Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl− and DMF ligands
Complex (Me 4 N) 2 [Mo 2 S 2 O 2 Cl 4 ] ((Me 4 N) 2 [ II ]) is synthesized by passing gaseous HCl through a solution of (Me 4 N) 2 [Mo 2 O 2 S 8 ] ((Me 4 N) 2 [ I ]). The recrystallization of (Me 4 N) 2 [ II ] from N , N -dimethylformamide (DMF) gives compound (Me 4 N)[Mo 2 S 2 O 2 Cl 3 (DMF) 3 ] ((...
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| Veröffentlicht in: | Russian journal of coordination chemistry 2015-11, Vol.41 (11), p.759-764 |
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| container_title | Russian journal of coordination chemistry |
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| creator | Ogienko, D. S. Smolentsev, A. I. Bashirov, D. A. Afonin, M. Yu Petrov, P. A. Konchenko, S. N. |
| description | Complex (Me
4
N)
2
[Mo
2
S
2
O
2
Cl
4
] ((Me
4
N)
2
[
II
]) is synthesized by passing gaseous HCl through a solution of (Me
4
N)
2
[Mo
2
O
2
S
8
] ((Me
4
N)
2
[
I
]). The recrystallization of (Me
4
N)
2
[
II
] from
N
,
N
-dimethylformamide (DMF) gives compound (Me
4
N)[Mo
2
S
2
O
2
Cl
3
(DMF)
3
] ((Me
4
N)[
III
]). The oxidation of (Et
4
N)
2
[
I
] with iodine in DMF affords the earlier described complex [Mo
2
S
2
O
2
(DMF)
6
]I
2
([
IV
]
I
2
). However, this complex was not structurally characterized. The structures of the synthesized compounds are determined by X-ray diffraction analyses (CIF files CCDC nos. 1059924–1059926). Thus, several complexes in which the binuclear fragment {Mo
2
S
2
O
2
}
2+
has a labile coordination environment were synthesized and characterized. |
| doi_str_mv | 10.1134/S1070328415110056 |
| format | Article |
| fullrecord | <record><control><sourceid>crossref_sprin</sourceid><recordid>TN_cdi_crossref_primary_10_1134_S1070328415110056</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1134_S1070328415110056</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1336-315bb816c29c3d8f712d0ae61f0bb593f7a79ef74750f68f31892db9ed9316733</originalsourceid><addsrcrecordid>eNp9ULFOwzAUtBBIlMIHsHlHAT87seMRBVqQWnUIzJHj2G2qNKnsVFAhdmY-kS_BoWxITO9Od_f03iF0CeQagMU3ORBBGE1jSAAISfgRGgEnacQYpMcBBzka9FN05v2akMEkRyjP922_Mt54rNoK-97tdL9zgXYW626zbcxrIG_zjuZ0Qd_pFX6p-xVuVFk3BmfN18fnT_JuPsFNvQzQn6MTqxpvLn7nGD1P7p-yh2i2mD5mt7NIA2M8YpCUZQpcU6lZlVoBtCLKcLCkLBPJrFBCGitikRDLUxsekbQqpakkAy4YGyM47NWu894ZW2xdvVFuXwAphlaKP62EDD1kfPC2S-OKdbdzbTjzn9A3BAljDQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl− and DMF ligands</title><source>Springer Nature - Complete Springer Journals</source><creator>Ogienko, D. S. ; Smolentsev, A. I. ; Bashirov, D. A. ; Afonin, M. Yu ; Petrov, P. A. ; Konchenko, S. N.</creator><creatorcontrib>Ogienko, D. S. ; Smolentsev, A. I. ; Bashirov, D. A. ; Afonin, M. Yu ; Petrov, P. A. ; Konchenko, S. N.</creatorcontrib><description>Complex (Me
4
N)
2
[Mo
2
S
2
O
2
Cl
4
] ((Me
4
N)
2
[
II
]) is synthesized by passing gaseous HCl through a solution of (Me
4
N)
2
[Mo
2
O
2
S
8
] ((Me
4
N)
2
[
I
]). The recrystallization of (Me
4
N)
2
[
II
] from
N
,
N
-dimethylformamide (DMF) gives compound (Me
4
N)[Mo
2
S
2
O
2
Cl
3
(DMF)
3
] ((Me
4
N)[
III
]). The oxidation of (Et
4
N)
2
[
I
] with iodine in DMF affords the earlier described complex [Mo
2
S
2
O
2
(DMF)
6
]I
2
([
IV
]
I
2
). However, this complex was not structurally characterized. The structures of the synthesized compounds are determined by X-ray diffraction analyses (CIF files CCDC nos. 1059924–1059926). Thus, several complexes in which the binuclear fragment {Mo
2
S
2
O
2
}
2+
has a labile coordination environment were synthesized and characterized.</description><identifier>ISSN: 1070-3284</identifier><identifier>EISSN: 1608-3318</identifier><identifier>DOI: 10.1134/S1070328415110056</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Physical Chemistry</subject><ispartof>Russian journal of coordination chemistry, 2015-11, Vol.41 (11), p.759-764</ispartof><rights>Pleiades Publishing, Ltd. 2015</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1336-315bb816c29c3d8f712d0ae61f0bb593f7a79ef74750f68f31892db9ed9316733</citedby><cites>FETCH-LOGICAL-c1336-315bb816c29c3d8f712d0ae61f0bb593f7a79ef74750f68f31892db9ed9316733</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070328415110056$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070328415110056$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Ogienko, D. S.</creatorcontrib><creatorcontrib>Smolentsev, A. I.</creatorcontrib><creatorcontrib>Bashirov, D. A.</creatorcontrib><creatorcontrib>Afonin, M. Yu</creatorcontrib><creatorcontrib>Petrov, P. A.</creatorcontrib><creatorcontrib>Konchenko, S. N.</creatorcontrib><title>Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl− and DMF ligands</title><title>Russian journal of coordination chemistry</title><addtitle>Russ J Coord Chem</addtitle><description>Complex (Me
