Volumetric studies on binary mixtures of some furan derivatives with benzene, chlorobenzene, and bromobenzene at 298.15 K
Molar excess volumes for the binary mixtures of tetrahydrofuran, furan, furfural, and furfuryl alcohol with benzene, chlorobenzene, and bromobenzene have been calculated from precise experimental density data at 298.15 K over the entire composition range. The results have been discussed in light of...
Gespeichert in:
| Veröffentlicht in: | Canadian journal of chemistry 1989-10, Vol.67 (10), p.1672-1675 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1675 |
|---|---|
| container_issue | 10 |
| container_start_page | 1672 |
| container_title | Canadian journal of chemistry |
| container_volume | 67 |
| creator | Naorem, Homendra Suri, S. K |
| description | Molar excess volumes for the binary mixtures of tetrahydrofuran, furan, furfural, and furfuryl alcohol with benzene, chlorobenzene, and bromobenzene have been calculated from precise experimental density data at 298.15 K over the entire composition range. The results have been discussed in light of unlike n-π interactions between the π-electron cloud of the aromatic ring and the oxygen atom of the heterocyclic ring. The substitution of a halogen atom in the aromatic ring activates the molecule for n-π interactions in tetrahydrofuran and furan solutions and deactivates the molecule in furfural and furfuryl alcohol solutions. Keywords: furan derivatives, binary mixtures, excess volumes, n-π interactions, π-π interactions. |
| doi_str_mv | 10.1139/v89-256 |
| format | Article |
| fullrecord | <record><control><sourceid>pascalfrancis_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1139_v89_256</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>6666659</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1986-ccf7ad652da92d4887ef2396727e2b056d440557f10fa775a889e91d5777641e3</originalsourceid><addsrcrecordid>eNp9kEtLAzEUhYMoWKv4F7IQBXFqkplMkqUUX1hwo26HTB40Mo-SzNTXRvyp_hJTpnand3O5534cOAeAQ4wmGKfifMlFQmi-BUY44yhJicDbYIQQ4kmGMrIL9kJ4jidDhI7Ax1Nb9bXpvFMwdL12JsC2gaVrpH-DtXvter-SLAxtbaDtvWygNt4tZeeW8fPiujksTfNuGnMG1bxqfbs5ZaNh6dv6V4Gyg0TwCabfn193-2DHyiqYg_Ueg8ery4fpTTK7v76dXswShQXPE6UskzqnREtBdMY5M5akImeEGVIimussQ5Qyi5GVjFHJuTACa8oYyzNs0jE4GXyVb0PwxhYL7-qYr8CoWHVWxM6K2FkkjwZyIYOSlY1hlQsbPF8NFRE7HbDGq9iOkV7N__E8_hteQ8VC2_QHOAmIlg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Volumetric studies on binary mixtures of some furan derivatives with benzene, chlorobenzene, and bromobenzene at 298.15 K</title><source>NRC Research Press</source><source>EZB-FREE-00999 freely available EZB journals</source><source>Free Full-Text Journals in Chemistry</source><creator>Naorem, Homendra ; Suri, S. K</creator><creatorcontrib>Naorem, Homendra ; Suri, S. K</creatorcontrib><description>Molar excess volumes for the binary mixtures of tetrahydrofuran, furan, furfural, and furfuryl alcohol with benzene, chlorobenzene, and bromobenzene have been calculated from precise experimental density data at 298.15 K over the entire composition range. The results have been discussed in light of unlike n-π interactions between the π-electron cloud of the aromatic ring and the oxygen atom of the heterocyclic ring. The substitution of a halogen atom in the aromatic ring activates the molecule for n-π interactions in tetrahydrofuran and furan solutions and deactivates the molecule in furfural and furfuryl alcohol solutions. Keywords: furan derivatives, binary mixtures, excess volumes, n-π interactions, π-π interactions.</description><identifier>ISSN: 0008-4042</identifier><identifier>EISSN: 1480-3291</identifier><identifier>DOI: 10.1139/v89-256</identifier><identifier>CODEN: CJCHAG</identifier><language>eng</language><publisher>Ottawa, Canada: NRC Research Press</publisher><subject>Chemical thermodynamics ; Chemistry ; Exact sciences and technology ; General and physical chemistry</subject><ispartof>Canadian journal of chemistry, 1989-10, Vol.67 (10), p.1672-1675</ispartof><rights>1990 INIST-CNRS</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1986-ccf7ad652da92d4887ef2396727e2b056d440557f10fa775a889e91d5777641e3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://cdnsciencepub.com/doi/pdf/10.1139/v89-256$$EPDF$$P50$$Gnrcresearch$$H</linktopdf><linktohtml>$$Uhttps://cdnsciencepub.com/doi/full/10.1139/v89-256$$EHTML$$P50$$Gnrcresearch$$H</linktohtml><link.rule.ids>314,780,784,2930,27922,27923,64426,65004</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=6666659$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Naorem, Homendra</creatorcontrib><creatorcontrib>Suri, S. K</creatorcontrib><title>Volumetric studies on binary mixtures of some furan derivatives with benzene, chlorobenzene, and bromobenzene at 298.15 K</title><title>Canadian journal of chemistry</title><addtitle>Revue canadienne de chimie</addtitle><description>Molar excess volumes for the binary mixtures of tetrahydrofuran, furan, furfural, and furfuryl alcohol with benzene, chlorobenzene, and bromobenzene have been calculated from precise experimental density data at 298.15 K over the entire composition range. The results have been discussed in light of unlike n-π interactions between the π-electron cloud of the aromatic ring and the oxygen atom of the heterocyclic ring. The substitution of a halogen atom in the aromatic ring activates the molecule for n-π interactions in tetrahydrofuran and furan solutions and deactivates the molecule in furfural and furfuryl alcohol solutions. Keywords: furan derivatives, binary mixtures, excess volumes, n-π interactions, π-π interactions.