Kinetics and mechanism of unimolecular heterolysis of cage-like compounds: XXI. Solvent effect on the realtive rate of heterolysis of 2-methyland 2-phenyl-2-haloadamantanes. Role of activation parameters

The kinetics of heterolysis of 2-chloro-2-methyladamantane, 2-bromo-2-methyladamantane, 2-chloro-2-phenyladamantane, and 2-bromo-2-phenyladamantane in isopropyl alcohol, tert-butyl alcohol, acetonitrile, nitromethane, cyclohexanone, and γ-butyrolactone were studied using the verdazyl technique. The...

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Veröffentlicht in:	Russian journal of organic chemistry 2009-09, Vol.45 (9), p.1336-1343
Hauptverfasser:	Dvorko, G. F, Vasil'kevich, A. I, Koshchii, I. V, Mikhal'chuk, K. V
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry and Materials Science Organic Chemistry
Online-Zugang:	Volltext
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