4
N)
2
[Mo
2
S
2
O
2
Cl
4
] ((Me
4
N)
2
[
II
]) is synthesized by passing gaseous HCl through a solution of (Me
4
N)
2
[Mo
2
O
2
S
8
] ((Me
4
N)
2
[
I
]). The recrystallization of (Me
4
N)
2
[
II
] from
N
,
N
-dimethylformamide (DMF) gives compound (Me
4
N)[Mo
2
S
2
O
2
Cl
3
(DMF)
3
] ((Me
4
N)[
III
]). The oxidation of (Et
4
N)
2
[
I
] with iodine in DMF affords the earlier described complex [Mo
2
S
2
O
2
(DMF)
6
]I
2
([
IV
]
I
2
). However, this complex was not structurally characterized. The structures of the synthesized compounds are determined by X-ray diffraction analyses (CIF files CCDC nos. 1059924–1059926). Thus, several complexes in which the binuclear fragment {Mo
2
S
2
O
2
}
2+
has a labile coordination environment were synthesized and characterized.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Physical Chemistry</subject><issn>1070-3284</issn><issn>1608-3318</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9ULFOwzAUtBBIlMIHsHlHAT87seMRBVqQWnUIzJHj2G2qNKnsVFAhdmY-kS_BoWxITO9Od_f03iF0CeQagMU3ORBBGE1jSAAISfgRGgEnacQYpMcBBzka9FN05v2akMEkRyjP922_Mt54rNoK-97tdL9zgXYW626zbcxrIG_zjuZ0Qd_pFX6p-xVuVFk3BmfN18fnT_JuPsFNvQzQn6MTqxpvLn7nGD1P7p-yh2i2mD5mt7NIA2M8YpCUZQpcU6lZlVoBtCLKcLCkLBPJrFBCGitikRDLUxsekbQqpakkAy4YGyM47NWu894ZW2xdvVFuXwAphlaKP62EDD1kfPC2S-OKdbdzbTjzn9A3BAljDQ</recordid><startdate>201511</startdate><enddate>201511</enddate><creator>Ogienko, D. S.</creator><creator>Smolentsev, A. I.</creator><creator>Bashirov, D. A.</creator><creator>Afonin, M. Yu</creator><creator>Petrov, P. A.</creator><creator>Konchenko, S. N.</creator><general>Pleiades Publishing</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201511</creationdate><title>Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl− and DMF ligands</title><author>Ogienko, D. S. ; Smolentsev, A. I. ; Bashirov, D. A. ; Afonin, M. Yu ; Petrov, P. A. ; Konchenko, S. N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1336-315bb816c29c3d8f712d0ae61f0bb593f7a79ef74750f68f31892db9ed9316733</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ogienko, D. S.</creatorcontrib><creatorcontrib>Smolentsev, A. I.</creatorcontrib><creatorcontrib>Bashirov, D. A.</creatorcontrib><creatorcontrib>Afonin, M. Yu</creatorcontrib><creatorcontrib>Petrov, P. A.</creatorcontrib><creatorcontrib>Konchenko, S. N.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ogienko, D. S.</au><au>Smolentsev, A. I.</au><au>Bashirov, D. A.</au><au>Afonin, M. Yu</au><au>Petrov, P. A.</au><au>Konchenko, S. N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl− and DMF ligands</atitle><jtitle>Russian journal of coordination chemistry</jtitle><stitle>Russ J Coord Chem</stitle><date>2015-11</date><risdate>2015</risdate><volume>41</volume><issue>11</issue><spage>759</spage><epage>764</epage><pages>759-764</pages><issn>1070-3284</issn><eissn>1608-3318</eissn><abstract>Complex (Me
4
N)
2
[Mo
2
S
2
O
2
Cl
4
] ((Me
4
N)
2
[
II
]) is synthesized by passing gaseous HCl through a solution of (Me
4
N)
2
[Mo
2
O
2
S
8
] ((Me
4
N)
2
[
I
]). The recrystallization of (Me
4
N)
2
[
II
] from
N
,
N
-dimethylformamide (DMF) gives compound (Me
4
N)[Mo
2
S
2
O
2
Cl
3
(DMF)
3
] ((Me
4
N)[
III
]). The oxidation of (Et
4
N)
2
[
I
] with iodine in DMF affords the earlier described complex [Mo
2
S
2
O
2
(DMF)
6
]I
2
([
IV
]
I
2
). However, this complex was not structurally characterized. The structures of the synthesized compounds are determined by X-ray diffraction analyses (CIF files CCDC nos. 1059924–1059926). Thus, several complexes in which the binuclear fragment {Mo
2
S
2
O
2
}
2+
has a labile coordination environment were synthesized and characterized.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070328415110056</doi><tpages>6</tpages></addata></record> |
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| identifier | ISSN: 1070-3284 |
| ispartof | Russian journal of coordination chemistry, 2015-11, Vol.41 (11), p.759-764 |
| issn | 1070-3284 1608-3318 |
| language | eng |
| recordid | cdi_crossref_primary_10_1134_S1070328415110056 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Chemistry Chemistry and Materials Science Inorganic Chemistry Physical Chemistry |
| title | Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl− and DMF ligands |
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