Thermochemical structural transformations of polyoxadiazoles
Changes in the physical and chemical structure of polyoxadiazole upon high-temperature heat treatment of Arselon fiber in inert and oxidizing atmosphere were studied. The role of the morphological rearrangement of the polymer in the turbostratic nucleation of carbon structures was determined. The me...
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| Veröffentlicht in: | Russian journal of applied chemistry 2015-08, Vol.88 (8), p.1304-1310 |
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| container_title | Russian journal of applied chemistry |
| container_volume | 88 |
| creator | Sazanov, Yu. N. Dobrovol’skaya, I. P. Lysenko, V. A. Sal’nikova, P. Yu Kosyakov, D. S. Pokryshkin, S. A. Fedorova, G. N. Kulikova, E. M. |
| description | Changes in the physical and chemical structure of polyoxadiazole upon high-temperature heat treatment of Arselon fiber in inert and oxidizing atmosphere were studied. The role of the morphological rearrangement of the polymer in the turbostratic nucleation of carbon structures was determined. The mechanism of the thermochemical degradation and intramolecular cyclization of intermediate and final polyheterocyclic compounds formed in the process was elucidated. |
| doi_str_mv | 10.1134/S1070427215080121 |
| format | Article |
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| subjects | Chemistry Chemistry and Materials Science Chemistry/Food Science Industrial Chemistry/Chemical Engineering Macromolecular Compounds and Polymeric Materials |
| title | Thermochemical structural transformations of polyoxadiazoles |
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