Preparation and 31 P NMR characterization of N-bonded complexes of platinum(II) with a phosphadithiatriazine: X-ray structure of trans -PtCl 2 (Pet 3 )(η 1 -N-Ph 2 PS 2 N 3 )

The reaction of Ph 2 PS 2 N 3 with [Pt 2 (μ-Cl) 2 (PEt 3 ) 4 ][BF 4 ] 2 or [PtCl 2 (PEt 3 )] 2 , in dichloromethane at 23° C produces the 1:1 adducts cis-[PtCl(PEt 3 ) 2 (Ph 2 PS 2 N 3 )][BF 4 ], 3, and trans-[PtCl 2 (PEt 3 )(Ph 2 PS 3 N 2 )], 4, respectively, in good yields. The 31 P NMR data for 3...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Canadian journal of chemistry 1992-10, Vol.70 (10), p.2602-2606
Hauptverfasser:	Chivers, Tristram, Hilts, Robert W., Krouse, Ian H., Cordes, A. Wallace, Hallford, Randal, Scott, Syrona R.
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!