STUDY OF NITRATION OF N,N′-DISUBSTITUTED HYDRAZINES

STUDY OF NITRATION OF N,N′-DISUBSTITUTED HYDRAZINES

The nitration of N, N′-disubstituted hydrazines (RNH-NHR) by means of nitric acid - acetic anhydride mixtures has been found to yield, in most cases, the azo derivatives (RN = NR). For example, when R = CH 3 , (CH 3 ) 2 (CN)C, CH 3 CO, or C 2 H 5 OCO, azo derivatives were formed. When R = HCO, nitro...

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Veröffentlicht in:Canadian journal of chemistry 1951-02, Vol.29 (2), p.223-227
Hauptverfasser: Picard, Jean P, Boivin, Jean L
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Humans
Hydrazines
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container_title Canadian journal of chemistry
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creator Picard, Jean P
Boivin, Jean L
description The nitration of N, N′-disubstituted hydrazines (RNH-NHR) by means of nitric acid - acetic anhydride mixtures has been found to yield, in most cases, the azo derivatives (RN = NR). For example, when R = CH 3 , (CH 3 ) 2 (CN)C, CH 3 CO, or C 2 H 5 OCO, azo derivatives were formed. When R = HCO, nitrogen, carbon dioxide, and nitrogen oxides were evolved. An exception was observed with N, N′-dibenzoylhydrazine which, under the same conditions, yielded the N, N′-dinitro-N, N′-dibenzoylhydrazine.
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subjects Humans
Hydrazines
title STUDY OF NITRATION OF N,N′-DISUBSTITUTED HYDRAZINES
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