Synthesis and photoluminescence of Zinc(II) complexes with tetrafluoroterephthalic acid (H2L). Crystal structure of coordination polymer [Zn(H2O)4(L) · 4H2O]n
Complexes Zn(H 2 O) 4 (L) ( I ) and Zn(H 2 O)(L) ( II ) (H 2 L = p -HOOCC 6 F 4 COOH) are synthesized. Single crystals of compound [Zn(H 2 O) 4 (L) · 4H 2 O] n ( III ) are grown. According to the X-ray diffraction data, the crystal structure of compound III is built of zigzag chains of coordination...
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| Veröffentlicht in: | Russian journal of coordination chemistry 2011-09, Vol.37 (9), p.650-656 |
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| creator | Larionov, S. V. Myachina, L. I. Klevtsova, R. F. Glinskaya, L. A. Kurat’eva, N. V. Uskov, E. M. Rakhmanov, M. I. Karpov, V. M. Platonov, V. E. Fadeeva, V. P. |
| description | Complexes Zn(H
2
O)
4
(L) (
I
) and Zn(H
2
O)(L) (
II
) (H
2
L =
p
-HOOCC
6
F
4
COOH) are synthesized. Single crystals of compound [Zn(H
2
O)
4
(L) · 4H
2
O]
n
(
III
) are grown. According to the X-ray diffraction data, the crystal structure of compound
III
is built of zigzag chains of coordination polymer Zn(H
2
O)
4
(L) and molecules of water of crystallization. The chain contains ions Zn
2+
, whose octahedral coordination sphere includes the O atoms of four water molecules and two O atoms of the deprotonated carboxyl groups. The chains in structure
III
are joined by a system of hydrogen bonds of coordinated water molecules and molecules of water of crystallization. The photoluminescence spectrum of H
2
L exhibits the band with λ
max
= 368 nm. The spectra of compounds
III
,
I
, and
II
contain bands at 322, 340, and 353 nm, respectively. |
| doi_str_mv | 10.1134/S1070328411090041 |
| format | Article |
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2
O)
4
(L) (
I
) and Zn(H
2
O)(L) (
II
) (H
2
L =
p
-HOOCC
6
F
4
COOH) are synthesized. Single crystals of compound [Zn(H
2
O)
4
(L) · 4H
2
O]
n
(
III
) are grown. According to the X-ray diffraction data, the crystal structure of compound
III
is built of zigzag chains of coordination polymer Zn(H
2
O)
4
(L) and molecules of water of crystallization. The chain contains ions Zn
2+
, whose octahedral coordination sphere includes the O atoms of four water molecules and two O atoms of the deprotonated carboxyl groups. The chains in structure
III
are joined by a system of hydrogen bonds of coordinated water molecules and molecules of water of crystallization. The photoluminescence spectrum of H
2
L exhibits the band with λ
max
= 368 nm. The spectra of compounds
III
,
I
, and
II
contain bands at 322, 340, and 353 nm, respectively.</description><identifier>ISSN: 1070-3284</identifier><identifier>EISSN: 1608-3318</identifier><identifier>DOI: 10.1134/S1070328411090041</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Physical Chemistry</subject><ispartof>Russian journal of coordination chemistry, 2011-09, Vol.37 (9), p.650-656</ispartof><rights>Pleiades Publishing, Ltd. 2011</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2031-b1bc11ad75f8ad1fe4d2772ac89d0b2831c8a5a745031d5a0519d65097c786b13</citedby><cites>FETCH-LOGICAL-c2031-b1bc11ad75f8ad1fe4d2772ac89d0b2831c8a5a745031d5a0519d65097c786b13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070328411090041$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070328411090041$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Larionov, S. V.</creatorcontrib><creatorcontrib>Myachina, L. I.</creatorcontrib><creatorcontrib>Klevtsova, R. F.</creatorcontrib><creatorcontrib>Glinskaya, L. A.</creatorcontrib><creatorcontrib>Kurat’eva, N. V.</creatorcontrib><creatorcontrib>Uskov, E. M.</creatorcontrib><creatorcontrib>Rakhmanov, M. I.</creatorcontrib><creatorcontrib>Karpov, V. M.</creatorcontrib><creatorcontrib>Platonov, V. E.</creatorcontrib><creatorcontrib>Fadeeva, V. P.</creatorcontrib><title>Synthesis and photoluminescence of Zinc(II) complexes with tetrafluoroterephthalic acid (H2L). Crystal structure of coordination polymer [Zn(H2O)4(L) · 4H2O]n</title><title>Russian journal of coordination chemistry</title><addtitle>Russ J Coord Chem</addtitle><description>Complexes Zn(H
2
O)
4
(L) (
I
) and Zn(H
2
O)(L) (
II
) (H
2
L =
p
-HOOCC
6
F
4
COOH) are synthesized. Single crystals of compound [Zn(H
2
O)
4
(L) · 4H
2
O]
n
(
III
) are grown. According to the X-ray diffraction data, the crystal structure of compound
III
is built of zigzag chains of coordination polymer Zn(H
2
O)
4
(L) and molecules of water of crystallization. The chain contains ions Zn
2+
, whose octahedral coordination sphere includes the O atoms of four water molecules and two O atoms of the deprotonated carboxyl groups. The chains in structure
