Crystal structure of 4,4-bipyridine-containing complexes of copper(II) nitrate with 1-[(2-Hydroxyethylimino)methyl]naphthalen-2-ol and 2-[(2-hydroxyethylimino)methyl]phenol
The crystal structures of (μ-4,4-bipyridine)-di(nitrato-1-[(2-hydroxyethylimino)methyl]naphthalen-2-olocopper ( I ) and catena-di(μ-4,4’-bipyridine)di(μ-4,4’-bipyridine)-di(nitrato-2-[2-(hydroxyethylimino) methyl]phenolocopper)diaquacopper(II) nitrate ( II ) were determined. In the crystal of I , ea...
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| Veröffentlicht in: | Russian journal of coordination chemistry 2009-07, Vol.35 (7), p.504-511 |
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| creator | Chumakov, Yu. M. Tsapkov, V. L. Petrenko, P. A. Popovski, L. G. Simonov, Yu. A. Bocelli, G. Antosyak, B. Ya Paraschivescu, A. O. Gulea, A. P. |
| description | The crystal structures of (μ-4,4-bipyridine)-di(nitrato-1-[(2-hydroxyethylimino)methyl]naphthalen-2-olocopper (
I
) and catena-di(μ-4,4’-bipyridine)di(μ-4,4’-bipyridine)-di(nitrato-2-[2-(hydroxyethylimino) methyl]phenolocopper)diaquacopper(II) nitrate (
II
) were determined. In the crystal of
I
, each of the two copper atoms coordinates a singly deprotonated tridentate azomethine molecule, a nitrate ion, and bipyridine, which functions as a bridge between the central atoms. The copper coordination polyhedron is a slightly distorted tetragonal pyramid with the base formed by the imine and bipyridine nitrogen atoms and the phenol and alcohol oxygen atoms. The axial site in the pyramid is occupied by the oxygen atom of the monodentate nitrate groups. In the trinuclear structure
II
with C
2
crystal chemical symmetry, the terminal coordination unit is composed through copper coordination of monodeprotonated 2-[2-(hydroxyethylimino)methyl]phenol, bipyridine, and the nitrate anion. In the crystal, the trinuclear molecules form infinite ribbons along the
z
axis in which the pyridine molecules perform the bridging function. The central copper atom has an octahedral configuration formed by the nitrogen atoms of four 4,4’-bipyridine molecules and oxygen of two water molecules. |
| doi_str_mv | 10.1134/S1070328409070070 |
| format | Article |
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I
) and catena-di(μ-4,4’-bipyridine)di(μ-4,4’-bipyridine)-di(nitrato-2-[2-(hydroxyethylimino) methyl]phenolocopper)diaquacopper(II) nitrate (
II
) were determined. In the crystal of
I
, each of the two copper atoms coordinates a singly deprotonated tridentate azomethine molecule, a nitrate ion, and bipyridine, which functions as a bridge between the central atoms. The copper coordination polyhedron is a slightly distorted tetragonal pyramid with the base formed by the imine and bipyridine nitrogen atoms and the phenol and alcohol oxygen atoms. The axial site in the pyramid is occupied by the oxygen atom of the monodentate nitrate groups. In the trinuclear structure
II
with C
2
crystal chemical symmetry, the terminal coordination unit is composed through copper coordination of monodeprotonated 2-[2-(hydroxyethylimino)methyl]phenol, bipyridine, and the nitrate anion. In the crystal, the trinuclear molecules form infinite ribbons along the
z
