Neutral and monocationic dinuclear (carbonyl)(cyclopentadienyl)(phenylchalcogenate) iron complexes of the general formulas [(RC5H4)Fe(CO)EPh]2 and [(RC5H4)Fe(CO)EPh]2PF6 (E = S or Te; R = H or Me): Synthesis, molecular structures, and EPR spectra
Heating of the compounds (RC 5 H 4 )Fe(CO) 2 TePh (R = H ( I ) and Me ( II )) in heptane afforded the dinuclear complexes [(RC 5 H 4 )Fe(CO)TePh] 2 ( III and IV , respectively). By oxidation with Fc + PF 6 − , these complexes were transformed into the paramagnetic cationic complexes [(RC 5 H 4 )Fe(C...
Gespeichert in:
| Veröffentlicht in: | Russian journal of coordination chemistry 2013, Vol.39 (12), p.822-828 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 828 |
|---|---|
| container_issue | 12 |
| container_start_page | 822 |
| container_title | Russian journal of coordination chemistry |
| container_volume | 39 |
| creator | Shapovalov, S. S. Pasynskii, A. A. Skabitskii, I. V. Sidorenkov, A. S. Krishtop, T. A. Minin, V. V. |
| description | Heating of the compounds (RC
5
H
4
)Fe(CO)
2
TePh (R = H (
I
) and Me (
II
)) in heptane afforded the dinuclear complexes [(RC
5
H
4
)Fe(CO)TePh]
2
(
III
and
IV
, respectively). By oxidation with Fc
+
PF
6
−
, these complexes were transformed into the paramagnetic cationic complexes [(RC
5
H
4
)Fe(CO)TePh]
2
PF
6
(
V
and
VI
, respectively). Structures
III–V
and [(C
5
H
5
)Fe(CO)SPh]
2
PF
6
(
VII
) were characterized by X-ray diffraction. |
| doi_str_mv | 10.1134/S1070328413120038 |
| format | Article |
| fullrecord | <record><control><sourceid>crossref_sprin</sourceid><recordid>TN_cdi_crossref_primary_10_1134_S1070328413120038</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1134_S1070328413120038</sourcerecordid><originalsourceid>FETCH-LOGICAL-c2038-2a772ee9b9763df00e1effff0ddcdfc0331e18a9b618a1658fe74fc38b102cc13</originalsourceid><addsrcrecordid>eNp9UU1P4zAQjRAr8bH7A7jNMZEIa8dtkoI4oKrdrsQuVQsnhCJ3MqZBrh3ZiUT_-J7Xgb0twgePZ57fm68oOuPsgnMx-r7mrGAiK0dc8IwxUR5ExzxnZSoELw_DO8DpgB9FJ96_MMYZG0-Ooz-_qe-c1CBNDTtrLMqusaZBqBvToybpIEbpNtbsdRLjHrVtyXSybugt0m4Hi1up0T6TkR0l0DhrAO2u1fRKHqyCbksQUBoyKet2vZYeHuPVdLwYJXOKp3fJbLl9yt7K-CC-nOcQz-Aa1mAd3NMVrIKzGJxflFzCem9CCt_489CEJgz6Dnzneux6RyE66M6WK_AtYej3a_RFSe3p2z97Gj3MZ_fTRXp79-Pn9OY2xSzMMM1kUWREk82kyEWtGCNOKhxW11grZGG4xEs52eTh5vm4VFSMFIpyw1mGyMVpxN910VnvHamqdc1Oun3FWTUsrvpvcYGTvXN8-GueyVUvtncmlPkJ6S_di5pE</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Neutral and monocationic dinuclear (carbonyl)(cyclopentadienyl)(phenylchalcogenate) iron complexes of the general formulas [(RC5H4)Fe(CO)EPh]2 and [(RC5H4)Fe(CO)EPh]2PF6 (E = S or Te; R = H or Me): Synthesis, molecular structures, and EPR spectra</title><source>SpringerLink</source><creator>Shapovalov, S. S. ; Pasynskii, A. A. ; Skabitskii, I. V. ; Sidorenkov, A. S. ; Krishtop, T. A. ; Minin, V. V.</creator><creatorcontrib>Shapovalov, S. S. ; Pasynskii, A. A. ; Skabitskii, I. V. ; Sidorenkov, A. S. ; Krishtop, T. A. ; Minin, V. V.</creatorcontrib><description>Heating of the compounds (RC
5
H
4
)Fe(CO)
2
TePh (R = H (
I
) and Me (
II
)) in heptane afforded the dinuclear complexes [(RC
5
H
4
)Fe(CO)TePh]
2
(
III
and
IV
, respectively). By oxidation with Fc
+
PF
6
−
, these complexes were transformed into the paramagnetic cationic complexes [(RC
5
H
4
)Fe(CO)TePh]
2
PF
6
(
V
and
