Ion-exchange reactions in the structure of perovskite-like layered oxides: I. Protonation of NaNdTiO4 complex oxide
The behavior of perovskite-like NaNdTiO 4 complex oxide in acid aqueous solutions was studied. By the X-ray and thermogravimetry analyses the instability of NaNdTiO 4 in aqueous solutions was found, which is determined by the sodium cation exchange for protons and by water molecules intercalation in...
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| Veröffentlicht in: | Russian journal of general chemistry 2011-07, Vol.81 (7), p.1434-1441 |
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| container_title | Russian journal of general chemistry |
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| creator | Zvereva, I. A. Silyukov, O. I. Chislov, M. V. |
| description | The behavior of perovskite-like NaNdTiO
4
complex oxide in acid aqueous solutions was studied. By the X-ray and thermogravimetry analyses the instability of NaNdTiO
4
in aqueous solutions was found, which is determined by the sodium cation exchange for protons and by water molecules intercalation into the interlayer space of the crystal structure. The proton-containing layered oxides HNdTiO
4
and H
x
Na
1−
x
NdTiO
4
·
y
H
2
O were obtained (1 <
x
< 0.64, 0 <
y
< 0.47). The structure of the H
0.73
Na
0.27
NdTiO
4
·0.3H
2
O compound was refined. |
| doi_str_mv | 10.1134/S1070363211070061 |
| format | Article |
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4
complex oxide in acid aqueous solutions was studied. By the X-ray and thermogravimetry analyses the instability of NaNdTiO
4
in aqueous solutions was found, which is determined by the sodium cation exchange for protons and by water molecules intercalation into the interlayer space of the crystal structure. The proton-containing layered oxides HNdTiO
4
and H
x
Na
1−
x
NdTiO
4
·
y
H
2
O were obtained (1 <
x
< 0.64, 0 <
y
< 0.47). The structure of the H
0.73
Na
0.27
NdTiO
4
·0.3H
2
O compound was refined.</description><identifier>ISSN: 1070-3632</identifier><identifier>EISSN: 1608-3350</identifier><identifier>DOI: 10.1134/S1070363211070061</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science</subject><ispartof>Russian journal of general chemistry, 2011-07, Vol.81 (7), p.1434-1441</ispartof><rights>Pleiades Publishing, Ltd. 2011</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c354t-4b7d85088d9f94f45a0a88f87dd3a1486da9dd959c11544f3acdd27f70c3ff593</citedby><cites>FETCH-LOGICAL-c354t-4b7d85088d9f94f45a0a88f87dd3a1486da9dd959c11544f3acdd27f70c3ff593</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070363211070061$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070363211070061$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Zvereva, I. A.</creatorcontrib><creatorcontrib>Silyukov, O. I.</creatorcontrib><creatorcontrib>Chislov, M. V.</creatorcontrib><title>Ion-exchange reactions in the structure of perovskite-like layered oxides: I. Protonation of NaNdTiO4 complex oxide</title><title>Russian journal of general chemistry</title><addtitle>Russ J Gen Chem</addtitle><description>The behavior of perovskite-like NaNdTiO
4
complex oxide in acid aqueous solutions was studied. By the X-ray and thermogravimetry analyses the instability of NaNdTiO
4
in aqueous solutions was found, which is determined by the sodium cation exchange for protons and by water molecules intercalation into the interlayer space of the crystal structure. The proton-containing layered oxides HNdTiO
4
and H
x
Na
1−
x
NdTiO
4
·
y
H
2
O were obtained (1 <
x
< 0.64, 0 <
y
< 0.47). The structure of the H
0.73
Na
0.27
NdTiO
4
·0.3H
2
O compound was refined.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><issn>1070-3632</issn><issn>1608-3350</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9kN1KAzEQhYMoWKsP4F1eIDXZJLtZ76T4U5BWsF4vMZnYbbebkqTSvr1Z6p3g1RxmzncYDkK3jE4Y4-LundGK8pIXbBC0ZGdoxEqqCOeSnmedt2S4X6KrGNeUsmwqRijOfE_gYFa6_wIcQJvU-j7itsdpBTimsDdpHwB7h3cQ_HfctAlI124Ad_oIASz2h9ZCvMezCX4LPvleDxkDMddzu2wXAhu_3XVwOFmv0YXTXYSb3zlGH0-Py-kLeV08z6YPr8RwKRIRn5VVkipla1cLJ6SmWimnKmu5ZkKVVtfW1rI2jEkhHNfG2qJyFTXcOVnzMWKnXBN8jAFcswvtVodjw2gztNb8aS0zxYmJ2ZsrCc3a70Of3_wH-gFuF2_q</recordid><startdate>20110701</startdate><enddate>20110701</enddate><creator>Zvereva, I. A.</creator><creator>Silyukov, O. I.</creator><creator>Chislov, M. V.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20110701</creationdate><title>Ion-exchange reactions in the structure of perovskite-like layered oxides: I. Protonation of NaNdTiO4 complex oxide</title><author>Zvereva, I. A. ; Silyukov, O. I. ; Chislov, M. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c354t-4b7d85088d9f94f45a0a88f87dd3a1486da9dd959c11544f3acdd27f70c3ff593</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zvereva, I. A.</creatorcontrib><creatorcontrib>Silyukov, O. I.</creatorcontrib><creatorcontrib>Chislov, M. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of general chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zvereva, I. A.</au><au>Silyukov, O. I.</au><au>Chislov, M. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ion-exchange reactions in the structure of perovskite-like layered oxides: I. Protonation of NaNdTiO4 complex oxide</atitle><jtitle>Russian journal of general chemistry</jtitle><stitle>Russ J Gen Chem</stitle><date>2011-07-01</date><risdate>2011</risdate><volume>81</volume><issue>7</issue><spage>1434</spage><epage>1441</epage><pages>1434-1441</pages><issn>1070-3632</issn><eissn>1608-3350</eissn><abstract>The behavior of perovskite-like NaNdTiO
4
complex oxide in acid aqueous solutions was studied. By the X-ray and thermogravimetry analyses the instability of NaNdTiO
4
in aqueous solutions was found, which is determined by the sodium cation exchange for protons and by water molecules intercalation into the interlayer space of the crystal structure. The proton-containing layered oxides HNdTiO
4
and H
x
Na
1−
x
NdTiO
4
·
y
H
2
O were obtained (1 <
x
< 0.64, 0 <
y
< 0.47). The structure of the H
0.73
Na
0.27
NdTiO
4
·0.3H
2
O compound was refined.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S1070363211070061</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Russian journal of general chemistry, 2011-07, Vol.81 (7), p.1434-1441 |
| issn | 1070-3632 1608-3350 |
| language | eng |
| recordid | cdi_crossref_primary_10_1134_S1070363211070061 |
| source | SpringerLink Journals |
| subjects | Chemistry Chemistry and Materials Science Chemistry/Food Science |
| title | Ion-exchange reactions in the structure of perovskite-like layered oxides: I. Protonation of NaNdTiO4 complex oxide |
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