Optimization of the new technology for manufacturing γ-polyoxymethylene

Optimization of the new technology for manufacturing γ-polyoxymethylene

A new technology of manufacturing γ-polyoxymethylene (γ-POM) by the polymerization 1,3,5-trioxane in the presence of a boron trifluoride etherate aprotic catalytic agent and a methylal telogen in the medium of the non-ozone-depleting solvent toluene, with an yield exceeding the yield of γ-POM manufa...

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Veröffentlicht in:Russian journal of general chemistry 2016-06, Vol.86 (6), p.1476-1478
Hauptverfasser: Zinov’ev, V. M., Fedoseev, A. M., Gladkova, O. A.
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Sprache:eng
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Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)
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container_issue 6
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container_title Russian journal of general chemistry
container_volume 86
creator Zinov’ev, V. M.
Fedoseev, A. M.
Gladkova, O. A.
description A new technology of manufacturing γ-polyoxymethylene (γ-POM) by the polymerization 1,3,5-trioxane in the presence of a boron trifluoride etherate aprotic catalytic agent and a methylal telogen in the medium of the non-ozone-depleting solvent toluene, with an yield exceeding the yield of γ-POM manufactured by the existing industrial technology by 30% is developed. Regression equations for the yield and weight-average particle size of γ-POM synthesized in the toluene medium were derived by means of the optimal experimental design technique. The equations were used to optimize parameters of the synthesis and obtain γ-POM with the weight-average particle size of 15 μm and the highest possible yield.
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subjects Chemistry
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Chemistry/Food Science
Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)
title Optimization of the new technology for manufacturing γ-polyoxymethylene
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