Complex fluoroanions in solution. IX. BF 3 –anion complexes and their disproportionation
Complex fluoroanions have been prepared with boron trifluoride and perchlorate, nitrate, nitrite, acetate, formate, azide, cyanide, cyanate, thiocyanate, and thiophenolate ions. The complexes formed from the anions of the strong acids, except the hydrogen halides, do not disproportionate to BF 2 (an...
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| Veröffentlicht in: | Canadian journal of chemistry 1978-11, Vol.56 (21), p.2764-2767 |
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| Hauptverfasser: | , |
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| Sprache: | eng |
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| container_end_page | 2767 |
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| container_issue | 21 |
| container_start_page | 2764 |
| container_title | Canadian journal of chemistry |
| container_volume | 56 |
| creator | Brownstein, S. Latremouille, G. |
| description | Complex fluoroanions have been prepared with boron trifluoride and perchlorate, nitrate, nitrite, acetate, formate, azide, cyanide, cyanate, thiocyanate, and thiophenolate ions. The complexes formed from the anions of the strong acids, except the hydrogen halides, do not disproportionate to BF
2
(anion)
2
−
. Complexes of anions of weaker acids may disproportionate and, or, complex a second molecule of BF
3
. Regularities in fluorine–boron coupling constants are tabulated. |
| doi_str_mv | 10.1139/v78-456 |
| format | Article |
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2
(anion)
2
−
. Complexes of anions of weaker acids may disproportionate and, or, complex a second molecule of BF
3
. Regularities in fluorine–boron coupling constants are tabulated.</description><identifier>ISSN: 0008-4042</identifier><identifier>EISSN: 1480-3291</identifier><identifier>DOI: 10.1139/v78-456</identifier><language>eng</language><ispartof>Canadian journal of chemistry, 1978-11, Vol.56 (21), p.2764-2767</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c706-51779ce48b4fbad53e0c18b0bc70e2681f08a9ead14f84b4f77c61cf951447b83</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Brownstein, S.</creatorcontrib><creatorcontrib>Latremouille, G.</creatorcontrib><title>Complex fluoroanions in solution. IX. BF 3 –anion complexes and their disproportionation</title><title>Canadian journal of chemistry</title><description>Complex fluoroanions have been prepared with boron trifluoride and perchlorate, nitrate, nitrite, acetate, formate, azide, cyanide, cyanate, thiocyanate, and thiophenolate ions. The complexes formed from the anions of the strong acids, except the hydrogen halides, do not disproportionate to BF
2
(anion)
2
−
. Complexes of anions of weaker acids may disproportionate and, or, complex a second molecule of BF
3
. Regularities in fluorine–boron coupling constants are tabulated.</description><issn>0008-4042</issn><issn>1480-3291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1978</creationdate><recordtype>article</recordtype><recordid>eNotkEFOwzAQRS0EEqEgruAdq4SZ2ImdJUS0VKrEpgvEJnIcWwSlcWS3CHbcgRtyEhzKZkZ__vy_eIRcI2SIrLp9FzLlRXlCEuQSUpZXeEoSAIhn4Pk5uQjhLUoBeZGQl9rtpsF8UDscnHdq7N0YaD_S4IbDPoqMrp8zer-kjP58ff_5VB8zJlA1dnT_anpPuz5M3k3OzyE1j0tyZtUQzNX_XpDt8mFbP6abp9W6vtukWkCZFihEpQ2XLbet6gpmQKNsoY2uyUuJFqSqjOqQW8njkxC6RG2rAjkXrWQLcnOs1d6F4I1tJt_vlP9sEJqZSBOJNJEI-wXR5FS-</recordid><startdate>19781101</startdate><enddate>19781101</enddate><creator>Brownstein, S.</creator><creator>Latremouille, G.</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19781101</creationdate><title>Complex fluoroanions in solution. IX. BF 3 –anion complexes and their disproportionation</title><author>Brownstein, S. ; Latremouille, G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c706-51779ce48b4fbad53e0c18b0bc70e2681f08a9ead14f84b4f77c61cf951447b83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1978</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Brownstein, S.</creatorcontrib><creatorcontrib>Latremouille, G.</creatorcontrib><collection>CrossRef</collection><jtitle>Canadian journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Brownstein, S.</au><au>Latremouille, G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Complex fluoroanions in solution. IX. BF 3 –anion complexes and their disproportionation</atitle><jtitle>Canadian journal of chemistry</jtitle><date>1978-11-01</date><risdate>1978</risdate><volume>56</volume><issue>21</issue><spage>2764</spage><epage>2767</epage><pages>2764-2767</pages><issn>0008-4042</issn><eissn>1480-3291</eissn><abstract>Complex fluoroanions have been prepared with boron trifluoride and perchlorate, nitrate, nitrite, acetate, formate, azide, cyanide, cyanate, thiocyanate, and thiophenolate ions. The complexes formed from the anions of the strong acids, except the hydrogen halides, do not disproportionate to BF
2
(anion)
2
−
. Complexes of anions of weaker acids may disproportionate and, or, complex a second molecule of BF
3
. Regularities in fluorine–boron coupling constants are tabulated.</abstract><doi>10.1139/v78-456</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0008-4042 |
| ispartof | Canadian journal of chemistry, 1978-11, Vol.56 (21), p.2764-2767 |
| issn | 0008-4042 1480-3291 |
| language | eng |
| recordid | cdi_crossref_primary_10_1139_v78_456 |
| source | NRC Research Press; EZB Free E-Journals; Free Full-Text Journals in Chemistry |
| title | Complex fluoroanions in solution. IX. BF 3 –anion complexes and their disproportionation |
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