Reactions of dichloromethane with chalcogens and dimethyl chalcogenides in the hydrazine hydrate-alkali system
Methods of synthesis of compounds MeY(CH 2 Y) n Me (Y=S, Se, Te; n = 1–3) containing several identical or different chalcogen atoms are suggested. The methods are based on the reactions of dichloromethane with elemental chalcogens (Y 2− ) and dimethyl dichalcogenides (MeY − ) activated in the system...
Gespeichert in:
| Veröffentlicht in: | Russian journal of general chemistry 2008-09, Vol.78 (9), p.1734-1741 |
|---|---|
| Hauptverfasser: | , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1741 |
|---|---|
| container_issue | 9 |
| container_start_page | 1734 |
| container_title | Russian journal of general chemistry |
| container_volume | 78 |
| creator | Levanova, E. P. Vshivtsev, V. Yu Sukhomazova, E. N. Grabel’nykh, V. A. Russavskaya, N. V. Zhanchipova, E. R. Klyba, L. V. Albanov, A. I. Korchevin, N. A. |
| description | Methods of synthesis of compounds MeY(CH
2
Y)
n
Me (Y=S, Se, Te;
n
= 1–3) containing several identical or different chalcogen atoms are suggested. The methods are based on the reactions of dichloromethane with elemental chalcogens (Y
2−
) and dimethyl dichalcogenides (MeY
−
) activated in the system hydrazine hydrate-alkali. The effect of the chalcogen on the reactivity toward dichloromethane is qualitatively assessed. With elemental tellurium in the system hydrazine hydrate-alkali, reduction of one chlorine atom in dichloromethane and formation of methyltellanyl derivatives are observed. |
| doi_str_mv | 10.1134/S1070363208090156 |
| format | Article |
| fullrecord | <record><control><sourceid>crossref_sprin</sourceid><recordid>TN_cdi_crossref_primary_10_1134_S1070363208090156</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1134_S1070363208090156</sourcerecordid><originalsourceid>FETCH-LOGICAL-c288t-8870160dd40f4c49ca02fc3504ac18b370ab2424c9ca1af3dfed6b8f3f24dde23</originalsourceid><addsrcrecordid>eNp9UNtKAzEUDKJgrX6Ab_mB1ZNLd9NHKd6gIHh5XrK5dFO3iSQRWb_eLC34IPh0hjMzhzmD0CWBK0IYv34h0ACrGQUBSyCL-gjNSA2iYmwBxwUXupr4U3SW0haAANR0hvyzkSq74BMOFmun-iHEsDO5l97gL5d7rHo5qLAxRSK9LpqJHYffvdMmYedx7g3uRx3lt_MHlE0lh3c5OJzGlM3uHJ1YOSRzcZhz9HZ3-7p6qNZP94-rm3WlqBC5EqKBkl5rDpYrvlQSqFXlEy4VER1rQHaUU64KQ6Rl2hpdd8IyS7nWhrI5Ivu7KoaUorHtR3Q7GceWQDsV1v4prHjo3pOK1m9MbLfhM_oS8x_TD2Q2b_Y</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Reactions of dichloromethane with chalcogens and dimethyl chalcogenides in the hydrazine hydrate-alkali system</title><source>SpringerLink Journals - AutoHoldings</source><creator>Levanova, E. P. ; Vshivtsev, V. Yu ; Sukhomazova, E. N. ; Grabel’nykh, V. A. ; Russavskaya, N. V. ; Zhanchipova, E. R. ; Klyba, L. V. ; Albanov, A. I. ; Korchevin, N. A.</creator><creatorcontrib>Levanova, E. P. ; Vshivtsev, V. Yu ; Sukhomazova, E. N. ; Grabel’nykh, V. A. ; Russavskaya, N. V. ; Zhanchipova, E. R. ; Klyba, L. V. ; Albanov, A. I. ; Korchevin, N. A.</creatorcontrib><description>Methods of synthesis of compounds MeY(CH
2
Y)
n
Me (Y=S, Se, Te;
n
= 1–3) containing several identical or different chalcogen atoms are suggested. The methods are based on the reactions of dichloromethane with elemental chalcogens (Y
2−
) and dimethyl dichalcogenides (MeY
−
