Pd(II) and Au(I) chloride complexes with tetrakis(butylthiomethyl)calix[4]arene: Synthesis and crystal structures
Two novel complexes, (AuCl) 4 L 3 ( I ) and (PdCl 2 ) 2 L 3 ( II ) (L 3 is calix[4]arene-thioether), were synthesized and their structures were determined. In complex I , one thioether group of molecule L 3 is coordinated to every Au atom. In complex II , the bidentate coordination of L 3 to the Pd...
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| Veröffentlicht in: | Russian journal of coordination chemistry 2008-05, Vol.34 (5), p.360-366 |
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| container_end_page | 366 |
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| container_issue | 5 |
| container_start_page | 360 |
| container_title | Russian journal of coordination chemistry |
| container_volume | 34 |
| creator | Kostin, G. A. Mashukov, V. I. Kurat’eva, N. V. Tkachev, S. V. Torgov, V. G. Drapailo, A. B. |
| description | Two novel complexes, (AuCl)
4
L
3
(
I
) and (PdCl
2
)
2
L
3
(
II
) (L
3
is calix[4]arene-thioether), were synthesized and their structures were determined. In complex
I
, one thioether group of molecule L
3
is coordinated to every Au atom. In complex
II
, the bidentate coordination of L
3
to the Pd atoms is observed; two thioether groups are in the
trans
-positions in the Pd square surrounding. Both complexes have the layered crystal lattices. In the Au complex, the layers are more stable due to the short contacts Au-Au (3.19–3.23 Å). |
| doi_str_mv | 10.1134/S1070328408050084 |
| format | Article |
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4
L
3
(
I
) and (PdCl
2
)
2
L
3
(
II
) (L
3
is calix[4]arene-thioether), were synthesized and their structures were determined. In complex
I
, one thioether group of molecule L
3
is coordinated to every Au atom. In complex
II
, the bidentate coordination of L
3
to the Pd atoms is observed; two thioether groups are in the
trans
-positions in the Pd square surrounding. Both complexes have the layered crystal lattices. In the Au complex, the layers are more stable due to the short contacts Au-Au (3.19–3.23 Å).</description><identifier>ISSN: 1070-3284</identifier><identifier>EISSN: 1608-3318</identifier><identifier>DOI: 10.1134/S1070328408050084</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Physical Chemistry</subject><ispartof>Russian journal of coordination chemistry, 2008-05, Vol.34 (5), p.360-366</ispartof><rights>MAIK Nauka 2008</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c288t-86d4289cdb9c9f86aa93ec55a22adead917b49b36b41103e7d6ba811fdc03e6a3</citedby><cites>FETCH-LOGICAL-c288t-86d4289cdb9c9f86aa93ec55a22adead917b49b36b41103e7d6ba811fdc03e6a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070328408050084$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070328408050084$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Kostin, G. A.</creatorcontrib><creatorcontrib>Mashukov, V. I.</creatorcontrib><creatorcontrib>Kurat’eva, N. V.</creatorcontrib><creatorcontrib>Tkachev, S. V.</creatorcontrib><creatorcontrib>Torgov, V. G.</creatorcontrib><creatorcontrib>Drapailo, A. B.</creatorcontrib><title>Pd(II) and Au(I) chloride complexes with tetrakis(butylthiomethyl)calix[4]arene: Synthesis and crystal structures</title><title>Russian journal of coordination chemistry</title><addtitle>Russ J Coord Chem</addtitle><description>Two novel complexes, (AuCl)
4
L
3
(
I
) and (PdCl
2
)
2
L
3
(
II
) (L
3
is calix[4]arene-thioether), were synthesized and their structures were determined. In complex
I
, one thioether group of molecule L
