</creator><creator>Matsumoto, Futoshi</creator><general>The Electrochemical Society, Inc</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20160101</creationdate><title>Synthesis of Reduced Graphene Oxide-Supported PtAu Catalysts and Their Electrocatalytic Activity for Formic Acid Oxidation</title><author>Jeevagan, Arockiam John ; Gunji, Takao ; Tanabe, Toyokazu ; Kaneko, Shingo ; Matsumoto, Futoshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c311t-9478821058ca0d4f1da009ea7cb42ffdaf5d03ffd73f73cd13b0bbc4578d34503</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Jeevagan, Arockiam John</creatorcontrib><creatorcontrib>Gunji, Takao</creatorcontrib><creatorcontrib>Tanabe, Toyokazu</creatorcontrib><creatorcontrib>Kaneko, Shingo</creatorcontrib><creatorcontrib>Matsumoto, Futoshi</creatorcontrib><collection>CrossRef</collection><jtitle>ECS transactions</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jeevagan, Arockiam John</au><au>Gunji, Takao</au><au>Tanabe, Toyokazu</au><au>Kaneko, Shingo</au><au>Matsumoto, Futoshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of Reduced Graphene Oxide-Supported PtAu Catalysts and Their Electrocatalytic Activity for Formic Acid Oxidation</atitle><jtitle>ECS transactions</jtitle><addtitle>ECS Trans</addtitle><date>2016-01-01</date><risdate>2016</risdate><volume>72</volume><issue>29</issue><spage>15</spage><epage>21</epage><pages>15-21</pages><issn>1938-5862</issn><eissn>1938-6737</eissn><abstract>In this paper, we demonstrate a one-pot synthesis of a reduced graphene oxide (RGO)-supported freely assembled binary alloy catalyst (PtAu/RGO) under alkaline conditions. The synthesized PtAu/RGO catalyst was characterized by powder X-ray diffraction (pXRD), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX) and X-ray photoelectron spectroscopy (XPS). It was found that graphene oxide (GO) was successfully reduced to RGO. The PtAu nanoparticles exhibited an alloyed structure with an average diameter of approximately 3.60 ± 0.20 nm and were uniformly distributed across the RGO surface. Furthermore, the electrocatalytic activity of the catalyst for formic acid (FA) oxidation was examined, and it exhibited better catalytic activity for the FA oxidation reaction.</abstract><pub>The Electrochemical Society, Inc</pub><doi>10.1149/07229.0015ecst</doi><tpages>7</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1938-5862
ispartof ECS transactions, 2016-01, Vol.72 (29), p.15-21
issn 1938-5862
1938-6737
language eng
recordid cdi_crossref_primary_10_1149_07229_0015ecst
source IOP Publishing Journals; Institute of Physics (IOP) Journals - HEAL-Link
title Synthesis of Reduced Graphene Oxide-Supported PtAu Catalysts and Their Electrocatalytic Activity for Formic Acid Oxidation
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-21T17%3A56%3A21IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-iop_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20of%20Reduced%20Graphene%20Oxide-Supported%20PtAu%20Catalysts%20and%20Their%20Electrocatalytic%20Activity%20for%20Formic%20Acid%20Oxidation&rft.jtitle=ECS%20transactions&rft.au=Jeevagan,%20Arockiam%20John&rft.date=2016-01-01&rft.volume=72&rft.issue=29&rft.spage=15&rft.epage=21&rft.pages=15-21&rft.issn=1938-5862&rft.eissn=1938-6737&rft_id=info:doi/10.1149/07229.0015ecst&rft_dat=%3Ciop_cross%3E10.1149/07229.0015ecst%3C/iop_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true