Acyl iodides in organic synthesis: XI. Unusual N-C bond cleavage in tertiary amines
Acyl iodides reacted with excess primary and secondary amines in a way similar to acyl chlorides, yielding the corresponding carboxylic acid amide and initial amine hydroiodide. Reactions of tertiary amines with acyl iodides were accompanied by cleavage of the N-C bond with formation of the correspo...
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| Veröffentlicht in: | Russian journal of organic chemistry 2008-04, Vol.44 (4), p.481-484 |
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| container_end_page | 484 |
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| container_title | Russian journal of organic chemistry |
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| creator | Voronkov, M. G. Tsyrendorzhieva, I. P. Rakhlin, V. I. |
| description | Acyl iodides reacted with excess primary and secondary amines in a way similar to acyl chlorides, yielding the corresponding carboxylic acid amide and initial amine hydroiodide. Reactions of tertiary amines with acyl iodides were accompanied by cleavage of the N-C bond with formation of the corresponding
N,N
-di(hydrocarbyl)carboxamide and alkyl iodide. In the presence of excess tertiary amine the latter was converted into quaternary tetra(hydrocarbyl)ammonium iodide. |
| doi_str_mv | 10.1134/S1070428008040015 |
| format | Article |
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N,N
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| subjects | Chemistry Chemistry and Materials Science Organic Chemistry |
| title | Acyl iodides in organic synthesis: XI. Unusual N-C bond cleavage in tertiary amines |
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