The importance of the electric interaction for stabilizing the antiferroelectric smectic liquid-crystalline phase

The importance of the interlayer molecular interaction to stabilize the antiferroelectric smectic C A * (S * C A ) phase is shown using dimer molecules in which chiral mesogenic units are connected by a polymethylene chain. According to the conformational effect of the polymethylene chain, two mesog...

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Veröffentlicht in:Japanese Journal of Applied Physics 1995, Vol.34 (7A), p.L830-L832
Hauptverfasser: KUSUMOTO, T, ISOZAKI, T, SUZUKI, Y, TAKANISHI, Y, TAKEZOE, H, FUKUDA, A, HIYAMA, T
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container_end_page L832
container_issue 7A
container_start_page L830
container_title Japanese Journal of Applied Physics
container_volume 34
creator KUSUMOTO, T
ISOZAKI, T
SUZUKI, Y
TAKANISHI, Y
TAKEZOE, H
FUKUDA, A
HIYAMA, T
description The importance of the interlayer molecular interaction to stabilize the antiferroelectric smectic C A * (S * C A ) phase is shown using dimer molecules in which chiral mesogenic units are connected by a polymethylene chain. According to the conformational effect of the polymethylene chain, two mesogenic units tend to align parallel or anticlinically for even or odd carbon number, respectively. In a dimer molecule with a longer chain length, however, another interaction overcomes the conformational effect and stabilizes the S * C A phase. This observation suggests the importance of the electric, possibly the dipole-dipole, interaction between mesogens in S * C A .
doi_str_mv 10.1143/jjap.34.l830
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source IOP Publishing Journals; Institute of Physics (IOP) Journals - HEAL-Link
subjects Condensed matter: electronic structure, electrical, magnetic, and optical properties
Dielectric, piezoelectric, ferroelectric and antiferroelectric materials
Dielectrics, piezoelectrics, and ferroelectrics and their properties
Exact sciences and technology
Ferroelectricity and antiferroelectricity
Liquids and liquid crystals
Liquids, emulsions, and suspensions
liquid crystals
Physics
Switching phenomena
title The importance of the electric interaction for stabilizing the antiferroelectric smectic liquid-crystalline phase
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