The mechanism of the infrared laser induced multiphoton decomposition of ethyl alcohol
The infrared laser induced multiphoton decomposition of ethyl alcohol has been studied in experiments with iodine as a radical scavenger and the deuterium substituted form CH 3 CD 2 OH of the alcohol. These experiments show that the principal product, C 2 H 4 , arises from a concerted molecular elim...
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| Veröffentlicht in: | Canadian journal of chemistry 1990-08, Vol.68 (8), p.1437-1439 |
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| container_end_page | 1439 |
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| container_issue | 8 |
| container_start_page | 1437 |
| container_title | Canadian journal of chemistry |
| container_volume | 68 |
| creator | Goodale, J. W Evans, D. K Ivanco, M McAlpine, Robert D |
| description | The infrared laser induced multiphoton decomposition of ethyl alcohol has been studied in experiments with iodine as a radical scavenger and the deuterium substituted form CH
3
CD
2
OH of the alcohol. These experiments show that the principal product, C
2
H
4
, arises from a concerted molecular elimination, as do most of the CH
4
and CH
3
CHO. The C
2
H
6
product results from recombination of the nascent methyl radicals formed in the minor bond breaking channel. Keywords: ethyl alcohol, multiphoton decomposition. |
| doi_str_mv | 10.1139/v90-219 |
| format | Article |
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3
CD
2
OH of the alcohol. These experiments show that the principal product, C
2
H
4
, arises from a concerted molecular elimination, as do most of the CH
4
and CH
3
CHO. The C
2
H
6
product results from recombination of the nascent methyl radicals formed in the minor bond breaking channel. Keywords: ethyl alcohol, multiphoton decomposition.</description><identifier>ISSN: 0008-4042</identifier><identifier>EISSN: 1480-3291</identifier><identifier>DOI: 10.1139/v90-219</identifier><language>eng</language><publisher>Ottawa, Canada: NRC Research Press</publisher><ispartof>Canadian journal of chemistry, 1990-08, Vol.68 (8), p.1437-1439</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c254t-8f5d7a29cc707c0906dab33256921aeb34d4c9096efade3bf3e61713cc92a6e63</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://cdnsciencepub.com/doi/pdf/10.1139/v90-219$$EPDF$$P50$$Gnrcresearch$$H</linktopdf><linktohtml>$$Uhttps://cdnsciencepub.com/doi/full/10.1139/v90-219$$EHTML$$P50$$Gnrcresearch$$H</linktohtml><link.rule.ids>314,776,780,2919,27901,27902,64401,64979</link.rule.ids></links><search><creatorcontrib>Goodale, J. W</creatorcontrib><creatorcontrib>Evans, D. K</creatorcontrib><creatorcontrib>Ivanco, M</creatorcontrib><creatorcontrib>McAlpine, Robert D</creatorcontrib><title>The mechanism of the infrared laser induced multiphoton decomposition of ethyl alcohol</title><title>Canadian journal of chemistry</title><addtitle>Revue canadienne de chimie</addtitle><description>The infrared laser induced multiphoton decomposition of ethyl alcohol has been studied in experiments with iodine as a radical scavenger and the deuterium substituted form CH
3
CD
2
OH of the alcohol. These experiments show that the principal product, C
2
H
4
, arises from a concerted molecular elimination, as do most of the CH
4
and CH
3
CHO. The C
2
H
6
product results from recombination of the nascent methyl radicals formed in the minor bond breaking channel. Keywords: ethyl alcohol, multiphoton decomposition.</description><issn>0008-4042</issn><issn>1480-3291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1990</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LxDAQQIMoWFfxL_SkIFQnSb9ylMUvWPCyei3pZEIrbVOSrrD_3sjuVU_DG97M4TF2zeGec6kevhVkgqsTlvC8hkwKxU9ZAgB1lkMuztlFCF8RKxBFwj63HaUjYaenPoyps-kSF_1kvfZk0kEH8hHNDiONu2Hp584tbkoNoRtnF_qljxTvaOn2Q6oHdJ0bLtmZ1UOgq-NcsY_np-36Ndu8v7ytHzcZiiJfstoWptJCIVZQISgojW6lFEWpBNfUytzkqECVZLUh2VpJJa-4RFRCl1TKFbs9_EXvQvBkm9n3o_b7hkPzm6OJOZqYI5p3B3Py6CmQ9tj9I9_8LR-lZjZW_gBHhm99</recordid><startdate>19900801</startdate><enddate>19900801</enddate><creator>Goodale, J. W</creator><creator>Evans, D. K</creator><creator>Ivanco, M</creator><creator>McAlpine, Robert D</creator><general>NRC Research Press</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19900801</creationdate><title>The mechanism of the infrared laser induced multiphoton decomposition of ethyl alcohol</title><author>Goodale, J. W ; Evans, D. K ; Ivanco, M ; McAlpine, Robert D</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c254t-8f5d7a29cc707c0906dab33256921aeb34d4c9096efade3bf3e61713cc92a6e63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1990</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Goodale, J. W</creatorcontrib><creatorcontrib>Evans, D. K</creatorcontrib><creatorcontrib>Ivanco, M</creatorcontrib><creatorcontrib>McAlpine, Robert D</creatorcontrib><collection>CrossRef</collection><jtitle>Canadian journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Goodale, J. W</au><au>Evans, D. K</au><au>Ivanco, M</au><au>McAlpine, Robert D</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The mechanism of the infrared laser induced multiphoton decomposition of ethyl alcohol</atitle><jtitle>Canadian journal of chemistry</jtitle><addtitle>Revue canadienne de chimie</addtitle><date>1990-08-01</date><risdate>1990</risdate><volume>68</volume><issue>8</issue><spage>1437</spage><epage>1439</epage><pages>1437-1439</pages><issn>0008-4042</issn><eissn>1480-3291</eissn><abstract>The infrared laser induced multiphoton decomposition of ethyl alcohol has been studied in experiments with iodine as a radical scavenger and the deuterium substituted form CH
3
CD
2
OH of the alcohol. These experiments show that the principal product, C
2
H
4
, arises from a concerted molecular elimination, as do most of the CH
4
and CH
3
CHO. The C
2
H
6
product results from recombination of the nascent methyl radicals formed in the minor bond breaking channel. Keywords: ethyl alcohol, multiphoton decomposition.</abstract><cop>Ottawa, Canada</cop><pub>NRC Research Press</pub><doi>10.1139/v90-219</doi><tpages>3</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0008-4042 |
| ispartof | Canadian journal of chemistry, 1990-08, Vol.68 (8), p.1437-1439 |
| issn | 0008-4042 1480-3291 |
| language | eng |
| recordid | cdi_crossref_primary_10_1139_v90_219 |
| source | NRC Research Press; EZB-FREE-00999 freely available EZB journals; Free Full-Text Journals in Chemistry |
| title | The mechanism of the infrared laser induced multiphoton decomposition of ethyl alcohol |
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