Photochemistry of 2-azido-2-alkyl-3-oxobutanoic esters and amides

Photolysis of 2-alkyl-2-azido-3-oxobutanoic esters and amides gave products resulting from alkyl or acyl migration onto nitrogen. The resulting ketimimes could be isolated in moderate purity, but the N-acyl imines were rapidly converted into solvation products or enamides (N-acetyl dehydroamino acid...

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Veröffentlicht in:	Canadian journal of chemistry 1990-08, Vol.68 (8), p.1425-1436
Hauptverfasser:	Edwards, Oliver E, Rank, Werner
Format:	Artikel
Sprache:	eng
Schlagworte:	Aliphatic compounds Chemistry Exact sciences and technology Organic chemistry Preparations and properties
Online-Zugang:	Volltext
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