Liquid-vapor equilibrium in the dimethyl sulfoxide-methanol system

Liquid-vapor equilibrium in the dimethyl sulfoxide-methanol system

The liquid-vapor phase equilibrium in the dimethyl sulfoxide-methanol binary system was studied with the use of a statistical method. Partial pressures of dimethyl sulfoxide and methanol were calculated by integrating the Gibbs-Duhem equation. Molar excess Gibbs energies were described by the Redlic...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Russian journal of applied chemistry 2012-09, Vol.85 (9), p.1335-1338
Hauptverfasser: Kazoyan, E. A., Khachatryan, A. S.
Format: Artikel
Sprache:eng
Schlagworte:
Applied Electrochemistry and Corrosion Protection of Metals
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Industrial Chemistry/Chemical Engineering
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 1338
container_issue 9
container_start_page 1335
container_title Russian journal of applied chemistry
container_volume 85
creator Kazoyan, E. A.
Khachatryan, A. S.
description The liquid-vapor phase equilibrium in the dimethyl sulfoxide-methanol binary system was studied with the use of a statistical method. Partial pressures of dimethyl sulfoxide and methanol were calculated by integrating the Gibbs-Duhem equation. Molar excess Gibbs energies were described by the Redlich-Kister equation, and correlation parameters were calculated. It was found that molar excess Gibbs energies are negative, and the deviation from ideality increases as temperature increases.
doi_str_mv 10.1134/S1070427212090066
format Article
fullrecord <record><control><sourceid>crossref_sprin</sourceid><recordid>TN_cdi_crossref_primary_10_1134_S1070427212090066</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1134_S1070427212090066</sourcerecordid><originalsourceid>FETCH-LOGICAL-c288t-4ed5702d6e3b2ed17e455466a311a9149e7c025426f0504ebb6771eca83c46403</originalsourceid><addsrcrecordid>eNp9kE9LxDAQxYMouK5-AG_9AtGZNE3aoy7qCgUP6rmk7dTN0j9r0or99qasN8HTPN6b3zA8xq4RbhBjefuKoEEKLVBABqDUCVuhgpTHIlOnQYeYL_k5u_B-DwCZUumK3ef2c7I1_zKHwUUUdGtLZ6cusn007iiqbUfjbm4jP7XN8G1r4oth-iFYsx-pu2RnjWk9Xf3ONXt_fHjbbHn-8vS8uct5JdJ05JLqRIOoFcWloBo1ySSRSpkY0WQoM9IViEQK1UACkspSaY1UmTSupJIQrxke71Zu8N5RUxyc7YybC4RiKaH4U0JgxJHxYbf_IFfsh8n14c1_oB942F4L</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Liquid-vapor equilibrium in the dimethyl sulfoxide-methanol system</title><source>SpringerLink Journals</source><creator>Kazoyan, E. A. ; Khachatryan, A. S.</creator><creatorcontrib>Kazoyan, E. A. ; Khachatryan, A. S.</creatorcontrib><description>The liquid-vapor phase equilibrium in the dimethyl sulfoxide-methanol binary system was studied with the use of a statistical method. Partial pressures of dimethyl sulfoxide and methanol were calculated by integrating the Gibbs-Duhem equation. Molar excess Gibbs energies were described by the Redlich-Kister equation, and correlation parameters were calculated. It was found that molar excess Gibbs energies are negative, and the deviation from ideality increases as temperature increases.</description><identifier>ISSN: 1070-4272</identifier><identifier>EISSN: 1608-3296</identifier><identifier>DOI: 10.1134/S1070427212090066</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Applied Electrochemistry and Corrosion Protection of Metals ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Industrial Chemistry/Chemical Engineering</subject><ispartof>Russian journal of applied chemistry, 2012-09, Vol.85 (9), p.1335-1338</ispartof><rights>Pleiades Publishing, Ltd. 2012</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c288t-4ed5702d6e3b2ed17e455466a311a9149e7c025426f0504ebb6771eca83c46403</citedby><cites>FETCH-LOGICAL-c288t-4ed5702d6e3b2ed17e455466a311a9149e7c025426f0504ebb6771eca83c46403</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070427212090066$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070427212090066$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Kazoyan, E. A.</creatorcontrib><creatorcontrib>Khachatryan, A. S.