Enhancement of third-order optical nonlinearities of soluble vanadyl phthalocyanines in doped polymer films
The third-order optical susceptibilities χ 1111 (3) (-3ω; ω, ω, ω)s of a soluble vanadyl phthalocyanine derivative (( t -Bu) 1.1 VOPc) are studied for thin films and doped polymethylmathacrylate films by optical third-harmonic generation measurements at wavelengths of 1543 nm and 1907 nm. The χ (3)...
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| Veröffentlicht in: | Japanese Journal of Applied Physics 1992-04, Vol.31 (4), p.1071-1975 |
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| container_end_page | 1975 |
|---|---|
| container_issue | 4 |
| container_start_page | 1071 |
| container_title | Japanese Journal of Applied Physics |
| container_volume | 31 |
| creator | HOSODA, M WADA, T YAMAMOTO, T KANEKO, A GARITO, A. F SASABE, H |
| description | The third-order optical susceptibilities χ
1111
(3)
(-3ω; ω, ω, ω)s of a soluble vanadyl phthalocyanine derivative ((
t
-Bu)
1.1
VOPc) are studied for thin films and doped polymethylmathacrylate films by optical third-harmonic generation measurements at wavelengths of 1543 nm and 1907 nm. The χ
(3)
values are enhanced by a factor of 2-7 at resonant and
nonresonant wavelengths, concurrent with an absorption change induced by exposure to solvent vapor. The red-shifted phase (phase II), obtained by the treatment, has larger χ
(3)
values than the as-prepared phase (phase I). The enhancement of third-order optical nonlinear susceptibilities in phthalocyanine thin films is discussed in terms of electronic transition and molecular packing. |
| doi_str_mv | 10.1143/jjap.31.1071 |
| format | Article |
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1111
(3)
(-3ω; ω, ω, ω)s of a soluble vanadyl phthalocyanine derivative ((
t
-Bu)
1.1
VOPc) are studied for thin films and doped polymethylmathacrylate films by optical third-harmonic generation measurements at wavelengths of 1543 nm and 1907 nm. The χ
(3)
values are enhanced by a factor of 2-7 at resonant and
nonresonant wavelengths, concurrent with an absorption change induced by exposure to solvent vapor. The red-shifted phase (phase II), obtained by the treatment, has larger χ
(3)
values than the as-prepared phase (phase I). The enhancement of third-order optical nonlinear susceptibilities in phthalocyanine thin films is discussed in terms of electronic transition and molecular packing.</description><identifier>ISSN: 0021-4922</identifier><identifier>EISSN: 1347-4065</identifier><identifier>DOI: 10.1143/jjap.31.1071</identifier><identifier>CODEN: JJAPA5</identifier><language>eng</language><publisher>Tokyo: Japanese journal of applied physics</publisher><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Exact sciences and technology ; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation ; Optical properties of specific thin films ; Physics</subject><ispartof>Japanese Journal of Applied Physics, 1992-04, Vol.31 (4), p.1071-1975</ispartof><rights>1992 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c272t-ba6ac477a9a580aa0f47098f894dabfeabeee5d3d68b3413cf1120698fd41e193</citedby><cites>FETCH-LOGICAL-c272t-ba6ac477a9a580aa0f47098f894dabfeabeee5d3d68b3413cf1120698fd41e193</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=5298795$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>HOSODA, M</creatorcontrib><creatorcontrib>WADA, T</creatorcontrib><creatorcontrib>YAMAMOTO, T</creatorcontrib><creatorcontrib>KANEKO, A</creatorcontrib><creatorcontrib>GARITO, A. F</creatorcontrib><creatorcontrib>SASABE, H</creatorcontrib><title>Enhancement of third-order optical nonlinearities of soluble vanadyl phthalocyanines in doped polymer films</title><title>Japanese Journal of Applied Physics</title><description>The third-order optical susceptibilities χ
1111
(3)
(-3ω; ω, ω, ω)s of a soluble vanadyl phthalocyanine derivative ((
t
-Bu)
1.1
VOPc) are studied for thin films and doped polymethylmathacrylate films by optical third-harmonic generation measurements at wavelengths of 1543 nm and 1907 nm. The χ
(3)
values are enhanced by a factor of 2-7 at resonant and
nonresonant wavelengths, concurrent with an absorption change induced by exposure to solvent vapor. The red-shifted phase (phase II), obtained by the treatment, has larger χ
(3)
