Liquid-phase oxidation of alkyl-substituted cyclohexylbenzenes
The reactivity of alkyl-substituted cyclohexylbenzenes in liquid-phase oxidation was estimated by the k 2 /⇃ k 6 value which considerably decreased as the number of methyl groups in the substrate molecule increased. The observed difference in the reactivity of the title compounds was attributed to t...
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| Veröffentlicht in: | Russian journal of organic chemistry 2008-04, Vol.44 (4), p.553-556 |
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| container_end_page | 556 |
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| container_issue | 4 |
| container_start_page | 553 |
| container_title | Russian journal of organic chemistry |
| container_volume | 44 |
| creator | Koshel’, G. N. Kurganova, E. A. Smirnova, E. V. Koshel’, S. G. Plakhtinskii, V. V. Belysheva, M. S. |
| description | The reactivity of alkyl-substituted cyclohexylbenzenes in liquid-phase oxidation was estimated by the
k
2
/⇃
k
6
value which considerably decreased as the number of methyl groups in the substrate molecule increased. The observed difference in the reactivity of the title compounds was attributed to the degree of coplanarity of intermediate radical species. |
| doi_str_mv | 10.1134/S1070428008040143 |
| format | Article |
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k
2
/⇃
k
6
value which considerably decreased as the number of methyl groups in the substrate molecule increased. The observed difference in the reactivity of the title compounds was attributed to the degree of coplanarity of intermediate radical species.</description><identifier>ISSN: 1070-4280</identifier><identifier>EISSN: 1608-3393</identifier><identifier>DOI: 10.1134/S1070428008040143</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Chemistry ; Chemistry and Materials Science ; Organic Chemistry</subject><ispartof>Russian journal of organic chemistry, 2008-04, Vol.44 (4), p.553-556</ispartof><rights>MAIK Nauka 2008</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c288t-e8e40917cb6ba77cc1d0f6c712e1b42ada0f3bccf90e4794fcde935dc21ed6fe3</citedby><cites>FETCH-LOGICAL-c288t-e8e40917cb6ba77cc1d0f6c712e1b42ada0f3bccf90e4794fcde935dc21ed6fe3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070428008040143$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070428008040143$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Koshel’, G. N.</creatorcontrib><creatorcontrib>Kurganova, E. A.</creatorcontrib><creatorcontrib>Smirnova, E. V.</creatorcontrib><creatorcontrib>Koshel’, S. G.</creatorcontrib><creatorcontrib>Plakhtinskii, V. V.</creatorcontrib><creatorcontrib>Belysheva, M. S.</creatorcontrib><title>Liquid-phase oxidation of alkyl-substituted cyclohexylbenzenes</title><title>Russian journal of organic chemistry</title><addtitle>Russ J Org Chem</addtitle><description>The reactivity of alkyl-substituted cyclohexylbenzenes in liquid-phase oxidation was estimated by the
k
2
/⇃
k
6
value which considerably decreased as the number of methyl groups in the substrate molecule increased. The observed difference in the reactivity of the title compounds was attributed to the degree of coplanarity of intermediate radical species.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Organic Chemistry</subject><issn>1070-4280</issn><issn>1608-3393</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNp9kM1KA0EQhAdRMEYfwNu-wGj3zLg_F0GCGiHgQT0v89NjJq67cWcXsj69E-JN8FQNVV9TFGOXCFeIUl2_IBSgRAlQggJU8ojNMIeSS1nJ43Qnm-_9U3YW4wYAVArN2O0qfI3B8e1aR8q6XXB6CF2bdT7TzcfU8DiaOIRhHMhldrJNt6bd1Bhqv6mleM5OvG4iXfzqnL093L8ulnz1_Pi0uFtxK8py4FSSggoLa3Kji8JadOBzW6AgNEpop8FLY62vgFRRKW8dVfLGWYHkck9yzvDw1_ZdjD35etuHT91PNUK9H6D-M0BixIGJKdu-U19vurFvU81_oB8AIF8E</recordid><startdate>20080401</startdate><enddate>20080401</enddate><creator>Koshel’, G. N.</creator><creator>Kurganova, E. A.</creator><creator>Smirnova, E. V.</creator><creator>Koshel’, S. G.</creator><creator>Plakhtinskii, V. V.</creator><creator>Belysheva, M. S.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20080401</creationdate><title>Liquid-phase oxidation of alkyl-substituted cyclohexylbenzenes</title><author>Koshel’, G. N. ; Kurganova, E. A. ; Smirnova, E. V. ; Koshel’, S. G. ; Plakhtinskii, V. V. ; Belysheva, M. S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c288t-e8e40917cb6ba77cc1d0f6c712e1b42ada0f3bccf90e4794fcde935dc21ed6fe3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Organic Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Koshel’, G. N.</creatorcontrib><creatorcontrib>Kurganova, E. A.</creatorcontrib><creatorcontrib>Smirnova, E. V.</creatorcontrib><creatorcontrib>Koshel’, S. G.</creatorcontrib><creatorcontrib>Plakhtinskii, V. V.</creatorcontrib><creatorcontrib>Belysheva, M. S.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of organic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Koshel’, G. N.</au><au>Kurganova, E. A.</au><au>Smirnova, E. V.</au><au>Koshel’, S. G.</au><au>Plakhtinskii, V. V.</au><au>Belysheva, M. S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Liquid-phase oxidation of alkyl-substituted cyclohexylbenzenes</atitle><jtitle>Russian journal of organic chemistry</jtitle><stitle>Russ J Org Chem</stitle><date>2008-04-01</date><risdate>2008</risdate><volume>44</volume><issue>4</issue><spage>553</spage><epage>556</epage><pages>553-556</pages><issn>1070-4280</issn><eissn>1608-3393</eissn><abstract>The reactivity of alkyl-substituted cyclohexylbenzenes in liquid-phase oxidation was estimated by the
k
2
/⇃
k
6
value which considerably decreased as the number of methyl groups in the substrate molecule increased. The observed difference in the reactivity of the title compounds was attributed to the degree of coplanarity of intermediate radical species.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S1070428008040143</doi><tpages>4</tpages></addata></record> |
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| ispartof | Russian journal of organic chemistry, 2008-04, Vol.44 (4), p.553-556 |
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| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Chemistry Chemistry and Materials Science Organic Chemistry |
| title | Liquid-phase oxidation of alkyl-substituted cyclohexylbenzenes |
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