Empirical method for consideration of solvent effect on the dissociation constants of carboxylic acids
An empirical method was used to calculate 363 dissociation constants of 33 benzoic and acetic acid derivatives in 11 solvents. The relative error in the calculations did not exceed 9.5%, and the average error was no higher than 3%. The calculated values were compared with those obtained by quantum-c...
Gespeichert in:
| Veröffentlicht in: | Russian journal of organic chemistry 2008, Vol.44 (1), p.52-61 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 61 |
|---|---|
| container_issue | 1 |
| container_start_page | 52 |
| container_title | Russian journal of organic chemistry |
| container_volume | 44 |
| creator | Zevatskii, Yu. E Samoilov, D. V |
| description | An empirical method was used to calculate 363 dissociation constants of 33 benzoic and acetic acid derivatives in 11 solvents. The relative error in the calculations did not exceed 9.5%, and the average error was no higher than 3%. The calculated values were compared with those obtained by quantum-chemical and other methods for determination of acid dissociation constants in different solvents. |
| doi_str_mv | 10.1134/S1070428008010065 |
| format | Article |
| fullrecord | <record><control><sourceid>fao_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1134_S1070428008010065</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>US201301941068</sourcerecordid><originalsourceid>FETCH-LOGICAL-c312t-1f93207b59b8c772f1f3c79296ac90ab87126a856eb7114b06a64c6c18d51c123</originalsourceid><addsrcrecordid>eNp9kMFOwzAQRC0EEqXwAZzwDwR27cRxjqgqFKkSh9Jz5Dh26yqNK9sg-vckCjckTrvambcaDSH3CI-IPH_aIJSQMwkgAQFEcUFmKEBmnFf8ctgHORv1a3IT4wEAcsz5jNjl8eSC06qjR5P2vqXWB6p9H11rgkrO99RbGn33ZfpEjbVGJzoc097Q1sXotZtcI5NUn-Lo1yo0_vvcOU2Vdm28JVdWddHc_c452b4sPxarbP3--rZ4XmeaI0sZ2oozKJuiaqQuS2bRcl1WrBJKV6AaWSITShbCNCVi3oBQItdCo2wL1Mj4nOD0VwcfYzC2PgV3VOFcI9RjUfWfogaGTUwcvP3OhPrgP0M_xPwXepggq3ytdsHFerthgBywyhGE5D9GfHRH</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Empirical method for consideration of solvent effect on the dissociation constants of carboxylic acids</title><source>SpringerLink Journals</source><creator>Zevatskii, Yu. E ; Samoilov, D. V</creator><creatorcontrib>Zevatskii, Yu. E ; Samoilov, D. V</creatorcontrib><description>An empirical method was used to calculate 363 dissociation constants of 33 benzoic and acetic acid derivatives in 11 solvents. The relative error in the calculations did not exceed 9.5%, and the average error was no higher than 3%. The calculated values were compared with those obtained by quantum-chemical and other methods for determination of acid dissociation constants in different solvents.</description><identifier>ISSN: 1070-4280</identifier><identifier>EISSN: 1608-3393</identifier><identifier>DOI: 10.1134/S1070428008010065</identifier><language>eng</language><publisher>Dordrecht: Dordrecht : SP MAIK Nauka/Interperiodica</publisher><subject>Chemistry ; Chemistry and Materials Science ; Organic Chemistry</subject><ispartof>Russian journal of organic chemistry, 2008, Vol.44 (1), p.52-61</ispartof><rights>Pleiades Publishing, Ltd. 2008</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c312t-1f93207b59b8c772f1f3c79296ac90ab87126a856eb7114b06a64c6c18d51c123</citedby><cites>FETCH-LOGICAL-c312t-1f93207b59b8c772f1f3c79296ac90ab87126a856eb7114b06a64c6c18d51c123</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070428008010065$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070428008010065$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,4024,27923,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Zevatskii, Yu. E</creatorcontrib><creatorcontrib>Samoilov, D. V</creatorcontrib><title>Empirical method for consideration of solvent effect on the dissociation constants of carboxylic acids</title><title>Russian journal of organic chemistry</title><addtitle>Russ J Org Chem</addtitle><description>An empirical method was used to calculate 363 dissociation constants of 33 benzoic and acetic acid derivatives in 11 solvents. The relative error in the calculations did not exceed 9.5%, and the average error was no higher than 3%. The calculated values were compared with those obtained by quantum-chemical and other methods for determination of acid dissociation constants in different solvents.