III
are joined by a system of hydrogen bonds of coordinated water molecules and molecules of water of crystallization. The photoluminescence spectrum of H
2
L exhibits the band with λ
max
= 368 nm. The spectra of compounds
III
,
I
, and
II
contain bands at 322, 340, and 353 nm, respectively.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Physical Chemistry</subject><issn>1070-3284</issn><issn>1608-3318</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9kE1OwzAQhSMEEqVwAHZeNosUT34aZ4kqoJUidVHYFKHIsR3iKrEj2xHkNByDPScjpeyQWM2M3vueRs_zrgHPAaL4Zgs4xVFIYgCcYRzDiTeBBSZBFAE5HfdRDg76uXdh7R5jwDjJJt7HdlCuFlZaRBVHXa2dbvpWKmGZUEwgXaGdVGy2XvuI6bZrxLuw6E26GjnhDK2aXhvthBFd7WraSIYokxzNVmHuz9HSDNbRBllneuZ68xPItDZcKuqkVqjTzdAKg553amQ2fjzLffT1ieLxeFGX3llFGyuufufUe7q_e1yugnzzsF7e5gELcQRBCSUDoDxNKkI5VCLmYZqGlJGM4zIkETBCE5rGyejmCcUJZHyR4CxlKVmUEE09OOYyo601oio6I1tqhgJwcWi4-NPwyIRHxo5e9SpMsde9UeOb_0DfwLZ-lg</recordid><startdate>201109</startdate><enddate>201109</enddate><creator>Larionov, S. V.</creator><creator>Myachina, L. I.</creator><creator>Klevtsova, R. F.</creator><creator>Glinskaya, L. A.</creator><creator>Kurat’eva, N. V.</creator><creator>Uskov, E. M.</creator><creator>Rakhmanov, M. I.</creator><creator>Karpov, V. M.</creator><creator>Platonov, V. E.</creator><creator>Fadeeva, V. P.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201109</creationdate><title>Synthesis and photoluminescence of Zinc(II) complexes with tetrafluoroterephthalic acid (H2L). Crystal structure of coordination polymer [Zn(H2O)4(L) · 4H2O]n</title><author>Larionov, S. V. ; Myachina, L. I. ; Klevtsova, R. F. ; Glinskaya, L. A. ; Kurat’eva, N. V. ; Uskov, E. M. ; Rakhmanov, M. I. ; Karpov, V. M. ; Platonov, V. E. ; Fadeeva, V. P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2031-b1bc11ad75f8ad1fe4d2772ac89d0b2831c8a5a745031d5a0519d65097c786b13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Larionov, S. V.</creatorcontrib><creatorcontrib>Myachina, L. I.</creatorcontrib><creatorcontrib>Klevtsova, R. F.</creatorcontrib><creatorcontrib>Glinskaya, L. A.</creatorcontrib><creatorcontrib>Kurat’eva, N. V.</creatorcontrib><creatorcontrib>Uskov, E. M.</creatorcontrib><creatorcontrib>Rakhmanov, M. I.</creatorcontrib><creatorcontrib>Karpov, V. M.</creatorcontrib><creatorcontrib>Platonov, V. E.</creatorcontrib><creatorcontrib>Fadeeva, V. P.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Larionov, S. V.</au><au>Myachina, L. I.</au><au>Klevtsova, R. F.</au><au>Glinskaya, L. A.</au><au>Kurat’eva, N. V.</au><au>Uskov, E. M.</au><au>Rakhmanov, M. I.</au><au>Karpov, V. M.</au><au>Platonov, V. E.</au><au>Fadeeva, V. P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and photoluminescence of Zinc(II) complexes with tetrafluoroterephthalic acid (H2L). Crystal structure of coordination polymer [Zn(H2O)4(L) · 4H2O]n</atitle><jtitle>Russian journal of coordination chemistry</jtitle><stitle>Russ J Coord Chem</stitle><date>2011-09</date><risdate>2011</risdate><volume>37</volume><issue>9</issue><spage>650</spage><epage>656</epage><pages>650-656</pages><issn>1070-3284</issn><eissn>1608-3318</eissn><abstract>Complexes Zn(H
2
O)
4
(L) (
I
) and Zn(H
2
O)(L) (
II
) (H
2
L =
p
-HOOCC
6
F
4
COOH) are synthesized. Single crystals of compound [Zn(H
2
O)
4
(L) · 4H
2
O]
n
(
III
) are grown. According to the X-ray diffraction data, the crystal structure of compound
III
is built of zigzag chains of coordination polymer Zn(H
2
O)
4
(L) and molecules of water of crystallization. The chain contains ions Zn
2+
, whose octahedral coordination sphere includes the O atoms of four water molecules and two O atoms of the deprotonated carboxyl groups. The chains in structure
III
are joined by a system of hydrogen bonds of coordinated water molecules and molecules of water of crystallization. The photoluminescence spectrum of H
2
L exhibits the band with λ
max
= 368 nm. The spectra of compounds
III
,
I
, and
II
contain bands at 322, 340, and 353 nm, respectively.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S1070328411090041</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1070-3284 |
| ispartof | Russian journal of coordination chemistry, 2011-09, Vol.37 (9), p.650-656 |
| issn | 1070-3284 1608-3318 |
| language | eng |
| recordid | cdi_crossref_primary_10_1134_S1070328411090041 |
| source | SpringerNature Journals |
| subjects | Chemistry Chemistry and Materials Science Inorganic Chemistry Physical Chemistry |
| title | Synthesis and photoluminescence of Zinc(II) complexes with tetrafluoroterephthalic acid (H2L). Crystal structure of coordination polymer [Zn(H2O)4(L) · 4H2O]n |
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