VI
, respectively). Structures
III–V
and [(C
5
H
5
)Fe(CO)SPh]
2
PF
6
(
VII
) were characterized by X-ray diffraction.</description><identifier>ISSN: 1070-3284</identifier><identifier>EISSN: 1608-3318</identifier><identifier>DOI: 10.1134/S1070328413120038</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Physical Chemistry</subject><ispartof>Russian journal of coordination chemistry, 2013, Vol.39 (12), p.822-828</ispartof><rights>Pleiades Publishing, Ltd. 2013</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2038-2a772ee9b9763df00e1effff0ddcdfc0331e18a9b618a1658fe74fc38b102cc13</citedby><cites>FETCH-LOGICAL-c2038-2a772ee9b9763df00e1effff0ddcdfc0331e18a9b618a1658fe74fc38b102cc13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070328413120038$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070328413120038$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Shapovalov, S. S.</creatorcontrib><creatorcontrib>Pasynskii, A. A.</creatorcontrib><creatorcontrib>Skabitskii, I. V.</creatorcontrib><creatorcontrib>Sidorenkov, A. S.</creatorcontrib><creatorcontrib>Krishtop, T. A.</creatorcontrib><creatorcontrib>Minin, V. V.</creatorcontrib><title>Neutral and monocationic dinuclear (carbonyl)(cyclopentadienyl)(phenylchalcogenate) iron complexes of the general formulas [(RC5H4)Fe(CO)EPh]2 and [(RC5H4)Fe(CO)EPh]2PF6 (E = S or Te; R = H or Me): Synthesis, molecular structures, and EPR spectra</title><title>Russian journal of coordination chemistry</title><addtitle>Russ J Coord Chem</addtitle><description>Heating of the compounds (RC
5
H
4
)Fe(CO)
2
TePh (R = H (
I
) and Me (
II
)) in heptane afforded the dinuclear complexes [(RC
5
H
4
)Fe(CO)TePh]
2
(
III
and
IV
, respectively). By oxidation with Fc
+
PF
6
−
, these complexes were transformed into the paramagnetic cationic complexes [(RC
5
H
4
)Fe(CO)TePh]
2
PF
6
(
V
and
VI
, respectively). Structures
III–V
and [(C
5
H
5
)Fe(CO)SPh]
2
PF
6
(
VII
) were characterized by X-ray diffraction.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Physical Chemistry</subject><issn>1070-3284</issn><issn>1608-3318</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp9UU1P4zAQjRAr8bH7A7jNMZEIa8dtkoI4oKrdrsQuVQsnhCJ3MqZBrh3ZiUT_-J7Xgb0twgePZ57fm68oOuPsgnMx-r7mrGAiK0dc8IwxUR5ExzxnZSoELw_DO8DpgB9FJ96_MMYZG0-Ooz-_qe-c1CBNDTtrLMqusaZBqBvToybpIEbpNtbsdRLjHrVtyXSybugt0m4Hi1up0T6TkR0l0DhrAO2u1fRKHqyCbksQUBoyKet2vZYeHuPVdLwYJXOKp3fJbLl9yt7K-CC-nOcQz-Aa1mAd3NMVrIKzGJxflFzCem9CCt_489CEJgz6Dnzneux6RyE66M6WK_AtYej3a_RFSe3p2z97Gj3MZ_fTRXp79-Pn9OY2xSzMMM1kUWREk82kyEWtGCNOKhxW11grZGG4xEs52eTh5vm4VFSMFIpyw1mGyMVpxN910VnvHamqdc1Oun3FWTUsrvpvcYGTvXN8-GueyVUvtncmlPkJ6S_di5pE</recordid><startdate>2013</startdate><enddate>2013</enddate><creator>Shapovalov, S. S.</creator><creator>Pasynskii, A. A.</creator><creator>Skabitskii, I. V.</creator><creator>Sidorenkov, A. S.</creator><creator>Krishtop, T. A.</creator><creator>Minin, V. V.</creator><general>Springer US</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2013</creationdate><title>Neutral and monocationic dinuclear (carbonyl)(cyclopentadienyl)(phenylchalcogenate) iron complexes of the general formulas [(RC5H4)Fe(CO)EPh]2 and [(RC5H4)Fe(CO)EPh]2PF6 (E = S or Te; R = H or Me): Synthesis, molecular structures, and EPR spectra</title><author>Shapovalov, S. S. ; Pasynskii, A. A. ; Skabitskii, I. V. ; Sidorenkov, A. S. ; Krishtop, T. A. ; Minin, V. