Synthesis and some transformations of 2-(2-thienyl)-1H-acenaphtho[1,2-d]imidazole
Three-component reaction of acenaphthenequinone, 9,10-thiophene-2-carbaldehyde and ammonium acetate in glacial acetic acid afforded 2-(2-thienyl)-1 H -acenaphtho[1,2- d ]imidazole. Its N -methylated product undergoes electrophilic substitution reactions (nitration, bromination, sulfonation, formylat...
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| Veröffentlicht in: | Russian journal of general chemistry 2014-09, Vol.84 (9), p.1697-1700 |
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| container_title | Russian journal of general chemistry |
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| creator | El’chaninov, M. M. Achkasova, A. A. El’chaninov, I. M. |
| description | Three-component reaction of acenaphthenequinone, 9,10-thiophene-2-carbaldehyde and ammonium acetate in glacial acetic acid afforded 2-(2-thienyl)-1
H
-acenaphtho[1,2-
d
]imidazole. Its
N
-methylated product undergoes electrophilic substitution reactions (nitration, bromination, sulfonation, formylation, acylation) in KOH-1-methyl-2-pyrrolidone mixture. Depending on the reaction conditions electrophilic attack occurred at both thiophene ring and acenaphthene fragment. |
| doi_str_mv | 10.1134/S1070363214090096 |
| format | Article |
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H
-acenaphtho[1,2-
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]imidazole. Its
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-methylated product undergoes electrophilic substitution reactions (nitration, bromination, sulfonation, formylation, acylation) in KOH-1-methyl-2-pyrrolidone mixture. Depending on the reaction conditions electrophilic attack occurred at both thiophene ring and acenaphthene fragment.</description><identifier>ISSN: 1070-3632</identifier><identifier>EISSN: 1608-3350</identifier><identifier>DOI: 10.1134/S1070363214090096</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science</subject><ispartof>Russian journal of general chemistry, 2014-09, Vol.84 (9), p.1697-1700</ispartof><rights>Pleiades Publishing, Ltd. 2014</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c288t-85ac421f119434485d55c18c41f9bff30c2a769b642063d6189a84f5f947750d3</citedby><cites>FETCH-LOGICAL-c288t-85ac421f119434485d55c18c41f9bff30c2a769b642063d6189a84f5f947750d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070363214090096$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070363214090096$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>El’chaninov, M. M.</creatorcontrib><creatorcontrib>Achkasova, A. A.</creatorcontrib><creatorcontrib>El’chaninov, I. M.</creatorcontrib><title>Synthesis and some transformations of 2-(2-thienyl)-1H-acenaphtho[1,2-d]imidazole</title><title>Russian journal of general chemistry</title><addtitle>Russ J Gen Chem</addtitle><description>Three-component reaction of acenaphthenequinone, 9,10-thiophene-2-carbaldehyde and ammonium acetate in glacial acetic acid afforded 2-(2-thienyl)-1
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-acenaphtho[1,2-
d
]imidazole. Its
N
-methylated product undergoes electrophilic substitution reactions (nitration, bromination, sulfonation, formylation, acylation) in KOH-1-methyl-2-pyrrolidone mixture. Depending on the reaction conditions electrophilic attack occurred at both thiophene ring and acenaphthene fragment.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070363214090096</doi><tpages>4</tpages></addata></record> |
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| source | SpringerNature Journals |
| subjects | Chemistry Chemistry and Materials Science Chemistry/Food Science |
| title | Synthesis and some transformations of 2-(2-thienyl)-1H-acenaphtho[1,2-d]imidazole |
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