Monomeric and dimeric V(III) complexes supported by organic amides
Reaction of VCl 3 (THF) 3 with two equivalents of R 2 NLi (R = Cy, Me 3 Si) yielded the two corresponding complexes (Cy 2 N) 2 V(μ-Cl) 2 Li(THF) 2 ( 1 ) and [(Me 3 Si) 2 N] 2 VCl(THF) ( 2 ). Both complexes decomposed in hot toluene. In the case of complex 1 the reaction led to dimerization and forma...
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| Veröffentlicht in: | Canadian journal of chemistry 1996-11, Vol.74 (11), p.1930-1935 |
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| container_end_page | 1935 |
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| container_issue | 11 |
| container_start_page | 1930 |
| container_title | Canadian journal of chemistry |
| container_volume | 74 |
| creator | Berno, Pietro Moore, Mark Minhas, Ravinder Gambarotta, Sandro |
| description | Reaction of VCl
3
(THF)
3
with two equivalents of R
2
NLi (R = Cy, Me
3
Si) yielded the two corresponding complexes (Cy
2
N)
2
V(μ-Cl)
2
Li(THF)
2
(
1
) and [(Me
3
Si)
2
N]
2
VCl(THF) (
2
). Both complexes decomposed in hot toluene. In the case of complex
1
the reaction led to dimerization and formation of the dimeric [(Cy
2
N)
2
V(μ-Cl)]
2
(
3
). Reaction of
2
with NaBH
4
yielded the unprecedented borohydride derivative [(Me
3
Si)
2
N]
2
V(BH
4
)(THF) (
4
). The structures of all the complexes were elucidated by X-ray analysis. Key words: vanadium, trivalent, amide, borohydride, dinuclear |
| doi_str_mv | 10.1139/v96-219 |
| format | Article |
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3
(THF)
3
with two equivalents of R
2
NLi (R = Cy, Me
3
Si) yielded the two corresponding complexes (Cy
2
N)
2
V(μ-Cl)
2
Li(THF)
2
(
1
) and [(Me
3
Si)
2
N]
2
VCl(THF) (
2
). Both complexes decomposed in hot toluene. In the case of complex
1
the reaction led to dimerization and formation of the dimeric [(Cy
2
N)
2
V(μ-Cl)]
2
(
3
). Reaction of
2
with NaBH
4
yielded the unprecedented borohydride derivative [(Me
3
Si)
2
N]
2
V(BH
4
)(THF) (
4
). The structures of all the complexes were elucidated by X-ray analysis. Key words: vanadium, trivalent, amide, borohydride, dinuclear</description><identifier>ISSN: 0008-4042</identifier><identifier>EISSN: 1480-3291</identifier><identifier>DOI: 10.1139/v96-219</identifier><language>eng</language><publisher>Ottawa, Canada: NRC Research Press</publisher><ispartof>Canadian journal of chemistry, 1996-11, Vol.74 (11), p.1930-1935</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c322t-cae907347cb118170457d2f3138f5370657eb7b6a20310df187ad22ab3601ce3</citedby><cites>FETCH-LOGICAL-c322t-cae907347cb118170457d2f3138f5370657eb7b6a20310df187ad22ab3601ce3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://cdnsciencepub.com/doi/pdf/10.1139/v96-219$$EPDF$$P50$$Gnrcresearch$$H</linktopdf><linktohtml>$$Uhttps://cdnsciencepub.com/doi/full/10.1139/v96-219$$EHTML$$P50$$Gnrcresearch$$H</linktohtml><link.rule.ids>314,780,784,2932,27924,27925,64428,65234</link.rule.ids></links><search><creatorcontrib>Berno, Pietro</creatorcontrib><creatorcontrib>Moore, Mark</creatorcontrib><creatorcontrib>Minhas, Ravinder</creatorcontrib><creatorcontrib>Gambarotta, Sandro</creatorcontrib><title>Monomeric and dimeric V(III) complexes supported by organic amides</title><title>Canadian journal of chemistry</title><addtitle>Revue canadienne de chimie</addtitle><description>Reaction of VCl
3
(THF)
3
with two equivalents of R
2
NLi (R = Cy, Me
3
Si) yielded the two corresponding complexes (Cy
2
N)
2
V(μ-Cl)
2
Li(THF)
2
(
1
) and [(Me
3
Si)
2
N]
2
VCl(THF) (
2