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Organic Chemistry</subject><issn>1070-4280</issn><issn>1608-3393</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNp9kMFOwzAQRC0EEqXwAZzwDwR27cRxjqgqFKkSh9Jz5Dh26yqNK9sg-vckCjckTrvambcaDSH3CI-IPH_aIJSQMwkgAQFEcUFmKEBmnFf8ctgHORv1a3IT4wEAcsz5jNjl8eSC06qjR5P2vqXWB6p9H11rgkrO99RbGn33ZfpEjbVGJzoc097Q1sXotZtcI5NUn-Lo1yo0_vvcOU2Vdm28JVdWddHc_c452b4sPxarbP3--rZ4XmeaI0sZ2oozKJuiaqQuS2bRcl1WrBJKV6AaWSITShbCNCVi3oBQItdCo2wL1Mj4nOD0VwcfYzC2PgV3VOFcI9RjUfWfogaGTUwcvP3OhPrgP0M_xPwXepggq3ytdsHFerthgBywyhGE5D9GfHRH</recordid><startdate>2008</startdate><enddate>2008</enddate><creator>Zevatskii, Yu. E</creator><creator>Samoilov, D. V</creator><general>Dordrecht : SP MAIK Nauka/Interperiodica</general><general>SP MAIK Nauka/Interperiodica</general><scope>FBQ</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2008</creationdate><title>Empirical method for consideration of solvent effect on the dissociation constants of carboxylic acids</title><author>Zevatskii, Yu. E ; Samoilov, D. V</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c312t-1f93207b59b8c772f1f3c79296ac90ab87126a856eb7114b06a64c6c18d51c123</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Organic Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zevatskii, Yu. E</creatorcontrib><creatorcontrib>Samoilov, D. V</creatorcontrib><collection>AGRIS</collection><collection>CrossRef</collection><jtitle>Russian journal of organic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zevatskii, Yu. E</au><au>Samoilov, D. V</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Empirical method for consideration of solvent effect on the dissociation constants of carboxylic acids</atitle><jtitle>Russian journal of organic chemistry</jtitle><stitle>Russ J Org Chem</stitle><date>2008</date><risdate>2008</risdate><volume>44</volume><issue>1</issue><spage>52</spage><epage>61</epage><pages>52-61</pages><issn>1070-4280</issn><eissn>1608-3393</eissn><abstract>An empirical method was used to calculate 363 dissociation constants of 33 benzoic and acetic acid derivatives in 11 solvents. The relative error in the calculations did not exceed 9.5%, and the average error was no higher than 3%. The calculated values were compared with those obtained by quantum-chemical and other methods for determination of acid dissociation constants in different solvents.</abstract><cop>Dordrecht</cop><pub>Dordrecht : SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S1070428008010065</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1070-4280 |
| ispartof | Russian journal of organic chemistry, 2008, Vol.44 (1), p.52-61 |
| issn | 1070-4280 1608-3393 |
| language | eng |
| recordid | cdi_crossref_primary_10_1134_S1070428008010065 |
| source | SpringerLink Journals |
| subjects | Chemistry Chemistry and Materials Science Organic Chemistry |
| title | Empirical method for consideration of solvent effect on the dissociation constants of carboxylic acids |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-01T13%3A18%3A47IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-fao_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Empirical%20method%20for%20consideration%20of%20solvent%20effect%20on%20the%20dissociation%20constants%20of%20carboxylic%20acids&rft.jtitle=Russian%20journal%20of%20organic%20chemistry&rft.au=Zevatskii,%20Yu.%20E&rft.date=2008&rft.volume=44&rft.issue=1&rft.spage=52&rft.epage=61&rft.pages=52-61&rft.issn=1070-4280&rft.eissn=1608-3393&rft_id=info:doi/10.1134/S1070428008010065&rft_dat=%3Cfao_cross%3EUS201301941068%3C/fao_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |