A new regiospecific synthesis of α,β-unsaturated ketones via acetylene derivatives
The reaction of trialkylalkynylborate salts with benzeneselenenyl chloride, followed by selective oxidation, provides a new synthetic pathway from acetylenes to acyclic trans-α,β-unsaturated ketones. The method is especially useful for preparing unsymmetric acyclic enones which are difficultly acces...
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| Veröffentlicht in: | Canadian journal of chemistry 1978-11, Vol.56 (21), p.2786-2788 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
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| container_end_page | 2788 |
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| container_issue | 21 |
| container_start_page | 2786 |
| container_title | Canadian journal of chemistry |
| container_volume | 56 |
| creator | Hooz, John Mortimer, Richard D |
| description | The reaction of trialkylalkynylborate salts with benzeneselenenyl chloride, followed by selective oxidation, provides a new synthetic pathway from acetylenes to acyclic trans-α,β-unsaturated ketones. The method is especially useful for preparing unsymmetric acyclic enones which are difficultly accessible using current procedures. |
| doi_str_mv | 10.1139/v78-459 |
| format | Article |
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| identifier | ISSN: 0008-4042 |
| ispartof | Canadian journal of chemistry, 1978-11, Vol.56 (21), p.2786-2788 |
| issn | 0008-4042 1480-3291 |
| language | eng |
| recordid | cdi_crossref_primary_10_1139_v78_459 |
| source | NRC Research Press; EZB Free E-Journals; Free Full-Text Journals in Chemistry |
| title | A new regiospecific synthesis of α,β-unsaturated ketones via acetylene derivatives |
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