1,3-Dioxan-5-ones: synthesis, deprotonation, and reactions of their lithium enolates

A general synthetic route to 2-alkyl- and 2,2-dialkyl-1,3-dioxan-5-ones, using tris(hydroxymethyl)-nitromethane as the starting material, is described. Deprotonation of these compounds was studied. It was established that these dioxanones could be deprotonated with LDA; however, the reduction of the...

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Veröffentlicht in:	Canadian journal of chemistry 1995-10, Vol.73 (10), p.1616-1626
Hauptverfasser:	Majewski, Marek, Gleave, D. Mark, Nowak, Pawel
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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