axis in which the pyridine molecules perform the bridging function. The central copper atom has an octahedral configuration formed by the nitrogen atoms of four 4,4’-bipyridine molecules and oxygen of two water molecules.</description><identifier>ISSN: 1070-3284</identifier><identifier>EISSN: 1608-3318</identifier><identifier>DOI: 10.1134/S1070328409070070</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Physical Chemistry</subject><ispartof>Russian journal of coordination chemistry, 2009-07, Vol.35 (7), p.504-511</ispartof><rights>Pleiades Publishing, Ltd. 2009</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c288t-f8cba66453e77c6fc5ff65207625dcc3d8540835fde1cd8f1ab90d93b523a5a3</citedby><cites>FETCH-LOGICAL-c288t-f8cba66453e77c6fc5ff65207625dcc3d8540835fde1cd8f1ab90d93b523a5a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070328409070070$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070328409070070$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Chumakov, Yu. M.</creatorcontrib><creatorcontrib>Tsapkov, V. L.</creatorcontrib><creatorcontrib>Petrenko, P. A.</creatorcontrib><creatorcontrib>Popovski, L. G.</creatorcontrib><creatorcontrib>Simonov, Yu. A.</creatorcontrib><creatorcontrib>Bocelli, G.</creatorcontrib><creatorcontrib>Antosyak, B. Ya</creatorcontrib><creatorcontrib>Paraschivescu, A. O.</creatorcontrib><creatorcontrib>Gulea, A. P.</creatorcontrib><title>Crystal structure of 4,4-bipyridine-containing complexes of copper(II) nitrate with 1-[(2-Hydroxyethylimino)methyl]naphthalen-2-ol and 2-[(2-hydroxyethylimino)methyl]phenol</title><title>Russian journal of coordination chemistry</title><addtitle>Russ J Coord Chem</addtitle><description>The crystal structures of (μ-4,4-bipyridine)-di(nitrato-1-[(2-hydroxyethylimino)methyl]naphthalen-2-olocopper (
I
) and catena-di(μ-4,4’-bipyridine)di(μ-4,4’-bipyridine)-di(nitrato-2-[2-(hydroxyethylimino) methyl]phenolocopper)diaquacopper(II) nitrate (
II
) were determined. In the crystal of
I
, each of the two copper atoms coordinates a singly deprotonated tridentate azomethine molecule, a nitrate ion, and bipyridine, which functions as a bridge between the central atoms. The copper coordination polyhedron is a slightly distorted tetragonal pyramid with the base formed by the imine and bipyridine nitrogen atoms and the phenol and alcohol oxygen atoms. The axial site in the pyramid is occupied by the oxygen atom of the monodentate nitrate groups. In the trinuclear structure
II
with C
2
crystal chemical symmetry, the terminal coordination unit is composed through copper coordination of monodeprotonated 2-[2-(hydroxyethylimino)methyl]phenol, bipyridine, and the nitrate anion. In the crystal, the trinuclear molecules form infinite ribbons along the
z
axis in which the pyridine molecules perform the bridging function. The central copper atom has an octahedral configuration formed by the nitrogen atoms of four 4,4’-bipyridine molecules and oxygen of two water molecules.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Physical Chemistry</subject><issn>1070-3284</issn><issn>1608-3318</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNp9kN9KwzAUxosoOKcP4F0uNzCaP02bXcpQNxh44e5ESpoma0ablCTD9Z18SLvNO1E4cD7O-X6Hw5cktxjdY0zThzeMckQJT9FsEEOdJSOcIQ4pxfx80MMIHvaXyVUIW4QwQmw2Sr7mvg9RNCBEv5Nx5xVwGqR3KSxN13tTGaugdDYKY43dAOnarlF7FQ426bpO-clyOQXWRC-iAp8m1gDD9wmBi77ybt-rWPeNaY110_aoP6zo6liLRllIoGuAsBUgR6T-C-lqZV1znVxo0QR189PHyfr5aT1fwNXry3L-uIKScB6h5rIUWZYyqvJcZloyrTNGUJ4RVklJK85SxCnTlcKy4hqLcoaqGS0ZoYIJOk7w6az0LgSvdNF50wrfFxgVh7SLX2kPDDkxYfDajfLF1u28Hb78B_oGJgqFag</recordid><startdate>20090701</startdate><enddate>20090701</enddate><creator>Chumakov, Yu. M.</creator><creator>Tsapkov, V. L.</creator><creator>Petrenko, P. A.</creator><creator>Popovski, L. G.</creator><creator>Simonov, Yu. A.</creator><creator>Bocelli, G.</creator><creator>Antosyak, B. Ya</creator><creator>Paraschivescu, A. O.