Vitrification of simulator of high-level Na-, Fe-, and Al-containing waste in a cold crucible, and the product properties
Parameters of the process of vitrification of simulator of the slurry of high-level Na-, Fe, and Alcontaining waste (made in the plant in Savannah River, USA) in the presence of lithium borosilicate frits by the method of induction melting in a cold crucible are determined. With the help of X-ray di...
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| Veröffentlicht in: | Inorganic materials : applied research 2011, Vol.2 (3), p.268-277 |
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| container_title | Inorganic materials : applied research |
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| creator | Stefanovsky, S. V. Ptashkin, A. G. Knyazev, O. A. Stefanovskaya, O. I. Nikonov, B. S. Omelianenko, B. I. Marra, J. C. |
| description | Parameters of the process of vitrification of simulator of the slurry of high-level Na-, Fe, and Alcontaining waste (made in the plant in Savannah River, USA) in the presence of lithium borosilicate frits by the method of induction melting in a cold crucible are determined. With the help of X-ray diffraction analysis, optical and electron microscopy, and IR spectroscopy, phase composition of the glassy material obtained is investigated. All the samples cut from different parts of the ingot are composed of U-containing glassy phase and the crystals of spinel. A tendency to enrichment of the lower zone of the ingot with heavier ions of transition and heavy metals as well as its depletion with oxides of lighter elements (Na, Cs, Ca, Al, Si) is observed. |
| doi_str_mv | 10.1134/S2075113311030257 |
| format | Article |
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All the samples cut from different parts of the ingot are composed of U-containing glassy phase and the crystals of spinel. A tendency to enrichment of the lower zone of the ingot with heavier ions of transition and heavy metals as well as its depletion with oxides of lighter elements (Na, Cs, Ca, Al, Si) is observed.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Inorganic Chemistry</subject><subject>Materials Science</subject><subject>New Methods of Treatment and Production of Materials with Required Properties</subject><issn>2075-1133</issn><issn>2075-115X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9UE1LAzEQDaJg0f4Ab_kBRpPshmyPpVgVih4s4m2ZzSZtSpqUJKv035ul4kVwGN588N4wPIRuGL1jrKrv3ziVonQVY7SiXMgzNBlXhDHxcf7bV9Ulmqa0oyUEE7NaTNDx3eZojVWQbfA4GJzsfnCQQxyHrd1sidOf2uEXILd4qQuA7_HcERV8Buut3-AvSFlj6zFgFVyPVRyU7Zw-cfNW40MM_aDyWA86ZqvTNbow4JKe_tQrtF4-rBdPZPX6-LyYr4hiQkgijBF1PTMN0EZpw7tGmoK9EEYaygznknYgZyAF72nJRkLd9UAF77RU1RVip7MqhpSiNu0h2j3EY8toO7rX_nGvaPhJkwrXb3Rsd2GIvnz5j-gb7C9xiQ</recordid><startdate>2011</startdate><enddate>2011</enddate><creator>Stefanovsky, S. 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Res</stitle><date>2011</date><risdate>2011</risdate><volume>2</volume><issue>3</issue><spage>268</spage><epage>277</epage><pages>268-277</pages><issn>2075-1133</issn><eissn>2075-115X</eissn><abstract>Parameters of the process of vitrification of simulator of the slurry of high-level Na-, Fe, and Alcontaining waste (made in the plant in Savannah River, USA) in the presence of lithium borosilicate frits by the method of induction melting in a cold crucible are determined. With the help of X-ray diffraction analysis, optical and electron microscopy, and IR spectroscopy, phase composition of the glassy material obtained is investigated. All the samples cut from different parts of the ingot are composed of U-containing glassy phase and the crystals of spinel. 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| subjects | Chemistry Chemistry and Materials Science Industrial Chemistry/Chemical Engineering Inorganic Chemistry Materials Science New Methods of Treatment and Production of Materials with Required Properties |
| title | Vitrification of simulator of high-level Na-, Fe-, and Al-containing waste in a cold crucible, and the product properties |
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