1-azaacepleiadylene—A novel peri-fused heterocyclic system

1-azaacepleiadylene—A novel peri-fused heterocyclic system

Treatment of 2-aryl-1 H ,4 H -2,3,7,8-tetrahydroacenaphtho[5,6- bc ]azepin-4-one with hydrazine hydrate on heating in ethylene glycol in the presence of alkali resulted in the reduction of the oxo group to CH 2 . Dehydrogenation of the reduction product with 2,3,5,6-tetrachloro-1,4-benzoquinone gave...

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Veröffentlicht in:Russian journal of organic chemistry 2009-06, Vol.45 (6), p.928-933
Hauptverfasser: Mezheritskii, V. V., Antonov, A. N., Tyurin, R. V., Minyaeva, L. G., Lysenko, K. A., Korobov, M. S.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Organic Chemistry
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Zusammenfassung:Treatment of 2-aryl-1 H ,4 H -2,3,7,8-tetrahydroacenaphtho[5,6- bc ]azepin-4-one with hydrazine hydrate on heating in ethylene glycol in the presence of alkali resulted in the reduction of the oxo group to CH 2 . Dehydrogenation of the reduction product with 2,3,5,6-tetrachloro-1,4-benzoquinone gave 2-aryl-1-azaacepleiadylene which is the first representative of a novel peri -fused heterocyclic system.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428009060219