) activated in the system hydrazine hydrate-alkali. The effect of the chalcogen on the reactivity toward dichloromethane is qualitatively assessed. With elemental tellurium in the system hydrazine hydrate-alkali, reduction of one chlorine atom in dichloromethane and formation of methyltellanyl derivatives are observed.</description><identifier>ISSN: 1070-3632</identifier><identifier>EISSN: 1608-3350</identifier><identifier>DOI: 10.1134/S1070363208090156</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science</subject><ispartof>Russian journal of general chemistry, 2008-09, Vol.78 (9), p.1734-1741</ispartof><rights>MAIK Nauka 2008</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c288t-8870160dd40f4c49ca02fc3504ac18b370ab2424c9ca1af3dfed6b8f3f24dde23</citedby><cites>FETCH-LOGICAL-c288t-8870160dd40f4c49ca02fc3504ac18b370ab2424c9ca1af3dfed6b8f3f24dde23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070363208090156$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070363208090156$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Levanova, E. P.</creatorcontrib><creatorcontrib>Vshivtsev, V. Yu</creatorcontrib><creatorcontrib>Sukhomazova, E. N.</creatorcontrib><creatorcontrib>Grabel’nykh, V. A.</creatorcontrib><creatorcontrib>Russavskaya, N. V.</creatorcontrib><creatorcontrib>Zhanchipova, E. R.</creatorcontrib><creatorcontrib>Klyba, L. V.</creatorcontrib><creatorcontrib>Albanov, A. I.</creatorcontrib><creatorcontrib>Korchevin, N. A.</creatorcontrib><title>Reactions of dichloromethane with chalcogens and dimethyl chalcogenides in the hydrazine hydrate-alkali system</title><title>Russian journal of general chemistry</title><addtitle>Russ J Gen Chem</addtitle><description>Methods of synthesis of compounds MeY(CH
2
Y)
n
Me (Y=S, Se, Te;
n
= 1–3) containing several identical or different chalcogen atoms are suggested. The methods are based on the reactions of dichloromethane with elemental chalcogens (Y
2−
) and dimethyl dichalcogenides (MeY
−
) activated in the system hydrazine hydrate-alkali. The effect of the chalcogen on the reactivity toward dichloromethane is qualitatively assessed. With elemental tellurium in the system hydrazine hydrate-alkali, reduction of one chlorine atom in dichloromethane and formation of methyltellanyl derivatives are observed.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><issn>1070-3632</issn><issn>1608-3350</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNp9UNtKAzEUDKJgrX6Ab_mB1ZNLd9NHKd6gIHh5XrK5dFO3iSQRWb_eLC34IPh0hjMzhzmD0CWBK0IYv34h0ACrGQUBSyCL-gjNSA2iYmwBxwUXupr4U3SW0haAANR0hvyzkSq74BMOFmun-iHEsDO5l97gL5d7rHo5qLAxRSK9LpqJHYffvdMmYedx7g3uRx3lt_MHlE0lh3c5OJzGlM3uHJ1YOSRzcZhz9HZ3-7p6qNZP94-rm3WlqBC5EqKBkl5rDpYrvlQSqFXlEy4VER1rQHaUU64KQ6Rl2hpdd8IyS7nWhrI5Ivu7KoaUorHtR3Q7GceWQDsV1v4prHjo3pOK1m9MbLfhM_oS8x_TD2Q2b_Y</recordid><startdate>20080901</startdate><enddate>20080901</enddate><creator>Levanova, E. P.</creator><creator>Vshivtsev, V. Yu</creator><creator>Sukhomazova, E. N.</creator><creator>Grabel’nykh, V. A.</creator><creator>Russavskaya, N. V.</creator><creator>Zhanchipova, E. R.</creator><creator>Klyba, L. V.</creator><creator>Albanov, A. I.</creator><creator>Korchevin, N. A.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20080901</creationdate><title>Reactions of dichloromethane with chalcogens and dimethyl chalcogenides in the hydrazine hydrate-alkali system</title><author>Levanova, E. P. ; Vshivtsev, V. Yu ; Sukhomazova, E. N. ; Grabel’nykh, V. A. ; Russavskaya, N. V. ; Zhanchipova, E. R. ; Klyba, L. V. ; Albanov, A. I. ; Korchevin, N. