Catalase activity of cobalt(II) complexes with N,N,N′,N′-tetrasubstituted thiocarbamoylsulfenamides
On the base of the kinetic and activation parameters of the hydrogen peroxide decomposition in the presence of chelates of CoX 2 salts (X = Cl, Br, I, NCS) with N,N,N′,N′ -tetrasubstituted thiocarbamoylsulfenamides containing exocyclic (out-of-chelate) fragments of dimethylamine ( I ), piperidine (...
Gespeichert in:
| Veröffentlicht in: | Russian journal of general chemistry 2013-05, Vol.83 (5), p.915-927 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 927 |
|---|---|
| container_issue | 5 |
| container_start_page | 915 |
| container_title | Russian journal of general chemistry |
| container_volume | 83 |
| creator | Chihichin, D. G. Kotseruba, V. A. Levchenko, O. A. Masanovets, G. N. Seyfullina, I. I. Kamalov, G. L. |
| description | On the base of the kinetic and activation parameters of the hydrogen peroxide decomposition in the presence of chelates of CoX
2
salts (X = Cl, Br, I, NCS) with
N,N,N′,N′
-tetrasubstituted thiocarbamoylsulfenamides containing exocyclic (out-of-chelate) fragments of dimethylamine (
I
), piperidine (
II
), and piperazine (
III
) the nature of acido-ligands influence on catalase activity of complexes
I–III
was revealed, depending on the structure and composition of the chelating ligand. Mononuclear complexes
I
(Br) and
II
(Br) can transform into 10-membered binuclear macrochelate intermediates. |
| doi_str_mv | 10.1134/S107036321305006X |
| format | Article |
| fullrecord | <record><control><sourceid>crossref_sprin</sourceid><recordid>TN_cdi_crossref_primary_10_1134_S107036321305006X</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1134_S107036321305006X</sourcerecordid><originalsourceid>FETCH-LOGICAL-c288t-84ca83f24b00b885be6adeeda2425a8f4c0185b1db4282749753023a4b6f9903</originalsourceid><addsrcrecordid>eNp9UE1LAzEQDaJgrf4Ab3tUcHXysdv0KMWPgujBHrwtk2zSpux2S5JVe_M3-ZP8JabWmyADM4957w3DI-SUwiWlXFw9UxgBLzmjHAqA8mWPDGgJMue8gP2EE51v-UNyFMISgCYRG5D5BCM2GEyGOrpXFzdZZzPdKWzi2XR6nmC7bsy7Cdmbi4vs8SLV18fnT8ujiR5Dr0J0sY-mzuLCdRq9wrbbNKFvrFlh62oTjsmBxSaYk985JLPbm9nkPn94uptOrh9yzaSMuRQaJbdMKAAlZaFMibUxNTLBCpRWaKBpS2slmGQjMR4VHBhHoUo7HgMfEro7q30Xgje2WnvXot9UFKptUNWfoJKH7TwhaVdz46tl1_tV-vIf0zcbiW2F</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Catalase activity of cobalt(II) complexes with N,N,N′,N′-tetrasubstituted thiocarbamoylsulfenamides</title><source>SpringerLink Journals</source><creator>Chihichin, D. G. ; Kotseruba, V. A. ; Levchenko, O. A. ; Masanovets, G. N. ; Seyfullina, I. I. ; Kamalov, G. L.</creator><creatorcontrib>Chihichin, D. G. ; Kotseruba, V. A. ; Levchenko, O. A. ; Masanovets, G. N. ; Seyfullina, I. I. ; Kamalov, G. L.</creatorcontrib><description>On the base of the kinetic and activation parameters of the hydrogen peroxide decomposition in the presence of chelates of CoX
2
salts (X = Cl, Br, I, NCS) with
N,N,N′,N′
-tetrasubstituted thiocarbamoylsulfenamides containing exocyclic (out-of-chelate) fragments of dimethylamine (
I
), piperidine (
II
), and piperazine (
III
) the nature of acido-ligands influence on catalase activity of complexes
I–III
was revealed, depending on the structure and composition of the chelating ligand. Mononuclear complexes
I
(Br) and
II
(Br) can transform into 10-membered binuclear macrochelate intermediates.</description><identifier>ISSN: 1070-3632</identifier><identifier>EISSN: 1608-3350</identifier><identifier>DOI: 10.1134/S107036321305006X</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science</subject><ispartof>Russian journal of general chemistry, 2013-05, Vol.83 (5), p.915-927</ispartof><rights>Pleiades Publishing, Ltd. 2013</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c288t-84ca83f24b00b885be6adeeda2425a8f4c0185b1db4282749753023a4b6f9903</citedby><cites>FETCH-LOGICAL-c288t-84ca83f24b00b885be6adeeda2425a8f4c0185b1db4282749753023a4b6f9903</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S107036321305006X$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S107036321305006X$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Chihichin, D. G.</creatorcontrib><creatorcontrib>Kotseruba, V. A.</creatorcontrib><creatorcontrib>Levchenko, O. A.</creatorcontrib><creatorcontrib>Masanovets, G. N.</creatorcontrib><creatorcontrib>Seyfullina, I. I.</creatorcontrib><creatorcontrib>Kamalov, G. L.</creatorcontrib><title>Catalase activity of cobalt(II) complexes with N,N,N′,N′-tetrasubstituted thiocarbamoylsulfenamides</title><title>Russian journal of general chemistry</title><addtitle>Russ J Gen Chem</addtitle><description>On the base of the kinetic and activation parameters of the hydrogen peroxide decomposition in the presence of chelates of CoX
