Experimental evaluation of quinolinium and isoquinolinium derivatives as corrosion inhibitors of mild steel in 0.5 M H2SO4 solution

The 1-methylquinolinium iodide (I) Qui + , I – and 2-methylisoquinolinium iodide iso Qui + , I – were investigated as a corrosion inhibitors for mild steel in sulfuric acid using electrochemical impedance spectroscopy and potentiodynamic polarization techniques. The results indicated that the corros...

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Veröffentlicht in:Protection of metals and physical chemistry of surfaces 2016-07, Vol.52 (4), p.731-736
Hauptverfasser: Elhadi, Said Mohamed, Bilel, Mezhoud, Abdelmalek, Bouraiou, Aissa, Chibani
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Bilel, Mezhoud
Abdelmalek, Bouraiou
Aissa, Chibani
description The 1-methylquinolinium iodide (I) Qui + , I – and 2-methylisoquinolinium iodide iso Qui + , I – were investigated as a corrosion inhibitors for mild steel in sulfuric acid using electrochemical impedance spectroscopy and potentiodynamic polarization techniques. The results indicated that the corrosion inhibition efficiency and extent of surface coverage were increased with increase in inhibitors concentrations. Polarization curves revealed that both inhibitors acted as a mixed-type inhibitor. The thermodynamic parameters were evaluated for corrosion inhibition process. The adsorption of both inhibitors on mild steel surface obeyed Langmuir adsorption isotherm.
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subjects Characterization and Evaluation of Materials
Chemistry and Materials Science
Corrosion and Coatings
Industrial Chemistry/Chemical Engineering
Inorganic Chemistry
Materials Science
Metallic Materials
Physicochemical Problems of Materials Protection
Tribology
title Experimental evaluation of quinolinium and isoquinolinium derivatives as corrosion inhibitors of mild steel in 0.5 M H2SO4 solution
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