Influence of optical purity on the smectic-Cβ phase of antiferroelectric liquid crystals

The Smectic- C β * (SmC β * ) phase, which appears between the SmA and SmC A * phases in an optically pure liquid crystal of MHPOBC, has been studied by means of simultaneous measurements of the dielectric constant ε and the electroclinic coefficient κ under a dc bias electric field. The result of e...

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Veröffentlicht in:Japanese Journal of Applied Physics 1996-01, Vol.35 (1B), p.L114-L116
Hauptverfasser: SAKO, T, KIMURA, Y, HAYAKAWA, R, OKABE, N, SUZUKI, Y
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container_end_page L116
container_issue 1B
container_start_page L114
container_title Japanese Journal of Applied Physics
container_volume 35
creator SAKO, T
KIMURA, Y
HAYAKAWA, R
OKABE, N
SUZUKI, Y
description The Smectic- C β * (SmC β * ) phase, which appears between the SmA and SmC A * phases in an optically pure liquid crystal of MHPOBC, has been studied by means of simultaneous measurements of the dielectric constant ε and the electroclinic coefficient κ under a dc bias electric field. The result of electroclinic coefficient measurement shows that the SmC β * phase is obviously different from the SmC * phase and can be considered as a ferrielectric phase. From the simultaneous measurement of ε and κ, we can observe the difference in the phase transition behaviors between pure and slightly racemized MHPOBC samples and confirm that the decrease of optical purity causes the change from the SmC β * phase to the SmC * phase.
doi_str_mv 10.1143/jjap.35.l114
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The result of electroclinic coefficient measurement shows that the SmC β * phase is obviously different from the SmC * phase and can be considered as a ferrielectric phase. 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source IOP Publishing Journals; Institute of Physics (IOP) Journals - HEAL-Link
subjects Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
Dielectric properties of solids and liquids
Dielectrics, piezoelectrics, and ferroelectrics and their properties
Exact sciences and technology
Liquid crystals
Orientational order of liquid crystals
electric and magnetic field effects on order
Permittivity (dielectric function)
Physics
Structure of solids and liquids
crystallography
title Influence of optical purity on the smectic-Cβ phase of antiferroelectric liquid crystals
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