The effect of reactant purity on the radiolysis of gaseous ethane and propane
The yields of products formed in the recombination of free radicals in the radiolysis of gaseous ethane and propane have been determined. The yields of butane from ethane radiolysis, and of 2, 3-dimethylbutane from propane radiolysis were found to be much lower than those reported in the literature....
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| Veröffentlicht in: | Canadian journal of chemistry 1977-02, Vol.55 (3), p.463-467 |
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| container_end_page | 467 |
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| container_issue | 3 |
| container_start_page | 463 |
| container_title | Canadian journal of chemistry |
| container_volume | 55 |
| creator | Gawłowski, Janusz Niedzielski, Jan Herman, Jan A |
| description | The yields of products formed in the recombination of free radicals in the radiolysis of gaseous ethane and propane have been determined. The yields of butane from ethane radiolysis, and of 2, 3-dimethylbutane from propane radiolysis were found to be much lower than those reported in the literature.The yields of these products increased markedly in the presence of the traces of water, either desorbed from the walls or introduced with insufficiently dried reagents. The details of experimental procedures warranting the total elimination of water are given. |
| doi_str_mv | 10.1139/v77-068 |
| format | Article |
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The yields of butane from ethane radiolysis, and of 2, 3-dimethylbutane from propane radiolysis were found to be much lower than those reported in the literature.The yields of these products increased markedly in the presence of the traces of water, either desorbed from the walls or introduced with insufficiently dried reagents. 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The yields of butane from ethane radiolysis, and of 2, 3-dimethylbutane from propane radiolysis were found to be much lower than those reported in the literature.The yields of these products increased markedly in the presence of the traces of water, either desorbed from the walls or introduced with insufficiently dried reagents. The details of experimental procedures warranting the total elimination of water are given.</abstract><cop>Ottawa, Canada</cop><pub>NRC Research Press</pub><doi>10.1139/v77-068</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Canadian journal of chemistry, 1977-02, Vol.55 (3), p.463-467 |
| issn | 0008-4042 1480-3291 |
| language | eng |
| recordid | cdi_crossref_primary_10_1139_v77_068 |
| source | NRC Research Press; EZB-FREE-00999 freely available EZB journals; Free Full-Text Journals in Chemistry |
| title | The effect of reactant purity on the radiolysis of gaseous ethane and propane |
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