</creator><creator>Gulea, A. P.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20090701</creationdate><title>Crystal structure of 4,4-bipyridine-containing complexes of copper(II) nitrate with 1-[(2-Hydroxyethylimino)methyl]naphthalen-2-ol and 2-[(2-hydroxyethylimino)methyl]phenol</title><author>Chumakov, Yu. M. ; Tsapkov, V. L. ; Petrenko, P. A. ; Popovski, L. G. ; Simonov, Yu. A. ; Bocelli, G. ; Antosyak, B. Ya ; Paraschivescu, A. O. ; Gulea, A. P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c288t-f8cba66453e77c6fc5ff65207625dcc3d8540835fde1cd8f1ab90d93b523a5a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chumakov, Yu. M.</creatorcontrib><creatorcontrib>Tsapkov, V. L.</creatorcontrib><creatorcontrib>Petrenko, P. A.</creatorcontrib><creatorcontrib>Popovski, L. G.</creatorcontrib><creatorcontrib>Simonov, Yu. A.</creatorcontrib><creatorcontrib>Bocelli, G.</creatorcontrib><creatorcontrib>Antosyak, B. Ya</creatorcontrib><creatorcontrib>Paraschivescu, A. O.</creatorcontrib><creatorcontrib>Gulea, A. P.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chumakov, Yu. M.</au><au>Tsapkov, V. L.</au><au>Petrenko, P. A.</au><au>Popovski, L. G.</au><au>Simonov, Yu. A.</au><au>Bocelli, G.</au><au>Antosyak, B. Ya</au><au>Paraschivescu, A. O.</au><au>Gulea, A. P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystal structure of 4,4-bipyridine-containing complexes of copper(II) nitrate with 1-[(2-Hydroxyethylimino)methyl]naphthalen-2-ol and 2-[(2-hydroxyethylimino)methyl]phenol</atitle><jtitle>Russian journal of coordination chemistry</jtitle><stitle>Russ J Coord Chem</stitle><date>2009-07-01</date><risdate>2009</risdate><volume>35</volume><issue>7</issue><spage>504</spage><epage>511</epage><pages>504-511</pages><issn>1070-3284</issn><eissn>1608-3318</eissn><abstract>The crystal structures of (μ-4,4-bipyridine)-di(nitrato-1-[(2-hydroxyethylimino)methyl]naphthalen-2-olocopper (
I
) and catena-di(μ-4,4’-bipyridine)di(μ-4,4’-bipyridine)-di(nitrato-2-[2-(hydroxyethylimino) methyl]phenolocopper)diaquacopper(II) nitrate (
II
) were determined. In the crystal of
I
, each of the two copper atoms coordinates a singly deprotonated tridentate azomethine molecule, a nitrate ion, and bipyridine, which functions as a bridge between the central atoms. The copper coordination polyhedron is a slightly distorted tetragonal pyramid with the base formed by the imine and bipyridine nitrogen atoms and the phenol and alcohol oxygen atoms. The axial site in the pyramid is occupied by the oxygen atom of the monodentate nitrate groups. In the trinuclear structure
II
with C
2
crystal chemical symmetry, the terminal coordination unit is composed through copper coordination of monodeprotonated 2-[2-(hydroxyethylimino)methyl]phenol, bipyridine, and the nitrate anion. In the crystal, the trinuclear molecules form infinite ribbons along the
z
axis in which the pyridine molecules perform the bridging function. The central copper atom has an octahedral configuration formed by the nitrogen atoms of four 4,4’-bipyridine molecules and oxygen of two water molecules.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S1070328409070070</doi><tpages>8</tpages></addata></record> |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Chemistry Chemistry and Materials Science Inorganic Chemistry Physical Chemistry |
| title | Crystal structure of 4,4-bipyridine-containing complexes of copper(II) nitrate with 1-[(2-Hydroxyethylimino)methyl]naphthalen-2-ol and 2-[(2-hydroxyethylimino)methyl]phenol |
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