MASS SPECTROMETRIC STUDY OF SUBLIMING SELENIUM
In the mass spectrum of the vapor from grey selenium subliming in the temperature range 102 to 187 °C all possible Se n + ions between n = 1 and n = 8 were detected in measurable quantities. The ions Se 5 + , Se 6 + , Se 7 + , and Se 8 + arise mainly from ionization of the corresponding parent molec...
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| Veröffentlicht in: | Canadian journal of chemistry 1966-12, Vol.44 (24), p.3063-3071 |
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| container_title | Canadian journal of chemistry |
| container_volume | 44 |
| creator | Fujisaki, H Westmore, J. B Tickner, A. W |
| description | In the mass spectrum of the vapor from grey selenium subliming in the temperature range 102 to 187 °C all possible Se
n
+
ions between n = 1 and n = 8 were detected in measurable quantities. The ions Se
5
+
, Se
6
+
, Se
7
+
, and Se
8
+
arise mainly from ionization of the corresponding parent molecules, which are believed to be cyclic. At 175 °C the composition of the vapor is Se
5
≤ 29.0%, Se
6
≥ 57.5%, Se
7
≥ 11.4%, and Se
8
≥ 2.0%. Thermodynamic data are reported for the sublimation of these molecules. Small amounts of Se
9
+
and Se
10
+
were also detected. |
| doi_str_mv | 10.1139/v66-448 |
| format | Article |
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n
+
ions between n = 1 and n = 8 were detected in measurable quantities. The ions Se
5
+
, Se
6
+
, Se
7
+
, and Se
8
+
arise mainly from ionization of the corresponding parent molecules, which are believed to be cyclic. At 175 °C the composition of the vapor is Se
5
≤ 29.0%, Se
6
≥ 57.5%, Se
7
≥ 11.4%, and Se
8
≥ 2.0%. Thermodynamic data are reported for the sublimation of these molecules. Small amounts of Se
9
+
and Se
10
+
were also detected.</description><identifier>ISSN: 0008-4042</identifier><identifier>EISSN: 1480-3291</identifier><identifier>DOI: 10.1139/v66-448</identifier><language>eng</language><publisher>Ottawa, Canada: NRC Research Press</publisher><ispartof>Canadian journal of chemistry, 1966-12, Vol.44 (24), p.3063-3071</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c287t-b4521cdcacacca39c25a6c8ae5e92c8220e52b32ba9bc5d9a0d13dcca26e15243</citedby><cites>FETCH-LOGICAL-c287t-b4521cdcacacca39c25a6c8ae5e92c8220e52b32ba9bc5d9a0d13dcca26e15243</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://cdnsciencepub.com/doi/pdf/10.1139/v66-448$$EPDF$$P50$$Gnrcresearch$$H</linktopdf><linktohtml>$$Uhttps://cdnsciencepub.com/doi/full/10.1139/v66-448$$EHTML$$P50$$Gnrcresearch$$H</linktohtml><link.rule.ids>314,780,784,2932,27924,27925,64428,65234</link.rule.ids></links><search><creatorcontrib>Fujisaki, H</creatorcontrib><creatorcontrib>Westmore, J. B</creatorcontrib><creatorcontrib>Tickner, A. W</creatorcontrib><title>MASS SPECTROMETRIC STUDY OF SUBLIMING SELENIUM</title><title>Canadian journal of chemistry</title><addtitle>Revue canadienne de chimie</addtitle><description>In the mass spectrum of the vapor from grey selenium subliming in the temperature range 102 to 187 °C all possible Se
n
+
ions between n = 1 and n = 8 were detected in measurable quantities. The ions Se
5
+
, Se
6
+
, Se
7
+
, and Se
8
+
arise mainly from ionization of the corresponding parent molecules, which are believed to be cyclic. At 175 °C the composition of the vapor is Se
5
≤ 29.0%, Se
6
≥ 57.5%, Se
7
≥ 11.4%, and Se
8
≥ 2.0%. Thermodynamic data are reported for the sublimation of these molecules. Small amounts of Se
9
+
and Se
10
+
were also detected.</description><issn>0008-4042</issn><issn>1480-3291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1966</creationdate><recordtype>article</recordtype><recordid>eNp9z89LwzAUwPEgCs4p_gs9KQiZyUvSpcfZdbPQrrK0B08hTVNU_DESEfzvjWxX5R0eDz48-CJ0ScmMUpbdfqUp5lweoQnlkmAGGT1GE0KIxJxwOEVnIbzEc05ATNCsXiiVqIcib7dNXbTbMk9U2y0fk2aVqO6uKutys05UURWbsqvP0cloXoO7OOwp6lZFm9_jqlmX-aLCFuT8E_dcALWDNXGsYZkFYVIrjRMuAysBiBPQM-hN1lsxZIYMlA2RQuqoAM6m6Hr_1_qPELwb9c4_vxn_rSnRv5k6ZuqYGeXNXr57611wxtunf_DV3_iA9G4Y2Q8JNFyG</recordid><startdate>19661215</startdate><enddate>19661215</enddate><creator>Fujisaki, H</creator><creator>Westmore, J. B</creator><creator>Tickner, A. W</creator><general>NRC Research Press</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19661215</creationdate><title>MASS SPECTROMETRIC STUDY OF SUBLIMING SELENIUM</title><author>Fujisaki, H ; Westmore, J. B ; Tickner, A. W</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c287t-b4521cdcacacca39c25a6c8ae5e92c8220e52b32ba9bc5d9a0d13dcca26e15243</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1966</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fujisaki, H</creatorcontrib><creatorcontrib>Westmore, J. B</creatorcontrib><creatorcontrib>Tickner, A. W</creatorcontrib><collection>CrossRef</collection><jtitle>Canadian journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fujisaki, H</au><au>Westmore, J. B</au><au>Tickner, A. W</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>MASS SPECTROMETRIC STUDY OF SUBLIMING SELENIUM</atitle><jtitle>Canadian journal of chemistry</jtitle><addtitle>Revue canadienne de chimie</addtitle><date>1966-12-15</date><risdate>1966</risdate><volume>44</volume><issue>24</issue><spage>3063</spage><epage>3071</epage><pages>3063-3071</pages><issn>0008-4042</issn><eissn>1480-3291</eissn><abstract>In the mass spectrum of the vapor from grey selenium subliming in the temperature range 102 to 187 °C all possible Se
n
+
ions between n = 1 and n = 8 were detected in measurable quantities. The ions Se
5
+
, Se
6
+
, Se
7
+
, and Se
8
+
arise mainly from ionization of the corresponding parent molecules, which are believed to be cyclic. At 175 °C the composition of the vapor is Se
5
≤ 29.0%, Se
6
≥ 57.5%, Se
7
≥ 11.4%, and Se
8
≥ 2.0%. Thermodynamic data are reported for the sublimation of these molecules. Small amounts of Se
9
+
and Se
10
+
were also detected.</abstract><cop>Ottawa, Canada</cop><pub>NRC Research Press</pub><doi>10.1139/v66-448</doi><tpages>9</tpages></addata></record> |
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| ispartof | Canadian journal of chemistry, 1966-12, Vol.44 (24), p.3063-3071 |
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| language | eng |
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| source | NRC Research Press; EZB-FREE-00999 freely available EZB journals; Free Full-Text Journals in Chemistry |
| title | MASS SPECTROMETRIC STUDY OF SUBLIMING SELENIUM |
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