Alkaline oxidation of diastereoisomeric 4a,10a-dihydrofusarubins to norjavanicin, fusarubin, and a new antibiotic isofusarubin: nonenzymic formation of products in Fusarium solani cultures

Alkaline oxidation of diastereoisomeric 4a,10a-dihydrofusarubins to norjavanicin, fusarubin, and a new antibiotic isofusarubin: nonenzymic formation of products in Fusarium solani cultures

Conversion of two diastereoisomeric 4a,10a-dihydrofusarubins, produced by Fusariumsolani, to fusarubin, norjavanicin, and a new compound, isofusarubin ((E)-6,7-dihydro-5,8-dihydroxy-2-methoxy-6-methylene-7-(2-oxopropylidene)-1,4-naphthalenedione), has been studied under a variety of culture conditio...

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Veröffentlicht in:Canadian journal of chemistry 1982-12, Vol.60 (23), p.2943-2949
Hauptverfasser: McCulloch, Archibald W., McInnes, A. Gavin, Smith, Donald G., Kurobane, Itsuo, Vining, Leo C.
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container_end_page 2949
container_issue 23
container_start_page 2943
container_title Canadian journal of chemistry
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creator McCulloch, Archibald W.
McInnes, A. Gavin
Smith, Donald G.
Kurobane, Itsuo
Vining, Leo C.
description Conversion of two diastereoisomeric 4a,10a-dihydrofusarubins, produced by Fusariumsolani, to fusarubin, norjavanicin, and a new compound, isofusarubin ((E)-6,7-dihydro-5,8-dihydroxy-2-methoxy-6-methylene-7-(2-oxopropylidene)-1,4-naphthalenedione), has been studied under a variety of culture conditions and in alkaline solution. Antibiotic and phototoxic activities of these compounds were determined and the structures of isofusarubin and of anhydroisofusarubin mono- and diacetates were elucidated by 1 H and 13 C nmr.
doi_str_mv 10.1139/v82-422
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title Alkaline oxidation of diastereoisomeric 4a,10a-dihydrofusarubins to norjavanicin, fusarubin, and a new antibiotic isofusarubin: nonenzymic formation of products in Fusarium solani cultures
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