The selective complexation of adamantane nitriles by tungsten pentacarbonyl

Adamantyl-1,3,4-oxathiazol-2-one is usually prepared as a mixture with 1-adamantanecarbonitrile. To separate these two compounds the mixture is reacted with thf*W(CO) 5 , which selectively forms a complex with the nitrile. The resulting mixture can then be readily separated into pure compounds by su...

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Veröffentlicht in:	Canadian journal of chemistry 1996-01, Vol.74 (1), p.107-113
Hauptverfasser:	Jefford, Valerie J, Schriver, Melbourne J, Zaworotko, Michael J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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