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2038-2a772ee9b9763df00e1effff0ddcdfc0331e18a9b618a1658fe74fc38b102cc13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shapovalov, S. S.</creatorcontrib><creatorcontrib>Pasynskii, A. A.</creatorcontrib><creatorcontrib>Skabitskii, I. V.</creatorcontrib><creatorcontrib>Sidorenkov, A. S.</creatorcontrib><creatorcontrib>Krishtop, T. A.</creatorcontrib><creatorcontrib>Minin, V. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shapovalov, S. S.</au><au>Pasynskii, A. A.</au><au>Skabitskii, I. V.</au><au>Sidorenkov, A. S.</au><au>Krishtop, T. A.</au><au>Minin, V. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Neutral and monocationic dinuclear (carbonyl)(cyclopentadienyl)(phenylchalcogenate) iron complexes of the general formulas [(RC5H4)Fe(CO)EPh]2 and [(RC5H4)Fe(CO)EPh]2PF6 (E = S or Te; R = H or Me): Synthesis, molecular structures, and EPR spectra</atitle><jtitle>Russian journal of coordination chemistry</jtitle><stitle>Russ J Coord Chem</stitle><date>2013</date><risdate>2013</risdate><volume>39</volume><issue>12</issue><spage>822</spage><epage>828</epage><pages>822-828</pages><issn>1070-3284</issn><eissn>1608-3318</eissn><abstract>Heating of the compounds (RC
5
H
4
)Fe(CO)
2
TePh (R = H (
I
) and Me (
II
)) in heptane afforded the dinuclear complexes [(RC
5
H
4
)Fe(CO)TePh]
2
(
III
and
IV
, respectively). By oxidation with Fc
+
PF
6
−
, these complexes were transformed into the paramagnetic cationic complexes [(RC
5
H
4
)Fe(CO)TePh]
2
PF
6
(
V
and
VI
, respectively). Structures
III–V
and [(C
5
H
5
)Fe(CO)SPh]
2
PF
6
(
VII
) were characterized by X-ray diffraction.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1134/S1070328413120038</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1070-3284 |
| ispartof | Russian journal of coordination chemistry, 2013, Vol.39 (12), p.822-828 |
| issn | 1070-3284 1608-3318 |
| language | eng |
| recordid | cdi_crossref_primary_10_1134_S1070328413120038 |
| source | SpringerLink |
| subjects | Chemistry Chemistry and Materials Science Inorganic Chemistry Physical Chemistry |
| title | Neutral and monocationic dinuclear (carbonyl)(cyclopentadienyl)(phenylchalcogenate) iron complexes of the general formulas [(RC5H4)Fe(CO)EPh]2 and [(RC5H4)Fe(CO)EPh]2PF6 (E = S or Te; R = H or Me): Synthesis, molecular structures, and EPR spectra |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-24T16%3A12%3A50IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref_sprin&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Neutral%20and%20monocationic%20dinuclear%20(carbonyl)(cyclopentadienyl)(phenylchalcogenate)%20iron%20complexes%20of%20the%20general%20formulas%20%5B(RC5H4)Fe(CO)EPh%5D2%20and%20%5B(RC5H4)Fe(CO)EPh%5D2PF6%20(E%20=%20S%20or%20Te;%20R%20=%20H%20or%20Me):%20Synthesis,%20molecular%20structures,%20and%20EPR%20spectra&rft.jtitle=Russian%20journal%20of%20coordination%20chemistry&rft.au=Shapovalov,%20S.%20S.&rft.date=2013&rft.volume=39&rft.issue=12&rft.spage=822&rft.epage=828&rft.pages=822-828&rft.issn=1070-3284&rft.eissn=1608-3318&rft_id=info:doi/10.1134/S1070328413120038&rft_dat=%3Ccrossref_sprin%3E10_1134_S1070328413120038%3C/crossref_sprin%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |