State of molybdenum clusters in solutions: III. Formation enthalpies of intermediate products of stepwise K2[Мо2(SO4)4] oxidation in 1 M H2SO4 solution
The enthalpies of stepwise oxidation reactions of the ions [Mo 2 (SO 4 ) 4 ] 4– → [Mo 2 (SO 4 ) 4 ] 3– → [Mo 2 (SO 4 ) 4 ] 2– → [Мо 2 (μ-О) 2 O 2 (Н 2 О) 6 ] 2– → 2(MoO 4 ) 2– , and also the enthalpies of formation of the binuclear molybdenum complexes K 3 [Mo 2 (SO 4 ) 4 ], K 2 [Mo 2 (SO 4 ) 4 ], a...
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| Veröffentlicht in: | Russian journal of general chemistry 2016, Vol.86 (1), p.5-8 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The enthalpies of stepwise oxidation reactions of the ions [Mo
2
(SO
4
)
4
]
4–
→ [Mo
2
(SO
4
)
4
]
3–
→ [Mo
2
(SO
4
)
4
]
2–
→ [Мо
2
(μ-О)
2
O
2
(Н
2
О)
6
]
2–
→ 2(MoO
4
)
2–
, and also the enthalpies of formation of the binuclear molybdenum complexes K
3
[Mo
2
(SO
4
)
4
], K
2
[Mo
2
(SO
4
)
4
], and [Мо
2
(μ-О)
2
O
2
(Н
2
О)
6
]SO
4
in a 1 М sulfuric acid solution at 298.15 K were determined by the calorimetric titration with continuous titrant input. |
|---|---|
| ISSN: | 1070-3632 1608-3350 |
| DOI: | 10.1134/S1070363216010023 |