</description><subject>Chemical thermodynamics</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><issn>0008-4042</issn><issn>1480-3291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1989</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLAzEUhYMoWKv4F7IQBXFqkplMkqUUX1hwo26HTB40Mo-SzNTXRvyp_hJTpnand3O5534cOAeAQ4wmGKfifMlFQmi-BUY44yhJicDbYIQQ4kmGMrIL9kJ4jidDhI7Ax1Nb9bXpvFMwdL12JsC2gaVrpH-DtXvter-SLAxtbaDtvWygNt4tZeeW8fPiujksTfNuGnMG1bxqfbs5ZaNh6dv6V4Gyg0TwCabfn193-2DHyiqYg_Ueg8ery4fpTTK7v76dXswShQXPE6UskzqnREtBdMY5M5akImeEGVIimussQ5Qyi5GVjFHJuTACa8oYyzNs0jE4GXyVb0PwxhYL7-qYr8CoWHVWxM6K2FkkjwZyIYOSlY1hlQsbPF8NFRE7HbDGq9iOkV7N__E8_hteQ8VC2_QHOAmIlg</recordid><startdate>19891001</startdate><enddate>19891001</enddate><creator>Naorem, Homendra</creator><creator>Suri, S. K</creator><general>NRC Research Press</general><general>National Research Council of Canada</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19891001</creationdate><title>Volumetric studies on binary mixtures of some furan derivatives with benzene, chlorobenzene, and bromobenzene at 298.15 K</title><author>Naorem, Homendra ; Suri, S. K</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1986-ccf7ad652da92d4887ef2396727e2b056d440557f10fa775a889e91d5777641e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1989</creationdate><topic>Chemical thermodynamics</topic><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Naorem, Homendra</creatorcontrib><creatorcontrib>Suri, S. K</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Canadian journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Naorem, Homendra</au><au>Suri, S. K</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Volumetric studies on binary mixtures of some furan derivatives with benzene, chlorobenzene, and bromobenzene at 298.15 K</atitle><jtitle>Canadian journal of chemistry</jtitle><addtitle>Revue canadienne de chimie</addtitle><date>1989-10-01</date><risdate>1989</risdate><volume>67</volume><issue>10</issue><spage>1672</spage><epage>1675</epage><pages>1672-1675</pages><issn>0008-4042</issn><eissn>1480-3291</eissn><coden>CJCHAG</coden><abstract>Molar excess volumes for the binary mixtures of tetrahydrofuran, furan, furfural, and furfuryl alcohol with benzene, chlorobenzene, and bromobenzene have been calculated from precise experimental density data at 298.15 K over the entire composition range. The results have been discussed in light of unlike n-π interactions between the π-electron cloud of the aromatic ring and the oxygen atom of the heterocyclic ring. The substitution of a halogen atom in the aromatic ring activates the molecule for n-π interactions in tetrahydrofuran and furan solutions and deactivates the molecule in furfural and furfuryl alcohol solutions. Keywords: furan derivatives, binary mixtures, excess volumes, n-π interactions, π-π interactions.</abstract><cop>Ottawa, Canada</cop><pub>NRC Research Press</pub><doi>10.1139/v89-256</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0008-4042 |
| ispartof | Canadian journal of chemistry, 1989-10, Vol.67 (10), p.1672-1675 |
| issn | 0008-4042 1480-3291 |
| language | eng |
| recordid | cdi_crossref_primary_10_1139_v89_256 |
| source | NRC Research Press; EZB-FREE-00999 freely available EZB journals; Free Full-Text Journals in Chemistry |
| subjects | Chemical thermodynamics Chemistry Exact sciences and technology General and physical chemistry |
| title | Volumetric studies on binary mixtures of some furan derivatives with benzene, chlorobenzene, and bromobenzene at 298.15 K |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-14T06%3A03%3A49IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pascalfrancis_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Volumetric%20studies%20on%20binary%20mixtures%20of%20some%20furan%20derivatives%20with%20benzene,%20chlorobenzene,%20and%20bromobenzene%20at%20298.15%E2%80%82K&rft.jtitle=Canadian%20journal%20of%20chemistry&rft.au=Naorem,%20Homendra&rft.date=1989-10-01&rft.volume=67&rft.issue=10&rft.spage=1672&rft.epage=1675&rft.pages=1672-1675&rft.issn=0008-4042&rft.eissn=1480-3291&rft.coden=CJCHAG&rft_id=info:doi/10.1139/v89-256&rft_dat=%3Cpascalfrancis_cross%3E6666659%3C/pascalfrancis_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |