Spectroscopic properties of highly concentrated Nd3-doped antimony-phosphate glass for microchip lasers

The alkaline antimony-phosphate glass doped with Nd 3+ was synthesized under different conditions with the controlled content of OH groups. The Nd 2 O 3 concentration varied in the range of 0.2–2.0 mol %; the Sb 2 O 5 concentration was 20 mol %. The absorption and Nd 3+ ion luminescence spectra and...

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Veröffentlicht in:Glass physics and chemistry 2015-03, Vol.41 (2), p.137-144
Hauptverfasser: Dmitryuk, A. V., Anan’ev, A. V., Maksimov, L. V., Savost’yanov, V. A., Tatarintsev, B. V., Zhilin, A. A., Eonsang, Park, Chan-Wook, Baik
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container_end_page 144
container_issue 2
container_start_page 137
container_title Glass physics and chemistry
container_volume 41
creator Dmitryuk, A. V.
Anan’ev, A. V.
Maksimov, L. V.
Savost’yanov, V. A.
Tatarintsev, B. V.
Zhilin, A. A.
Eonsang, Park
Chan-Wook, Baik
description The alkaline antimony-phosphate glass doped with Nd 3+ was synthesized under different conditions with the controlled content of OH groups. The Nd 2 O 3 concentration varied in the range of 0.2–2.0 mol %; the Sb 2 O 5 concentration was 20 mol %. The absorption and Nd 3+ ion luminescence spectra and the absorption spectra of OH groups were obtained. Quenching of the Nd 3+ ion luminescence depending on the Nd 2 O 3 and OH group concentrations was studied. It was found that the optimized spectroscopic and kinetic parameters of glass (emission cross section, emission width, radiative lifetime) are close to the parameters of the SCHOTT GLAS industrial laser glass. It was shown that the immediate environment of Nd 3+ ions is formed by phosphate polyhedra.
doi_str_mv 10.1134/S1087659615020054
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subjects Ceramics
Characterization and Evaluation of Materials
Chemistry and Materials Science
Composites
Glass
Materials Science
Natural Materials
Physical Chemistry
title Spectroscopic properties of highly concentrated Nd3-doped antimony-phosphate glass for microchip lasers
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