2
salts (X = Cl, Br, I, NCS) with
N,N,N′,N′
-tetrasubstituted thiocarbamoylsulfenamides containing exocyclic (out-of-chelate) fragments of dimethylamine (
I
), piperidine (
II
), and piperazine (
III
) the nature of acido-ligands influence on catalase activity of complexes
I–III
was revealed, depending on the structure and composition of the chelating ligand. Mononuclear complexes
I
(Br) and
II
(Br) can transform into 10-membered binuclear macrochelate intermediates.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><issn>1070-3632</issn><issn>1608-3350</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp9UE1LAzEQDaJgrf4Ab3tUcHXysdv0KMWPgujBHrwtk2zSpux2S5JVe_M3-ZP8JabWmyADM4957w3DI-SUwiWlXFw9UxgBLzmjHAqA8mWPDGgJMue8gP2EE51v-UNyFMISgCYRG5D5BCM2GEyGOrpXFzdZZzPdKWzi2XR6nmC7bsy7Cdmbi4vs8SLV18fnT8ujiR5Dr0J0sY-mzuLCdRq9wrbbNKFvrFlh62oTjsmBxSaYk985JLPbm9nkPn94uptOrh9yzaSMuRQaJbdMKAAlZaFMibUxNTLBCpRWaKBpS2slmGQjMR4VHBhHoUo7HgMfEro7q30Xgje2WnvXot9UFKptUNWfoJKH7TwhaVdz46tl1_tV-vIf0zcbiW2F</recordid><startdate>20130501</startdate><enddate>20130501</enddate><creator>Chihichin, D. G.</creator><creator>Kotseruba, V. A.</creator><creator>Levchenko, O. A.</creator><creator>Masanovets, G. N.</creator><creator>Seyfullina, I. I.</creator><creator>Kamalov, G. L.</creator><general>Springer US</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20130501</creationdate><title>Catalase activity of cobalt(II) complexes with N,N,N′,N′-tetrasubstituted thiocarbamoylsulfenamides</title><author>Chihichin, D. G. ; Kotseruba, V. A. ; Levchenko, O. A. ; Masanovets, G. N. ; Seyfullina, I. I. ; Kamalov, G. L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c288t-84ca83f24b00b885be6adeeda2425a8f4c0185b1db4282749753023a4b6f9903</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chihichin, D. G.</creatorcontrib><creatorcontrib>Kotseruba, V. A.</creatorcontrib><creatorcontrib>Levchenko, O. A.</creatorcontrib><creatorcontrib>Masanovets, G. N.</creatorcontrib><creatorcontrib>Seyfullina, I. I.</creatorcontrib><creatorcontrib>Kamalov, G. L.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of general chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chihichin, D. G.</au><au>Kotseruba, V. A.</au><au>Levchenko, O. A.</au><au>Masanovets, G. N.</au><au>Seyfullina, I. I.</au><au>Kamalov, G. L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Catalase activity of cobalt(II) complexes with N,N,N′,N′-tetrasubstituted thiocarbamoylsulfenamides</atitle><jtitle>Russian journal of general chemistry</jtitle><stitle>Russ J Gen Chem</stitle><date>2013-05-01</date><risdate>2013</risdate><volume>83</volume><issue>5</issue><spage>915</spage><epage>927</epage><pages>915-927</pages><issn>1070-3632</issn><eissn>1608-3350</eissn><abstract>On the base of the kinetic and activation parameters of the hydrogen peroxide decomposition in the presence of chelates of CoX
2
salts (X = Cl, Br, I, NCS) with
N,N,N′,N′
-tetrasubstituted thiocarbamoylsulfenamides containing exocyclic (out-of-chelate) fragments of dimethylamine (
I
), piperidine (
II
), and piperazine (
III
) the nature of acido-ligands influence on catalase activity of complexes
I–III
was revealed, depending on the structure and composition of the chelating ligand. Mononuclear complexes
I
(Br) and
II
(Br) can transform into 10-membered binuclear macrochelate intermediates.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1134/S107036321305006X</doi><tpages>13</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1070-3632 |
| ispartof | Russian journal of general chemistry, 2013-05, Vol.83 (5), p.915-927 |
| issn | 1070-3632 1608-3350 |
| language | eng |
| recordid | cdi_crossref_primary_10_1134_S107036321305006X |
| source | SpringerLink Journals |
| subjects | Chemistry Chemistry and Materials Science Chemistry/Food Science |
| title | Catalase activity of cobalt(II) complexes with N,N,N′,N′-tetrasubstituted thiocarbamoylsulfenamides |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-05T14%3A40%3A35IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref_sprin&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Catalase%20activity%20of%20cobalt(II)%20complexes%20with%20N,N,N%E2%80%B2,N%E2%80%B2-tetrasubstituted%20thiocarbamoylsulfenamides&rft.jtitle=Russian%20journal%20of%20general%20chemistry&rft.au=Chihichin,%20D.%20G.&rft.date=2013-05-01&rft.volume=83&rft.issue=5&rft.spage=915&rft.epage=927&rft.pages=915-927&rft.issn=1070-3632&rft.eissn=1608-3350&rft_id=info:doi/10.1134/S107036321305006X&rft_dat=%3Ccrossref_sprin%3E10_1134_S107036321305006X%3C/crossref_sprin%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |