Mechanism of Radical Control in Capacitive RF Plasma for ULSI Processing

The radicals of capacitive plasmas actually used in mass production were analyzed using various measurement systems. The composition of radicals in bulk plasma depends on the gas chemistry, the dissociation process, and interaction with the wall. It is revealed that parent gas (C 4 F 8 ) is dissocia...

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Veröffentlicht in:Japanese Journal of Applied Physics 1998-04, Vol.37 (4S), p.2394
Hauptverfasser: Tatsumi, Tetsuya, Hayashi, Hisataka, Morishita, Satoshi, Noda, Shuichi, Okigawa, Mitsuru, Itabashi, Naoshi, Hikosaka, Yukinobu, Inoue, Masami
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container_issue 4S
container_start_page 2394
container_title Japanese Journal of Applied Physics
container_volume 37
creator Tatsumi, Tetsuya
Hayashi, Hisataka
Morishita, Satoshi
Noda, Shuichi
Okigawa, Mitsuru
Itabashi, Naoshi
Hikosaka, Yukinobu
Inoue, Masami
description The radicals of capacitive plasmas actually used in mass production were analyzed using various measurement systems. The composition of radicals in bulk plasma depends on the gas chemistry, the dissociation process, and interaction with the wall. It is revealed that parent gas (C 4 F 8 ) is dissociated by multiple collision with electrons according to τ· n e , where τ is the residence time, n e is the electron density, σ is the dissociation collision cross section and v is the electron velocity. A high-performance etching process, which can realize 0.09 µmφ contact holes with aspect ratio of 11, was achieved using a short residence time to suppress the excess dissociation and the control of deposition species through the addition of O 2 to C 4 F 8 /Ar plasma as well as the reduction of the density of F radicals through the reaction with the Si wall.
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