</creatorcontrib><title>Liquid-vapor equilibrium in the dimethyl sulfoxide-methanol system</title><title>Russian journal of applied chemistry</title><addtitle>Russ J Appl Chem</addtitle><description>The liquid-vapor phase equilibrium in the dimethyl sulfoxide-methanol binary system was studied with the use of a statistical method. Partial pressures of dimethyl sulfoxide and methanol were calculated by integrating the Gibbs-Duhem equation. Molar excess Gibbs energies were described by the Redlich-Kister equation, and correlation parameters were calculated. It was found that molar excess Gibbs energies are negative, and the deviation from ideality increases as temperature increases.</description><subject>Applied Electrochemistry and Corrosion Protection of Metals</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Industrial Chemistry/Chemical Engineering</subject><issn>1070-4272</issn><issn>1608-3296</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp9kE9LxDAQxYMouK5-AG_9AtGZNE3aoy7qCgUP6rmk7dTN0j9r0or99qasN8HTPN6b3zA8xq4RbhBjefuKoEEKLVBABqDUCVuhgpTHIlOnQYeYL_k5u_B-DwCZUumK3ef2c7I1_zKHwUUUdGtLZ6cusn007iiqbUfjbm4jP7XN8G1r4oth-iFYsx-pu2RnjWk9Xf3ONXt_fHjbbHn-8vS8uct5JdJ05JLqRIOoFcWloBo1ySSRSpkY0WQoM9IViEQK1UACkspSaY1UmTSupJIQrxke71Zu8N5RUxyc7YybC4RiKaH4U0JgxJHxYbf_IFfsh8n14c1_oB942F4L</recordid><startdate>20120901</startdate><enddate>20120901</enddate><creator>Kazoyan, E. A.</creator><creator>Khachatryan, A. S.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20120901</creationdate><title>Liquid-vapor equilibrium in the dimethyl sulfoxide-methanol system</title><author>Kazoyan, E. A. ; Khachatryan, A. S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c288t-4ed5702d6e3b2ed17e455466a311a9149e7c025426f0504ebb6771eca83c46403</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Applied Electrochemistry and Corrosion Protection of Metals</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Industrial Chemistry/Chemical Engineering</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kazoyan, E. A.</creatorcontrib><creatorcontrib>Khachatryan, A. S.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of applied chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kazoyan, E. A.</au><au>Khachatryan, A. S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Liquid-vapor equilibrium in the dimethyl sulfoxide-methanol system</atitle><jtitle>Russian journal of applied chemistry</jtitle><stitle>Russ J Appl Chem</stitle><date>2012-09-01</date><risdate>2012</risdate><volume>85</volume><issue>9</issue><spage>1335</spage><epage>1338</epage><pages>1335-1338</pages><issn>1070-4272</issn><eissn>1608-3296</eissn><abstract>The liquid-vapor phase equilibrium in the dimethyl sulfoxide-methanol binary system was studied with the use of a statistical method. Partial pressures of dimethyl sulfoxide and methanol were calculated by integrating the Gibbs-Duhem equation. Molar excess Gibbs energies were described by the Redlich-Kister equation, and correlation parameters were calculated. It was found that molar excess Gibbs energies are negative, and the deviation from ideality increases as temperature increases.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S1070427212090066</doi><tpages>4</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1070-4272
ispartof Russian journal of applied chemistry, 2012-09, Vol.85 (9), p.1335-1338
issn 1070-4272
1608-3296
language eng
recordid cdi_crossref_primary_10_1134_S1070427212090066
source SpringerLink Journals
subjects Applied Electrochemistry and Corrosion Protection of Metals
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Industrial Chemistry/Chemical Engineering
title Liquid-vapor equilibrium in the dimethyl sulfoxide-methanol system
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-03T04%3A56%3A39IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref_sprin&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Liquid-vapor%20equilibrium%20in%20the%20dimethyl%20sulfoxide-methanol%20system&rft.jtitle=Russian%20journal%20of%20applied%20chemistry&rft.au=Kazoyan,%20E.%20A.&rft.date=2012-09-01&rft.volume=85&rft.issue=9&rft.spage=1335&rft.epage=1338&rft.pages=1335-1338&rft.issn=1070-4272&rft.eissn=1608-3296&rft_id=info:doi/10.1134/S1070427212090066&rft_dat=%3Ccrossref_sprin%3E10_1134_S1070427212090066%3C/crossref_sprin%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true