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c288t-8870160dd40f4c49ca02fc3504ac18b370ab2424c9ca1af3dfed6b8f3f24dde23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Levanova, E. P.</creatorcontrib><creatorcontrib>Vshivtsev, V. Yu</creatorcontrib><creatorcontrib>Sukhomazova, E. N.</creatorcontrib><creatorcontrib>Grabel’nykh, V. A.</creatorcontrib><creatorcontrib>Russavskaya, N. V.</creatorcontrib><creatorcontrib>Zhanchipova, E. R.</creatorcontrib><creatorcontrib>Klyba, L. V.</creatorcontrib><creatorcontrib>Albanov, A. I.</creatorcontrib><creatorcontrib>Korchevin, N. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of general chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Levanova, E. P.</au><au>Vshivtsev, V. Yu</au><au>Sukhomazova, E. N.</au><au>Grabel’nykh, V. A.</au><au>Russavskaya, N. V.</au><au>Zhanchipova, E. R.</au><au>Klyba, L. V.</au><au>Albanov, A. I.</au><au>Korchevin, N. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Reactions of dichloromethane with chalcogens and dimethyl chalcogenides in the hydrazine hydrate-alkali system</atitle><jtitle>Russian journal of general chemistry</jtitle><stitle>Russ J Gen Chem</stitle><date>2008-09-01</date><risdate>2008</risdate><volume>78</volume><issue>9</issue><spage>1734</spage><epage>1741</epage><pages>1734-1741</pages><issn>1070-3632</issn><eissn>1608-3350</eissn><abstract>Methods of synthesis of compounds MeY(CH
2
Y)
n
Me (Y=S, Se, Te;
n
= 1–3) containing several identical or different chalcogen atoms are suggested. The methods are based on the reactions of dichloromethane with elemental chalcogens (Y
2−
) and dimethyl dichalcogenides (MeY
−
) activated in the system hydrazine hydrate-alkali. The effect of the chalcogen on the reactivity toward dichloromethane is qualitatively assessed. With elemental tellurium in the system hydrazine hydrate-alkali, reduction of one chlorine atom in dichloromethane and formation of methyltellanyl derivatives are observed.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S1070363208090156</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1070-3632 |
| ispartof | Russian journal of general chemistry, 2008-09, Vol.78 (9), p.1734-1741 |
| issn | 1070-3632 1608-3350 |
| language | eng |
| recordid | cdi_crossref_primary_10_1134_S1070363208090156 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Chemistry Chemistry and Materials Science Chemistry/Food Science |
| title | Reactions of dichloromethane with chalcogens and dimethyl chalcogenides in the hydrazine hydrate-alkali system |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T02%3A04%3A47IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref_sprin&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Reactions%20of%20dichloromethane%20with%20chalcogens%20and%20dimethyl%20chalcogenides%20in%20the%20hydrazine%20hydrate-alkali%20system&rft.jtitle=Russian%20journal%20of%20general%20chemistry&rft.au=Levanova,%20E.%20P.&rft.date=2008-09-01&rft.volume=78&rft.issue=9&rft.spage=1734&rft.epage=1741&rft.pages=1734-1741&rft.issn=1070-3632&rft.eissn=1608-3350&rft_id=info:doi/10.1134/S1070363208090156&rft_dat=%3Ccrossref_sprin%3E10_1134_S1070363208090156%3C/crossref_sprin%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |