One-electron transfer processes in the reaction of elemental gallium, indium, and tin with tetrahalogeno-ortho-benzoquinones
Tin reacts with tetrahalogeno-o-benzoquinones X 4 C 6 O 2 (X = Cl, Br) in refluxing toluene to give the tin(IV) catecholato species Sn(O 2 C 6 X 4 ) 2 , and neutral and anionic derivatives have also been obtained. A mixture of Sn + X 4 C 6 O 2 -o + I 2 + 1,10-phenanthroline (phen) yields SnI 2 (O 2...
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| Veröffentlicht in: | Canadian journal of chemistry 1989-11, Vol.67 (11), p.1807-1814 |
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| container_title | Canadian journal of chemistry |
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| creator | Annan, Theodore A Tuck, Dennis G |
| description | Tin reacts with tetrahalogeno-o-benzoquinones X
4
C
6
O
2
(X = Cl, Br) in refluxing toluene to give the tin(IV) catecholato species Sn(O
2
C
6
X
4
)
2
, and neutral and anionic derivatives have also been obtained. A mixture of Sn + X
4
C
6
O
2
-o + I
2
+ 1,10-phenanthroline (phen) yields SnI
2
(O
2
C
6
X
4
)phen. With gallium or indium (= M), the corresponding experiments give derivatives of M
II
(e.g., [M(O
2
C
6
X
4
)phen]
2
), or M
III
(e.g., MI(O
2
C
6
X
4
)phen). Intermediate paramagnetic species were detected in the case of
, and a reaction mechanism involving one-electron transfer processes is proposed on the basis of these results. Solvated crystals of the compound InCl(O
2
C
6
Cl
4
)(C
6
H
7
N)
3
were obtained from CH
2
Cl
2
solution, and the structure of this molecule has been determined by X-ray crystallographic methods. Keywords: gallium, indium, tin, benzoquinones, oxidation. |
| doi_str_mv | 10.1139/v89-280 |
| format | Article |
| fullrecord | <record><control><sourceid>pascalfrancis_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1139_v89_280</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>19565633</sourcerecordid><originalsourceid>FETCH-LOGICAL-c284t-a91894b917379e98b075c4678942b30ed832fcffb0a625f396cafee616d4110e3</originalsourceid><addsrcrecordid>eNp10MtKAzEUBuAgCtYqvkI2KojRXOaWpRRvIHSj6yGTOemMTJMxSRXFhzfaoiC4OuTwnT_wI3TI6DljQl68VJLwim6hCcsqSgSXbBtNKKUVyWjGd9FeCE_pWVKeT9DH3AKBAXT0zuLolQ0GPB690xACBNynbQfYg9KxT8QZnPgSbFQDXqhh6FfLs6Ta76lsi2M6ee1jhyOkvE4NbgHWEedj50gD9t09r3rrLIR9tGPUEOBgM6fo8frqYXZL7uc3d7PLe6J5lUWiJKtk1khWilKCrBpa5joryrTkjaDQVoIbbUxDVcFzI2ShlQEoWNFmjFEQU3SyztXeheDB1KPvl8q_1YzWX6XVqbQ6lZbk0VqOKmg1mNSH7sMvl3mRF0Ikd7x21msPAZTX3Y_ahNVjaxI8_R_-_f0TLvqKMQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>One-electron transfer processes in the reaction of elemental gallium, indium, and tin with tetrahalogeno-ortho-benzoquinones</title><source>NRC Research Press</source><source>EZB-FREE-00999 freely available EZB journals</source><source>Free Full-Text Journals in Chemistry</source><creator>Annan, Theodore A ; Tuck, Dennis G</creator><creatorcontrib>Annan, Theodore A ; Tuck, Dennis G</creatorcontrib><description>Tin reacts with tetrahalogeno-o-benzoquinones X
4
C
6
O
2
(X = Cl, Br) in refluxing toluene to give the tin(IV) catecholato species Sn(O
2
C
6
X
4
)
2
, and neutral and anionic derivatives have also been obtained. A mixture of Sn + X
4
C
6
O
2
-o + I
2
+ 1,10-phenanthroline (phen) yields SnI
2
(O
2
C
6
X
4
)phen. With gallium or indium (= M), the corresponding experiments give derivatives of M
II
(e.g., [M(O
2
C
6
X
4
)phen]
2
), or M
III
(e.g., MI(O
2
C
6
X
4
)phen). Intermediate paramagnetic species were detected in the case of
, and a reaction mechanism involving one-electron transfer processes is proposed on the basis of these results. Solvated crystals of the compound InCl(O
2
C
6
Cl
4
)(C
6
H
7
N)
3
were obtained from CH
2
Cl
2
solution, and the structure of this molecule has been determined by X-ray crystallographic methods. Keywords: gallium, indium, tin, benzoquinones, oxidation.</description><identifier>ISSN: 0008-4042</identifier><identifier>EISSN: 1480-3291</identifier><identifier>DOI: 10.1139/v89-280</identifier><identifier>CODEN: CJCHAG</identifier><language>eng</language><publisher>Ottawa, Canada: NRC Research Press</publisher><subject>Chemistry ; Exact sciences and technology ; Ge, sn, pb derivatives ; Organic chemistry ; Organometalloidal and organometallic compounds ; Preparations and properties</subject><ispartof>Canadian journal of chemistry, 1989-11, Vol.67 (11), p.1807-1814</ispartof><rights>1991 INIST-CNRS</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c284t-a91894b917379e98b075c4678942b30ed832fcffb0a625f396cafee616d4110e3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://cdnsciencepub.com/doi/pdf/10.1139/v89-280$$EPDF$$P50$$Gnrcresearch$$H</linktopdf><linktohtml>$$Uhttps://cdnsciencepub.com/doi/full/10.1139/v89-280$$EHTML$$P50$$Gnrcresearch$$H</linktohtml><link.rule.ids>314,776,780,2919,27901,27902,64401,64979</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=19565633$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Annan, Theodore A</creatorcontrib><creatorcontrib>Tuck, Dennis G</creatorcontrib><title>One-electron transfer processes in the reaction of elemental gallium, indium, and tin with tetrahalogeno-ortho-benzoquinones</title><title>Canadian journal of chemistry</title><addtitle>Revue canadienne de chimie</addtitle><description>Tin reacts with tetrahalogeno-o-benzoquinones X
4
C
6
O
2
(X = Cl, Br) in refluxing toluene to give the tin(IV) catecholato species Sn(O
2
C
6
X
4
)
2
, and neutral and anionic derivatives have also been obtained. A mixture of Sn + X
4
C
6
O
2
-o + I
2
+ 1,10-phenanthroline (phen) yields SnI
2
(O
2
C
6
X
4
)phen. With gallium or indium (= M), the corresponding experiments give derivatives of M
II
(e.g., [M(O
2
C
6
X
4
)phen]
2
), or M
III
(e.g., MI(O
2
C
6
X
4
)phen). Intermediate paramagnetic species were detected in the case of
, and a reaction mechanism involving one-electron transfer processes is proposed on the basis of these results. Solvated crystals of the compound InCl(O
2
C
6
Cl
4
)(C
6
H
7
N)
3
were obtained from CH
2
Cl
2
solution, and the structure of this molecule has been determined by X-ray crystallographic methods. Keywords: gallium, indium, tin, benzoquinones, oxidation.</description><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>Ge, sn, pb derivatives</subject><subject>Organic chemistry</subject><subject>Organometalloidal and organometallic compounds</subject><subject>Preparations and properties</subject><issn>0008-4042</issn><issn>1480-3291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1989</creationdate><recordtype>article</recordtype><recordid>eNp10MtKAzEUBuAgCtYqvkI2KojRXOaWpRRvIHSj6yGTOemMTJMxSRXFhzfaoiC4OuTwnT_wI3TI6DljQl68VJLwim6hCcsqSgSXbBtNKKUVyWjGd9FeCE_pWVKeT9DH3AKBAXT0zuLolQ0GPB690xACBNynbQfYg9KxT8QZnPgSbFQDXqhh6FfLs6Ta76lsi2M6ee1jhyOkvE4NbgHWEedj50gD9t09r3rrLIR9tGPUEOBgM6fo8frqYXZL7uc3d7PLe6J5lUWiJKtk1khWilKCrBpa5joryrTkjaDQVoIbbUxDVcFzI2ShlQEoWNFmjFEQU3SyztXeheDB1KPvl8q_1YzWX6XVqbQ6lZbk0VqOKmg1mNSH7sMvl3mRF0Ikd7x21msPAZTX3Y_ahNVjaxI8_R_-_f0TLvqKMQ</recordid><startdate>19891101</startdate><enddate>19891101</enddate><creator>Annan, Theodore