values than the as-prepared phase (phase I). The enhancement of third-order optical nonlinear susceptibilities in phthalocyanine thin films is discussed in terms of electronic transition and molecular packing.</description><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Exact sciences and technology</subject><subject>Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation</subject><subject>Optical properties of specific thin films</subject><subject>Physics</subject><issn>0021-4922</issn><issn>1347-4065</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1992</creationdate><recordtype>article</recordtype><recordid>eNo9kE1LxDAURYMoOI7u_AFZuLRjXpN-LYdhHB0GdKHr8tokNGOalKQK_fd2GHF1eXDehXsIuQe2AhD86XjEYcVhBayAC7IALopEsDy7JAvGUkhElabX5CbG43zmmYAF-dq6Dl2reuVG6jUdOxNk4oNUgfphNC1a6ryzxikMZjQqnqjo7XdjFf1Bh3KydOjGDq1vJ3QzGKlxVPpBSTp4O_VzlTa2j7fkSqON6u4vl-TzefuxeUkOb7vXzfqQtGmRjkmDObaiKLDCrGSITIuCVaUuKyGx0QobpVQmuczLhgvgrQZIWT4TUoCCii_J47m3DT7GoHQ9BNNjmGpg9UlUvd-v32sO9UnUjD-c8QHjPFeH2YeJ_z9ZWpVFlfFfvklrxA</recordid><startdate>19920401</startdate><enddate>19920401</enddate><creator>HOSODA, M</creator><creator>WADA, T</creator><creator>YAMAMOTO, T</creator><creator>KANEKO, A</creator><creator>GARITO, A. F</creator><creator>SASABE, H</creator><general>Japanese journal of applied physics</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19920401</creationdate><title>Enhancement of third-order optical nonlinearities of soluble vanadyl phthalocyanines in doped polymer films</title><author>HOSODA, M ; WADA, T ; YAMAMOTO, T ; KANEKO, A ; GARITO, A. F ; SASABE, H</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c272t-ba6ac477a9a580aa0f47098f894dabfeabeee5d3d68b3413cf1120698fd41e193</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1992</creationdate><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Exact sciences and technology</topic><topic>Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation</topic><topic>Optical properties of specific thin films</topic><topic>Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>HOSODA, M</creatorcontrib><creatorcontrib>WADA, T</creatorcontrib><creatorcontrib>YAMAMOTO, T</creatorcontrib><creatorcontrib>KANEKO, A</creatorcontrib><creatorcontrib>GARITO, A. F</creatorcontrib><creatorcontrib>SASABE, H</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Japanese Journal of Applied Physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>HOSODA, M</au><au>WADA, T</au><au>YAMAMOTO, T</au><au>KANEKO, A</au><au>GARITO, A. F</au><au>SASABE, H</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhancement of third-order optical nonlinearities of soluble vanadyl phthalocyanines in doped polymer films</atitle><jtitle>Japanese Journal of Applied Physics</jtitle><date>1992-04-01</date><risdate>1992</risdate><volume>31</volume><issue>4</issue><spage>1071</spage><epage>1975</epage><pages>1071-1975</pages><issn>0021-4922</issn><eissn>1347-4065</eissn><coden>JJAPA5</coden><abstract>The third-order optical susceptibilities χ
1111
(3)
(-3ω; ω, ω, ω)s of a soluble vanadyl phthalocyanine derivative ((
t
-Bu)
1.1
VOPc) are studied for thin films and doped polymethylmathacrylate films by optical third-harmonic generation measurements at wavelengths of 1543 nm and 1907 nm. The χ
(3)
values are enhanced by a factor of 2-7 at resonant and
nonresonant wavelengths, concurrent with an absorption change induced by exposure to solvent vapor. The red-shifted phase (phase II), obtained by the treatment, has larger χ
(3)
values than the as-prepared phase (phase I). The enhancement of third-order optical nonlinear susceptibilities in phthalocyanine thin films is discussed in terms of electronic transition and molecular packing.</abstract><cop>Tokyo</cop><pub>Japanese journal of applied physics</pub><doi>10.1143/jjap.31.1071</doi><tpages>905</tpages></addata></record> |
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| ispartof | Japanese Journal of Applied Physics, 1992-04, Vol.31 (4), p.1071-1975 |
| issn | 0021-4922 1347-4065 |
| language | eng |
| recordid | cdi_crossref_primary_10_1143_JJAP_31_1071 |
| source | Institute of Physics Journals |
| subjects | Condensed matter: electronic structure, electrical, magnetic, and optical properties Exact sciences and technology Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation Optical properties of specific thin films Physics |
| title | Enhancement of third-order optical nonlinearities of soluble vanadyl phthalocyanines in doped polymer films |
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