). Both complexes decomposed in hot toluene. In the case of complex
1
the reaction led to dimerization and formation of the dimeric [(Cy
2
N)
2
V(μ-Cl)]
2
(
3
). Reaction of
2
with NaBH
4
yielded the unprecedented borohydride derivative [(Me
3
Si)
2
N]
2
V(BH
4
)(THF) (
4
). The structures of all the complexes were elucidated by X-ray analysis. Key words: vanadium, trivalent, amide, borohydride, dinuclear</description><issn>0008-4042</issn><issn>1480-3291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1996</creationdate><recordtype>article</recordtype><recordid>eNp9j0tLxDAUhYMoWEfxL3TlC6L3Jm3TLp3BR2HEzeA2pHloZdqUZBTn39uhs9XVPRe-c-Aj5BzhFpFXd99VQRlWByTBrATKWYWHJAGAkmaQsWNyEuPn-ApgeULmL773nQ2tTlVvUtNO-e2qruvrVPtuWNsfG9P4NQw-bKxJm23qw7vqd42uNTaekiOn1tGe7e-MrB4fVotnunx9qhf3S6o5Yxuqla1A8EzoBrFEAVkuDHMceelyLqDIhW1EUygGHME4LIUyjKmGF4Da8hm5nGZ18DEG6-QQ2k6FrUSQO3M5msvRfCRvJrIPOthoVdAf_8AXf8N7SA7G8V8_hmWH</recordid><startdate>19961101</startdate><enddate>19961101</enddate><creator>Berno, Pietro</creator><creator>Moore, Mark</creator><creator>Minhas, Ravinder</creator><creator>Gambarotta, Sandro</creator><general>NRC Research Press</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19961101</creationdate><title>Monomeric and dimeric V(III) complexes supported by organic amides</title><author>Berno, Pietro ; Moore, Mark ; Minhas, Ravinder ; Gambarotta, Sandro</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c322t-cae907347cb118170457d2f3138f5370657eb7b6a20310df187ad22ab3601ce3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1996</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Berno, Pietro</creatorcontrib><creatorcontrib>Moore, Mark</creatorcontrib><creatorcontrib>Minhas, Ravinder</creatorcontrib><creatorcontrib>Gambarotta, Sandro</creatorcontrib><collection>CrossRef</collection><jtitle>Canadian journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Berno, Pietro</au><au>Moore, Mark</au><au>Minhas, Ravinder</au><au>Gambarotta, Sandro</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Monomeric and dimeric V(III) complexes supported by organic amides</atitle><jtitle>Canadian journal of chemistry</jtitle><addtitle>Revue canadienne de chimie</addtitle><date>1996-11-01</date><risdate>1996</risdate><volume>74</volume><issue>11</issue><spage>1930</spage><epage>1935</epage><pages>1930-1935</pages><issn>0008-4042</issn><eissn>1480-3291</eissn><abstract>Reaction of VCl
3
(THF)
3
with two equivalents of R
2
NLi (R = Cy, Me
3
Si) yielded the two corresponding complexes (Cy
2
N)
2
V(μ-Cl)
2
Li(THF)
2
(
1
) and [(Me
3
Si)
2
N]
2
VCl(THF) (
2
). Both complexes decomposed in hot toluene. In the case of complex
1
the reaction led to dimerization and formation of the dimeric [(Cy
2
N)
2
V(μ-Cl)]
2
(
3
). Reaction of
2
with NaBH
4
yielded the unprecedented borohydride derivative [(Me
3
Si)
2
N]
2
V(BH
4
)(THF) (
4
). The structures of all the complexes were elucidated by X-ray analysis. Key words: vanadium, trivalent, amide, borohydride, dinuclear</abstract><cop>Ottawa, Canada</cop><pub>NRC Research Press</pub><doi>10.1139/v96-219</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Canadian journal of chemistry, 1996-11, Vol.74 (11), p.1930-1935 |
| issn | 0008-4042 1480-3291 |
| language | eng |
| recordid | cdi_crossref_primary_10_1139_v96_219 |
| source | Canadian Science Publishing (NRC Research Press) Current; EZB-FREE-00999 freely available EZB journals; Free Full-Text Journals in Chemistry |
| title | Monomeric and dimeric V(III) complexes supported by organic amides |
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