A</creator><creator>Tuck, Dennis G</creator><general>NRC Research Press</general><general>National Research Council of Canada</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19891101</creationdate><title>One-electron transfer processes in the reaction of elemental gallium, indium, and tin with tetrahalogeno-ortho-benzoquinones</title><author>Annan, Theodore A ; Tuck, Dennis G</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c284t-a91894b917379e98b075c4678942b30ed832fcffb0a625f396cafee616d4110e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1989</creationdate><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>Ge, sn, pb derivatives</topic><topic>Organic chemistry</topic><topic>Organometalloidal and organometallic compounds</topic><topic>Preparations and properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Annan, Theodore A</creatorcontrib><creatorcontrib>Tuck, Dennis G</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Canadian journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Annan, Theodore A</au><au>Tuck, Dennis G</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>One-electron transfer processes in the reaction of elemental gallium, indium, and tin with tetrahalogeno-ortho-benzoquinones</atitle><jtitle>Canadian journal of chemistry</jtitle><addtitle>Revue canadienne de chimie</addtitle><date>1989-11-01</date><risdate>1989</risdate><volume>67</volume><issue>11</issue><spage>1807</spage><epage>1814</epage><pages>1807-1814</pages><issn>0008-4042</issn><eissn>1480-3291</eissn><coden>CJCHAG</coden><abstract>Tin reacts with tetrahalogeno-o-benzoquinones X
4
C
6
O
2
(X = Cl, Br) in refluxing toluene to give the tin(IV) catecholato species Sn(O
2
C
6
X
4
)
2
, and neutral and anionic derivatives have also been obtained. A mixture of Sn + X
4
C
6
O
2
-o + I
2
+ 1,10-phenanthroline (phen) yields SnI
2
(O
2
C
6
X
4
)phen. With gallium or indium (= M), the corresponding experiments give derivatives of M
II
(e.g., [M(O
2
C
6
X
4
)phen]
2
), or M
III
(e.g., MI(O
2
C
6
X
4
)phen). Intermediate paramagnetic species were detected in the case of
, and a reaction mechanism involving one-electron transfer processes is proposed on the basis of these results. Solvated crystals of the compound InCl(O
2
C
6
Cl
4
)(C
6
H
7
N)
3
were obtained from CH
2
Cl
2
solution, and the structure of this molecule has been determined by X-ray crystallographic methods. Keywords: gallium, indium, tin, benzoquinones, oxidation.</abstract><cop>Ottawa, Canada</cop><pub>NRC Research Press</pub><doi>10.1139/v89-280</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0008-4042 |
| ispartof | Canadian journal of chemistry, 1989-11, Vol.67 (11), p.1807-1814 |
| issn | 0008-4042 1480-3291 |
| language | eng |
| recordid | cdi_crossref_primary_10_1139_v89_280 |
| source | NRC Research Press; EZB-FREE-00999 freely available EZB journals; Free Full-Text Journals in Chemistry |
| subjects | Chemistry Exact sciences and technology Ge, sn, pb derivatives Organic chemistry Organometalloidal and organometallic compounds Preparations and properties |
| title | One-electron transfer processes in the reaction of elemental gallium, indium, and tin with tetrahalogeno-ortho-benzoquinones |
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