3
is coordinated to every Au atom. In complex
II
, the bidentate coordination of L
3
to the Pd atoms is observed; two thioether groups are in the
trans
-positions in the Pd square surrounding. Both complexes have the layered crystal lattices. In the Au complex, the layers are more stable due to the short contacts Au-Au (3.19–3.23 Å).</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Physical Chemistry</subject><issn>1070-3284</issn><issn>1608-3318</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNp9kF9LwzAUxYMoOKcfwLc8bg_VpGm7xLcx_FMYKEyfREqa3NrMrJ1Jiuu3t3O-CT7dczn3d7gchC4puaKUJdcrSmaExTwhnKSE8OQIjWhGeMQY5ceDHuxo75-iM-_XhFBCUjFCn096kudTLBuN591kUKq2rTMasGo3Wws78PjLhBoHCE5-GD8pu9DbUJt2A6Hu7VRJa3avyZt00MANXvVNqMEb_5OpXO-DtNgH16nQOfDn6KSS1sPF7xyjl7vb58VDtHy8zxfzZaRizkPEM53EXChdCiUqnkkpGKg0lXEsNUgt6KxMRMmyMqGUMJjprJSc0kqrYcskGyN6yFWu9d5BVWyd2UjXF5QU-86KP50NTHxg_HDbvIMr1m3nmuHNf6BvrjlwKQ</recordid><startdate>20080501</startdate><enddate>20080501</enddate><creator>Kostin, G. A.</creator><creator>Mashukov, V. I.</creator><creator>Kurat’eva, N. V.</creator><creator>Tkachev, S. V.</creator><creator>Torgov, V. G.</creator><creator>Drapailo, A. B.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20080501</creationdate><title>Pd(II) and Au(I) chloride complexes with tetrakis(butylthiomethyl)calix[4]arene: Synthesis and crystal structures</title><author>Kostin, G. A. ; Mashukov, V. I. ; Kurat’eva, N. V. ; Tkachev, S. V. ; Torgov, V. G. ; Drapailo, A. B.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c288t-86d4289cdb9c9f86aa93ec55a22adead917b49b36b41103e7d6ba811fdc03e6a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kostin, G. A.</creatorcontrib><creatorcontrib>Mashukov, V. I.</creatorcontrib><creatorcontrib>Kurat’eva, N. V.</creatorcontrib><creatorcontrib>Tkachev, S. V.</creatorcontrib><creatorcontrib>Torgov, V. G.</creatorcontrib><creatorcontrib>Drapailo, A. B.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kostin, G. A.</au><au>Mashukov, V. I.</au><au>Kurat’eva, N. V.</au><au>Tkachev, S. V.</au><au>Torgov, V. G.</au><au>Drapailo, A. B.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Pd(II) and Au(I) chloride complexes with tetrakis(butylthiomethyl)calix[4]arene: Synthesis and crystal structures</atitle><jtitle>Russian journal of coordination chemistry</jtitle><stitle>Russ J Coord Chem</stitle><date>2008-05-01</date><risdate>2008</risdate><volume>34</volume><issue>5</issue><spage>360</spage><epage>366</epage><pages>360-366</pages><issn>1070-3284</issn><eissn>1608-3318</eissn><abstract>Two novel complexes, (AuCl)
4
L
3
(
I
) and (PdCl
2
)
2
L
3
(
II
) (L
3
is calix[4]arene-thioether), were synthesized and their structures were determined. In complex
I
, one thioether group of molecule L
3
is coordinated to every Au atom. In complex
II
, the bidentate coordination of L
3
to the Pd atoms is observed; two thioether groups are in the
trans
-positions in the Pd square surrounding. Both complexes have the layered crystal lattices. In the Au complex, the layers are more stable due to the short contacts Au-Au (3.19–3.23 Å).</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S1070328408050084</doi><tpages>7</tpages></addata></record> |
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| issn | 1070-3284 1608-3318 |
| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Chemistry Chemistry and Materials Science Inorganic Chemistry Physical Chemistry |
| title | Pd(II) and Au(I) chloride complexes with tetrakis(butylthiomethyl)calix[4]arene: Synthesis and crystal structures |
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