Investigation of addition mechanism of diazoles to vinylorganosilanes by methods of quantum chemistry

The behavior of pyrazole and imidazole in the reactions with vinyltrimethoxysilane and vinylsilatrane in the presence of the catalytic amount of lithium was studied by the B3LYP/6-311G(d,p) method. It is established that these processes are accompanied by the formation of lithium salts of diazoles....

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Veröffentlicht in:	Russian journal of general chemistry 2012-03, Vol.82 (3), p.468-475
Hauptverfasser:	Knyazev, S. P., Gordeev, E. G., Belova, L. O., Abramkin, A. M., Sheludyakov, V. D., Panfilova, V. M., Pletneva, M. V., Kirilin, A. D.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry and Materials Science Chemistry/Food Science
Online-Zugang:	Volltext
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